Borane-ammonia complex - ≥90% , CAS No.13774-81-7

CAS: 13774-81-7 Cat. No.: B137458 Molecular Weight: 30.87 EC Number: 642-983-4

GRADE & PURITY ≥90%

Synonyms

azaniumylboranuide | DTXCID001324415 | Ammonia borane

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Overview

Ammonia borane is a proposed storage medium for hydrogen in motor fuel vehicles. It is more hydrogen-dense than liquid hydrogen and is also able to exist at normal temperatures and pressures. It is also used in organic synthesis.
A proposed storage medium for hydrogen in motor fuel vehicles, also used in organic synthesis.

Specifications

Synonyms

azaniumylboranuide | DTXCID001324415 | Ammonia borane

Specifications & Purity

≥90%

Storage

Store at 2-8°C, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥90%

Names and Identifiers

• Canonical Smiles: [BH3-][NH3+]
• IUPAC Name: azaniumylboranuide
• InChIKey: PJYXJGDRFASJSB-UHFFFAOYSA-N
• INCHI: 1S/BH6N/c1-2/h1-2H3
• Isomeric SMILES: [BH3-][NH3+]
• Molecular Weight: 30.87
• Reaxy-Rn: 27903382
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=27903382&ln=

Chemical and Physical Properties

• Sensitivity: Moisture sensitive，Heat sensitive
• Melt Point(°C): 98 °C

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71. Shuo Zhang, Jun Liu, Chao Shang, Mingzhen Hu, Hexin Zhou, Xuemin Hu, Wenxiu Yang, Erhong Duan, Zhuozhi Wang, Jie Xu, Shuo Wang.  (2024)  Enhanced catalysis of Au/TiO2 for transfer hydrogenation of unsaturated nitro compounds by surface engineering.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2024.159503]

72. Bomin Feng, Jun Chen, Yifei Yang, Mao Yang, Hongbing Wang, Changyin Zhong, Yawei Hao, Jinhua Yang, Jian Jiao, Yunxi Yao.  (2024)  Fabrication of BN thin films by chemical vapor deposition on 4H–SiC (0001) single-crystalline surfaces.  VACUUM,      [PMID:] [10.1016/j.vacuum.2024.113009]

73. Ruyi Cui, Yong Zhou, Xingyi Xu, Hengxin Fang, Wenlong Wang, Sanmei Wang, Pengbo Lyu, Lizhong Sun, Biao Wang, Changqing Sun.  (2025)  Fine-tuning Ru nanocatalyst size in UiO-66-NH2-derived carbon nitride for efficient hydrogen production from ammonia borane.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,      [PMID:] [10.1016/j.ijhydene.2025.02.369]

74. Xusheng Yang, Le Zhou, Changsong Chen, Weidong Jiang, Xiaobin Zhang, Pingchuan Pan, Shengbin Zhou, Kaiming Zhang, Bin Xu.  (2024)  Gamma-ray-irradiated preparation and performance of magnetothermally responsive hybrid materials towards the tandem hydrogenation of halonitrobenzenes.  Surfaces and Interfaces,      [PMID:] [10.1016/j.surfin.2024.104042]

75. Bingke Yang, Haojie Li, Zhen Yao, Lili Xing, Xuetao Wang, Yilin Zhu.  (2025)  Investigation of Reaction Mechanism and Conditions on Ammonia Borane Alcoholysis with Different Alcohols(CH3OH, CH3CH2OH, (CH2OH)2).  NEW JOURNAL OF CHEMISTRY,      [PMID:] [10.1039/D4NJ05365F]

76. Ximei Sun, Feirong Wang, Jieqiong Wang, Hao Xiao, Qiang Kang, Yiqian Zeng, Qinglai Yang, Xiaofeng Tan.  (2024)  Ionic liquid-induced Pd aerogels with interface regulation for boosted catalytic reduction of 4-nitrophenol.  MICROPOROUS AND MESOPOROUS MATERIALS,      [PMID:] [10.1016/j.micromeso.2024.113027]

77. Patrick Ryan Galligan, Hongwei Liu, Guang Wang, Mohsen Tamtaji, Yaxuan Li, Tsz Wing Tang, Yanguang Zhou, Zhengtang Luo.  (2024)  Lightweight, freestanding hybrids of graphene and hexagonal boron nitride foams.  COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING,      [PMID:] [10.1016/j.compositesa.2024.108176]

78. Hongxia Zhang, Qiaoting Niu, Yahang Mou, Zhihao Bian, Tianle Zhang, Changqing Chu, Dezhi Han, Fang Wang, Guangjian Wang, Liancheng Bing.  (2025)  MCM-41-supported ultrafine PtNi nanoparticles as highly active catalysts for hydrogen generation from ammonia borane hydrolysis and tandem reduction of 4-nitrophenol.  Journal of Environmental Chemical Engineering,      [PMID:] [10.1016/j.jece.2025.115936]

