Nysted Reagent - 20 wt. % suspension in THF , CAS No.41114-59-4

CAS: 41114-59-4 Cat. No.: N124096 Summenformel: C₆H₁₂Br₂OZn₃ Molekulargewicht: 456.14

GRADE & PURITY 20 wt. % suspension in THF

Synonyms

DTXSID1061071 | EINECS 212-042-9 | AMY1250 | (trimethylsilyl)ethene | V0067 | Vinyltrimethylsilane, >=99.5% | MFCD00008606 | NSC 93553 | BP-21122 | NSC-115430 | C.I. Disperse Blue 73 | NSC93553 | NSC-93553 | hydroxyisocaproic acid | J-525108 | A851124 | N

Storage

Room temperature,Desiccated

Shipped In

Normal

Übersicht

Reactant for:

· Synthesis of amphidinolide T3 using a ring-closing metathesis and asymmetric dihydroxylation strategy

· Methylenation of carbonyl compounds

· Olefination reactions

Useful reagent for the methylenation of ketones and α-ketols.

Specifications

Synonyme

DTXSID1061071 | EINECS 212-042-9 | AMY1250 | (trimethylsilyl)ethene | V0067 | Vinyltrimethylsilane, >=99.5% | MFCD00008606 | NSC 93553 | BP-21122 | NSC-115430 | C.I. Disperse Blue 73 | NSC93553 | NSC-93553 | hydroxyisocaproic acid | J-525108 | A851124 | N

Spezifikationen & Reinheit

20 wt. % suspension in THF

Storage

Room temperature,Desiccated

Verschickt in

Normal

Namen und Kennungen

Pubchem Sid

508811003

Pubchem Sid Url

https://pubchem.ncbi.nlm.nih.gov/substance/508811003

Kanonisches Lächeln

C[Si](C)(C)C=C

IUPAC Name

ethenyl(trimethyl)silane

InChIKey

GCSJLQSCSDMKTP-UHFFFAOYSA-N

INCHI

1S/C5H12Si/c1-5-6(2,3)4/h5H,1H2,2-4H3

Isomere SMILES

C[Si](C)(C)C=C

WGK Deutschland

3

Alternative CAS-Nummer

41114-59-4

Molekulargewicht

456.14

Reaxy-Rn

956572

Reaxys-RN_link_address

https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=956572&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organometallic compounds
    • Klasse Organometalloid compounds
      • Subclass Organosilicon compounds
        • Ebene5 Alkylsilanes
          • Ebene6 Trialkylsilanes

• Kingdom: Organic compounds
• Superclass: Organometallic compounds
• Klasse: Organometalloid compounds
• Subclass: Organosilicon compounds
• Intermediate Tree Nodes: Alkylsilanes
• Direct Parent: Trialkylsilanes
• Alternative Parents: Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Trialkylsilane - Hydrocarbon derivative - Aliphatic acyclic compound
• Beschreibung: This compound belongs to the class of organic compounds known as trialkylsilanes. These are organosilicon compounds containing exactly one alkyl chain attached to the silicon atom.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemische und physikalische Eigenschaften

• Empfindlichkeit: Air & Moisture Sensitive
• Flammpunkt (°F): -14.8 °F
• Flammpunkt (°C): -26°C
• Molekulargewicht: 100.230 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 100.071 Da
• Monoisotopic Mass: 100.071 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 6
• Formal Charge: 0
• Complexity: 49.400
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3