Grubbs Catalyst - Ru 12.3% , CAS No.172222-30-9

CAS: 172222-30-9 Cat. No.: G113747 Summenformel: C₄₃H₇₂Cl₂P₂Ru Molekulargewicht: 822.96 EG-Nummer: 629-485-2

GRADE & PURITY Ru 12.3%

Synonyms

Umicore Grubbs Catalyst M102

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Übersicht

Ruthenium-Based Metathesis Catalysts,widely used in organic synthesis.

Product class
M-P, Homogeneous Catalysts, M-C, Grubbs Catalyst® 1st Generation, Carbene Ligands, Phosphorus Ligands - Achiral

Reaction type
Alkene Metathesis, Acyclic Diene Metathesis, Cross Metathesis, Ring Arrangement Metathesis , Ring Closing Metathesis, Ring Opening Metathesis Polymerization, Self Metathesis

Chemical properties

Chemical formula

C43H72Cl2P2Ru

Empirical formula

Ru(PCy3)2(benzylidene)Cl2

Molecular weight

822.96

Metal

Ru

Theoretical metal content

12

Physical state

powder

Color

purple

Applications & references

Formal Synthesis of (-)-Haliclonin A: Stereoselective Construction of an Azabicyclo[3.3.1]nonane Ring System by a Tandem Radical Reaction.

Reference: Org. Lett. 2020, 22, 13, 5046–5050

Formylation of a metathesis-derived ansa[4]-ferrocene: a simple route to anticancer organometallics.

Reference: Dalton Trans. 2020, (doi.org/10.1039/D0DT01975E)

Aerogels for the separation of asphalt-containing oil–water mixtures and the effect of asphalt stabilizer.

Reference: RSC Adv. 2020,10, 24840-24846

Asymmetric total synthesis of the naturally occurring antibiotic Anthracimycin

Reference: Org. Lett. 2020, 22, 14, 5550–5554

Sequential two-fold Claisen Rearrangement, One-pot Ring Closing Metathesis and Cross-metathesis as a Route to Substituted Benzo[b]azepine-2-one, Benzo[b]azepine and Benzo[b]oxepine Derivatives.

Reference: Helv Chem Acta 2020 ASAP (doi.org/10.1002/hlca.202000216)

Specifications

Synonyme

Umicore Grubbs Catalyst M102

Spezifikationen & Reinheit

Ru 12.3%

Storage

Store at 2-8°C,Argon charged

Verschickt in

Wet ice

Dieses Produkt erfordert Kühlkettenversand. Grundversand und andere Economy-Optionen sind nicht verfügbar.

Namen und Kennungen

• Kanonisches Lächeln: C[Ph].P(C1CCCCC1)(C2CCCCC2)C3CCCCC3.P(C4CCCCC4)(C5CCCCC5)C6CCCCC6.Cl.Cl.[Ru
• WGK Deutschland: 3
• UN-Nummer: 1325
• Molekulargewicht: 822.96

Chemische und physikalische Eigenschaften

• Empfindlichkeit: Air and Light sensitive.
• Schmelzpunkt (°C): 153°C

Referenzen

1. Hongmei Qin, Man Liu, Shiyu Qin, Shixian Zhang, Xingnan Zhou, Chenjian Li, Yuhao Wei, Dan Chen, Rong Fan, Shan Wang, Quanling Yang, Chuanxi Xiong, Qing Wang.  (2024)  Stereoisomerically enhanced polynorbornene-imide dielectric energy storage performance.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.149244]

Häufig gestellte Fragen

How should this product be stored?

Store at 2–8 °C under argon. It is supplied under an argon blanket; reseal under inert gas after each use.

What documentation is provided?

Available product documentation, including Certificates of Analysis (COA), Safety Data Sheets (SDS), and specification sheets, is shown in the product document area. Document availability and access follow the current site policy.

How is this product shipped?

This product ships chilled on wet ice. Unpack on arrival and transfer it to the storage condition stated above.

What are the CAS number, molecular formula and molecular weight?

The CAS Number is 172222-30-9, the molecular formula is C43H72Cl2P2Ru, and the molecular weight is 822.96 g/mol.