79. Ziyuan Xiu, Wei Mu, Xin Zhou, Xiaojun Han.  (2024)  Mild polarization electric field in ultra-thin BN-Fe-graphene sandwich structure for efficient nitrogen reduction.  CHINESE JOURNAL OF CATALYSIS,      [PMID:] [10.1016/S1872-2067(24)60114-2]

80. Menghui Wei, Junchao Han, Qikang Wu, Jingjing Li, Zili Ji, Zhi Li, Jia Liang, Yanhui Guo.  (2024)  Monolithic CoMoB based catalyst enabling high water-sources adaptive hydrolysis of borohydrides.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.148879]

81. Yutong Li, Qiuhong Wei, Haoyue Huang, Shujun Qiu, Yongpeng Xia, Yongjin Zou, Fen Xu, Lixian Sun, Hailiang Chu.  (2025)  Multi-interfacial engineering of CoN/CoP heterostructures by synergistic coupling of Ru and MXene for high-efficiency hydrogen generation from ammonia-borane hydrolysis.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,      [PMID:] [10.1016/j.ijhydene.2025.02.117]

82. Yuyang Cao, Shilong Yang, Pu Liu, Qianqian Zhu, Xiucheng Zheng.  (2025)  Nickel-promoted ruthenium nanocatalysts for controllable hydrogen production from NH3BH3 hydrolysis.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2025.162345]

83. Jie Jin, Haoran Li, Shanshan Wu, Jing Wang, Qunling Fang, Chunyan Xu, Yunqi Xu, Weili Kong, Di Wang, Shouhu Xuan.  (2024)  NIR-enhanced multi-mode catalytic activity over Pd nanocrystals sandwiched within magnetic polydopamine hollow spheres.  CRYSTENGCOMM,  26  (27): (3609-3626).  [PMID:] [10.1039/D4CE00490F]

84. Weizhe Wang, Debiao Xiao, Shulei Fan, Senlin Deng, Shijie Yang, Zhaocheng Li, Tangyou Sun, Jing Peng, Zhimou Xu.  (2024)  Portable dual-functional hygroscopic device for efficient atmospheric water harvesting and hydrogen production in diverse environments.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.157651]

85. Chi Ma, Zhiyong Zhong, Quanjun Xiang.  (2024)  Regulating electrons transfer through Pd-O-Bi bridges for boosting photocatalytic CO2 reduction.  Molecular Catalysis,      [PMID:] [10.1016/j.mcat.2024.114700]

86. Chuang Liu, Dan Wei, Chengwang Yin, Shujun Qiu, Yongpeng Xia, Yongjin Zou, Fen Xu, Lixian Sun, Hailiang Chu.  (2024)  Ruthenium nanoparticles supported on functionalized carbon nanotubes as high-efficiency catalysts for ammonia borane hydrolysis.  MATERIALS CHEMISTRY AND PHYSICS,      [PMID:] [10.1016/j.matchemphys.2024.129398]

87. Hailiang Chu, Guangyao Li, Chuang Liu, Chenhui Cui, Yutong Li, Shujun Qiu, Yongpeng Xia, Yongjin Zou, Fen Xu, Lixian Sun.  (2024)  Ruthenium-Based High-Entropy Alloys Expediting Hydrogen Evolution through Catalytic Hydrolysis of Ammonia Borane.  ACS Applied Energy Materials,      [PMID:] [10.1021/acsaem.4c01875]

88. Haibo Tao, Yan Xia, Tao Tang, Yuan Zhang, Shi Qiu, Junkang Chen, Zhengjiang Xu, Lei Li, Jiajun Qiu, Panfeng Wang, Jianghong Wu, Xiaobing Zhao, Shuogui Xu, Guocheng Wang.  (2024)  Self-responsive H2-releasing microneedle patch temporally adapts to the sequential microenvironment requirements for optimal diabetic wound healing.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.151200]

89. Zhang Wei, Qin Lizhong, Qi Xiaohui, Na Liyan, Hua Ruinian.  (2024)  Synthesis and photocatalytic properties of β-NaY(Gd)F4:Yb3+,Er3+@W18O49 nanocomposites.  JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS,  35  (27): (1-12).  [PMID:] [10.1007/s10854-024-13565-6]

90. Lu Li, Shiyu Ma, Huimin Liu, Zixuan Zeng, Qijie Li, Chunlin Song, Jingang Yang.  (2024)  Ternary Fe–Ni–B particles supported on Cu(OH)2–Cu foam: A highly efficient and stable catalyst for hydrolysis of ammonia borane.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,      [PMID:] [10.1016/j.ijhydene.2024.07.391]

