Lithium metaborate - ACS, ≥98%, used for Lithium metaborate fusion can be used for the preparation of geological materials. The fusion of rock samples with LMB results in the formation of glasses that are easily soluble in dilute acids. This method allows

CAS: 13453-69-5 Cat. No.: L101993 Summenformel: LiBO₂ Molekulargewicht: 49.75 EG-Nummer: 236-631-5

GRADE & PURITY ACS, ≥98%

Synonyms

Q3080967 | J-006553 | Borate(1-),tetrahydroxy-, lithium, hexahydrate (9CI) | lithium;oxido(oxo)borane | MFCD00011089 | Lithiummetaborate | 100% Lithium metaborate; granular | lithium boranate | Borate(1-),tetrahydroxy-,lithium,hexahydrate(9ci) | lithium s

Storage

Room temperature,Argon charged,Desiccated

Shipped In

Normal

Übersicht

Lithium metaborate (LMB) isa good ion conductor and wide bandgap insulator commonly used as a flux orsolvent to identify and characterize uranium and thorium-containing resistantminerals. LMB is also used as a chemical modifier during thegeneration of new compounds from clays and refractory materials. Because of itshigh optical damage thresholds, mechanical durability, and deep-ultraviolettransparency, it is a suitable material for non-linear optics.

Specifications

Synonyme

Q3080967 | J-006553 | Borate(1-),tetrahydroxy-, lithium, hexahydrate (9CI) | lithium;oxido(oxo)borane | MFCD00011089 | Lithiummetaborate | 100% Lithium metaborate; granular | lithium boranate | Borate(1-),tetrahydroxy-,lithium,hexahydrate(9ci) | lithium s

Spezifikationen & Reinheit

ACS, ≥98%

Anmeldung

Lithium metaborate fusion can be used for the preparation of geological materials. The fusion of rock samples with LMB results in the formation of glasses that are easily soluble in dilute acids. This method allows the preparation of whole-rock solutions

Storage

Room temperature,Argon charged,Desiccated

Verschickt in

Normal

Note

ACS

Reinheit

≥98%

Namen und Kennungen

• Pubchem Sid: 508812437
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/508812437
• Kanonisches Lächeln: [Li+].B(=O)[O-]
• IUPAC Name: lithium;oxido(oxo)borane
• InChIKey: HZRMTWQRDMYLNW-UHFFFAOYSA-N
• INCHI: 1S/BO2.Li/c2-1-3;/q-1;+1
• Isomere SMILES: [Li+].B(=O)[O-]
• WGK Deutschland: 1
• Molekulargewicht: 49.75
• Reaxy-Rn: 14934829
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=14934829&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Mixed metal/non-metal compounds
    • Klasse Metalloid organides
      • Subclass Metalloid oxides

• Kingdom: Inorganic compounds
• Superclass: Mixed metal/non-metal compounds
• Klasse: Metalloid organides
• Subclass: Metalloid oxides
• Intermediate Tree Nodes: Not available
• Direct Parent: Metalloid oxides
• Alternative Parents: Metalloid salts Inorganic oxides Inorganic lithium salts
• Molecular Framework: Not available
• Substituents: Metalloid oxide - Inorganic lithium salt - Inorganic oxide - Inorganic salt - Inorganic metalloid salt
• Beschreibung: This compound belongs to the class of inorganic compounds known as metalloid oxides. These are inorganic compounds containing an oxygen atom of an oxidation state of -2, in which the heaviest atom bonded to the oxygen is a metalloid.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemische und physikalische Eigenschaften

• Löslichkeit: Soluble in water (25.7 mg/ml at 20 °C)
• Empfindlichkeit: Moisture sensitive
• Schmelzpunkt (°C): 845 °C
• Molekulargewicht: 49.800 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 50.0151 Da
• Monoisotopic Mass: 50.0151 Da
• Topological Polar Surface Area: 40.100 Ų
• Heavy Atom Count: 4
• Formal Charge: 0
• Complexity: 13.500
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

Referenzen

1. Zhengshan Yang, Huayi Yin, Bowen Deng, Dihua Wang.  (2023)  Electrolyte engineering for efficient molten-carbonate electrolysis of CO2.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2023.145146]

2. Xiaoqing Zhang, Jianwei Xiong, Fengzhen Chang, Zhuijun Xu, Zheng Wang, Philip Hall, Ya-Jun Cheng, Yonggao Xia.  (2022)  Sol/Antisolvent Coating for High Initial Coulombic Efficiency and Ultra-stable Mechanical Integrity of Ni-Rich Cathode Materials.  ACS Applied Materials & Interfaces,      [PMID:36166735] [10.1021/acsami.2c10613]

