Ir[dFMeppy]₂-(4,4′-dCF₃bpy)PF₆ - ≥95% , CAS No.2229858-27-7

CAS: 2229858-27-7 Cat. No.: I463575 Summenformel: C₃₆H₂₂F₁₆IrN₄P Molekulargewicht: 1037.75 EG-Nummer: 889-021-1 PubChem CID: 166604231

GRADE & PURITY ≥95%

Synonyms

4,4'-Bis(trifluoromethyl)-2,2'-bipyridinebis[3,5-difluoro-2-[5-methyl-2-pyridinyl)phenyl]iridium(III)hexafluorophosphate | Photocatalyst

Storage

Protected from light,Argon charged,Room temperature

Shipped In

Normal

Übersicht

Application

Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF3 and supersilanol；

Specifications

Synonyme

4,4'-Bis(trifluoromethyl)-2,2'-bipyridinebis[3,5-difluoro-2-[5-methyl-2-pyridinyl)phenyl]iridium(III)hexafluorophosphate | Photocatalyst

Spezifikationen & Reinheit

≥95%

Storage

Protected from light,Argon charged,Room temperature

Verschickt in

Normal

Reinheit

≥95%

Namen und Kennungen

• Pubchem Sid: 488203117
• Kanonisches Lächeln: CC1=CN=C(C=C1)C2=CC=CC=[C-]2.CC1=CN=C(C=C1)C2=CC=CC=[C-]2.C1=CN=C(C=C1C(F)(F)F)C2=NC=CC(=C2)C(F)(F)F.F[P-](F)(F)(F)(F)F.[Ir+3]
• Isomere SMILES: CC1=CN=C(C=C1)C2=CC=CC=[C-]2.CC1=CN=C(C=C1)C2=CC=CC=[C-]2.C1=CN=C(C=C1C(F)(F)F)C2=NC=CC(=C2)C(F)(F)F.F[P-](F)(F)(F)(F)F.[Ir+3]
• PubChem CID: 166604231
• Molekulargewicht: 1037.75

Chemische und physikalische Eigenschaften

• Empfindlichkeit: Light sensitive
• Schmelzpunkt (°C): ＞300°C