91. Yihan Zhang, Song Wu, Ting Sun, Qianggen Li, Guangyin Fan.  (2024)  Ultrafast joule-heating-assisted O, N dual-doping of unfunctionalized carbon enhances Ru nanoparticle-catalyzed hydrogen production.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:39591857] [10.1016/j.jcis.2024.11.141]

92. Linyan Bian, Licheng Liang, Yanping Fan, Xianyun Liu, Fei Liang, Qiuming Peng, Shumin Han, Lili Liu, Baozhong Liu.  (2024)  V-doped activated Ru/Ti2.5V0.5C2 dual-active center accelerate hydrogen production from ammonia borane.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:38820839] [10.1016/j.jcis.2024.05.190]

93. Fenglong Wu, Xiao Tian, Jin Song, Ying Zhang, Wei Li.  (2025)  Amorphous MoO2-wrapped Mo supported low-crystalline Co nanosheets for enhanced OH bond cleavage: synergistic effect of abundant active sites and robust interfaces.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:40628063] [10.1016/j.jcis.2025.138322]

94. Dawson Wai-Shun Suen, Yujie Yan, Eugene Yin-Cheung Wong, Xiao-Ying Lu, Jiajun Chen, Chi-Wing Tsang, Chunzhen Yang, Shaobo Ouyang.  (2025)  A novel catalyst featuring highly stable cobalt and manganese nitride nanoclusters dispersed on single atom-anchored carbon nanotubes for hydrolytic release of hydrogen from ammonia borane.  Surfaces and Interfaces,      [PMID:] [10.1016/j.surfin.2025.106519]

95. Luo Tao, Li Shen-Ao, Chen Liu-Cheng, Zhong Guo-Hua, Lin Hai-Qing, Chen Xiao-Jia.  (2025)  Superconductivity of zirconium-nitrogen hydrides at megabar pressures.  Communications Materials,  6  (1): (1-9).  [PMID:] [10.1038/s43246-025-00808-0]

96. Yutong Li, Haoyue Huang, Qiuhong Wei, Shujun Qiu, Yongpeng Xia, Fen Xu, Lixian Sun, Hailiang Chu.  (2025)  Ruthenium Nanoparticles Anchored on Cobalt Oxide Married with Nitrogen and Phosphorus Co-Doped Carbon for Hydrolytic Dehydrogenation of Ammonia Borane.  ACS Catalysis,      [PMID:] [10.1021/acscatal.5c01378]

97. Zishuo Hou, Wuyang Zhang, Gangfeng Li, Hannan Cui, Hongli Chen, Tengjiao Wang, Yafei Feng, Peng Li.  (2025)  Coaxial Fibrous Dressing Enabling Sequential NO/H2 Release for Temporally Programmed Antibacterial and Healing-Promoting Functions in Infected Diabetic Wound Treatment.  ACS Applied Materials & Interfaces,      [PMID:40504663] [10.1021/acsami.5c07099]

98. Aining Zhang, Xue Jiang, Bingrui Xiong, Jiayi Chen, Xin Liu, Siyuan Wang, Bofu Li, Mian Peng, Wei Li.  (2025)  Sustained-Release Photothermal Microneedles for Postoperative Incisional Analgesia and Wound Healing via Hydrogen Therapy.  Advanced Science,      [PMID:40548456] [10.1002/advs.202503698]

99. Yunlong Zhang, Rui Pu, Shaoli Chen, Qilong Yan.  (2025)  Thermal Interaction Mechanisms of Ammonium Perchlorate and Ammonia Borane.  MOLECULES,  30  (13): (2680).  [PMID:40649199] [10.3390/molecules30132680]

100. Wang Qi, Zhang Minyi, Jiang Weihao, Li Dejian, Qi Beijie, Shi Shi, Shi Shuo, Yi Chengqing.  (2025)  Spontaneous hydrogen-releasing nanoenzyme alleviates osteoarthritis via oxidative stress reduction and mitochondrial dysfunction reversal.  JOURNAL OF NANOBIOTECHNOLOGY,  23  (1): (1-19).  [PMID:41076526] [10.1186/s12951-025-03716-0]

101. Xiaoxuan Ren, Yue Sun, Shengjie Li, Xuwen Gao, Guizheng Zou.  (2025)  Defect-Involved Chemiluminescence of Unary Copper Nanocrystals towards Semi-Automatic Immunoassay.  ANALYTICAL CHEMISTRY,      [PMID:41163362] [10.1021/acs.analchem.5c05245]