3. Tao Zhang, Liwei Zhuang, Dan Li, Lingzong Meng, Tianlong Deng, Yafei Guo, Yong Ma.  (2022)  Solid–Liquid Phase Equilibria and Boron Species Distribution in the Quaternary System LiCl–LiBO2–Li2B4O7–H2O at T = 323.15 K and P = 0.1 MPa.  JOURNAL OF CHEMICAL AND ENGINEERING DATA,      [PMID:] [10.1021/acs.jced.2c00261]

4. Lingyan Gui, Dongdong Li, Jiangtao Wu, Xianyang Meng.  (2022)  Apparent molar heat capacities of aqueous solutions of LiBO2, NaBO2, KBO2, Na2B4O7 and K2B4O7 at T = (298.12, 313.13 and 328.14) K using a Picker flow calorimeter.  JOURNAL OF CHEMICAL THERMODYNAMICS,      [PMID:] [10.1016/j.jct.2022.106879]

5. Zhao Liangcheng, Wei Li, Hu Yanqiao, Chen Qingzhi, Cheng Wencui, Zhang Jinming, Li Xing, An Ziyi, Meng Jianwei, Liu Huajie.  (2021)  Optimization of Lithium Metaborate Fusion and Post-ultrasonic Extraction for Multi-element Determination in Graphite by ICP-AES.  ANALYTICAL SCIENCES,  37  (12): (1735-1740).  [PMID:34148920] [10.2116/analsci.20P441]

6. Tao Zhang, Lan Yang, Dan Li, Lingzong Meng, Yafei Guo, Tianlong Deng.  (2021)  Thermodynamic properties and thermodynamic modelling for aqueous mixed system containing lithium metaborate and sodium metaborate.  JOURNAL OF CHEMICAL THERMODYNAMICS,      [PMID:] [10.1016/j.jct.2021.106446]

7. Lan Yang, Lele Chen, Tao Zhang, Dan Li, Lingzong Meng, Tianlong Deng, Yafei Guo.  (2020)  Solubility determination and thermodynamic modeling of solid−liquid equilibria in the LiBO2−Li2B4O7−H2O system at 298.15 K and 323.15 K.  FLUID PHASE EQUILIBRIA,      [PMID:] [10.1016/j.fluid.2020.112783]

8. Hainan Bai, Jiulin Hu, Xiaoguang Li, Yusen Duan, Feng Shao, Takahiro Kozawa, Makio Naito, Jingxian Zhang.  (2018)  Influence of LiBO2 addition on the microstructure and lithium-ion conductivity of Li1+xAlxTi2−x(PO4)3(x = 0.3) ceramic electrolyte.  CERAMICS INTERNATIONAL,      [PMID:] [10.1016/j.ceramint.2018.01.058]

9. Sun Haofeng, Wang Minghao, Li Wenjie, Liu Yang, Sun Xinyu, Wang Wenjie, Guo Yuqiao, Xie Yi, Wu Changzheng.  (2025)  2D free-standing ultra-large ferromagnetic nanosheets via a topotactic transformation strategy.  Science China-Chemistry,      [PMID:] [10.1007/s11426-024-2340-0]

10. Lei Shi, Chunlin He, Xinsheng Li.  (2025)  Highly effective and selective recovery of scandium using high-surface area silica prepared from calcium silicate hydrate.  JOURNAL OF RARE EARTHS,      [PMID:] [10.1016/j.jre.2025.02.011]

11. Hongyu Qi, Jiaxin Han, Lin Xing, Jia Xu, Yushan Liu, Xun Wang, Tao Zhang, Yong Ma, Lingzong Meng.  (2025)  Solid and Liquid Phase Equilibrium in the Quinary System LiCl–Li2SO4–LiBO2–Li2B4O7–H2O at 323.15 K.  JOURNAL OF CHEMICAL AND ENGINEERING DATA,      [PMID:] [10.1021/acs.jced.5c00204]

12. Bailin Chen, Yansheng Jiang, Hangwei Jia, Shuai An, Xueling Hou, Shilie Pan.  (2026)  NH4B3PO6(OH)3: A Hydroxyborophosphate with Short DUV Cutoff Edge and Large Birefringence.  INORGANIC CHEMISTRY,      [PMID:41892393] [10.1021/acs.inorgchem.6c00827]