102. Ying Zhang, Yuxuan Chen, Tong Zheng, Juan Mu, Zhengwang Zhu, Haifeng Zhang, Yandong Wang.  (2025)  Effect of Ni Content on the Microstructure and Catalytic Performance of NiFeCoCrMn Alloy.  ACS Applied Energy Materials,      [PMID:] [10.1021/acsaem.5c02772]

103. Feng Chen, Xuelong He, Baokang Lyu, Xiang Lin, Tiejun Chen, Zhenzhen Feng, Xinghao Li, Bin Sun, Yaozu Liao, Weiyi Zhang.  (2025)  Polymeric Porous Organic Cages: A Platform for Processable Catalysis and Separation.  ACS Applied Materials & Interfaces,      [PMID:41400591] [10.1021/acsami.5c21228]

104. Tsz Wing Tang, Ritika Ritika, Mohsen Tamtaji, Hongwei Liu, Yunxia Hu, Zhenjing Liu, Patrick Ryan Galligan, Mengyang Xu, Jinghan Shen, Jun Wang, Jiawen You, Yuyin Li, GuanHua Chen, Igor Aharonovich, Zhengtang Luo.  (2025)  Structured-Defect Engineering of Hexagonal Boron Nitride for Identified Visible Single-Photon Emitters.  ACS Nano,      [PMID:40019736] [10.1021/acsnano.4c11413]

105. Ruizhe Wu, Sheng Wu, Jie Pan.  (2025)  Revealing the Principles of Confining Electroplated Lithium beneath the CVD Grown Single Layer 2D Materials.  Small,  21  (8): (2408986).  [PMID:39811944] [10.1002/smll.202408986]

106. Lei Liu, Zijian Zhou, Ying Liu, Xin Yu, Dunxi Yu, Minghou Xu.  (2025)  Multi-shell nanostructures minimize diffusion pathways and dual active sites decouple activation for efficient ammonia borane hydrolysis.  Journal of Materials Chemistry A,      [PMID:] [10.1039/D5TA08596A]

107. Yu-Yang Cao, Yi Xiong, Xiao-Li Zhang, Xin-Xin Guan, Xiu-Cheng Zheng.  (2025)  Chitosan-derived carbon aerogel stabilized Ru nanoparticles: Facile fabrication and application in catalyzing NH3BH3 hydrolytic dehydrogenation.  FUEL,      [PMID:] [10.1016/j.fuel.2025.136383]

108. Ma Jiaxin, Shao Cong, Wang Yirong, Niu Guosheng, Yang Kaiyi, Zhao Yao, Wang Fuyi, Nie Zongxiu, Wang Jizheng.  (2026)  Ammonia Borane All-In-One Modification Strategy Enables High-Performance Perovskite Solar Cells.  Nano-Micro Letters,  18  (1): (93).  [PMID:41479044] [10.1007/s40820-025-01951-6]

109. Wenxing Jiang, Yuanting Peng, Qiqi Wan, Endao Zhang, Junbo Hou, Xiaodong Zhuang, Changchun Ke.  (2026)  Pd-integrated nanostructured electrode-boosted direct ammonia borane fuel cells with power density of over 700 mW cm−2.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2026.173017]

110. Shujun Qiu, Wenjin Huang, Yutong Li, Yongpeng Xia, Hailiang Chu, Yongjin Zou, Fen Xu, Lixian Sun.  (2026)  Cobalt-induced superior catalytic performance of ruthenium nanoparticles anchored on titania nanosheets for ammonia borane hydrolysis.  JOURNAL OF ALLOYS AND COMPOUNDS,      [PMID:] [10.1016/j.jallcom.2026.186977]

111. Jiankang Zhang, Hao Xu, Jie Gan, Shuangfeng Xing, Xinshuo Zhao, Yong Qin.  (2026)  Enhanced generation and stabilization of oxygen vacancy on defective ceria by platinum cluster as dual-site catalysts to boost hydrogen production activity and stability.  APPLIED CATALYSIS B-ENVIRONMENTAL,      [PMID:] [10.1016/j.apcatb.2026.126623]

112. Xinyuan Luo, Junhao Luo, Kang Chen, Jincheng Huang, Jing Zhao, Lang Gan, Yanjie Ren.  (2026)  In-situ construction of core-shell Co3N@C catalysts for boosted hydrogen evolution from ammonia borane hydrolysis.  JOURNAL OF POWER SOURCES,      [PMID:] [10.1016/j.jpowsour.2026.239894]

113. Xingyu Liu, Huiyang Li, Guoli Zhao, Weiya Yang.  (2026)  Novel green synthesis of NiO–Co3O4–CuO composites as highly active catalyst for ammonia borane hydrolysis.  JOURNAL OF THE INDIAN CHEMICAL SOCIETY,  103  (5): (102576).  [PMID:] [10.1016/j.jics.2026.102576]