Nysted Reagent - 20 wt. % suspension in THF , CAS No.41114-59-4

CAS: 41114-59-4 Cat. No.: N124096 Molecular Weight: 456.14

GRADE & PURITY 20 wt. % suspension in THF

Synonyms

DTXSID1061071 | EINECS 212-042-9 | AMY1250 | (trimethylsilyl)ethene | V0067 | Vinyltrimethylsilane, >=99.5% | MFCD00008606 | NSC 93553 | BP-21122 | NSC-115430 | C.I. Disperse Blue 73 | NSC93553 | NSC-93553 | hydroxyisocaproic acid | J-525108 | A851124 | N

Storage

Room temperature,Desiccated,Cool

Shipped In

Normal

Overview

Reactant for:

· Synthesis of amphidinolide T3 using a ring-closing metathesis and asymmetric dihydroxylation strategy

· Methylenation of carbonyl compounds

· Olefination reactions

Useful reagent for the methylenation of ketones and α-ketols.

Specifications

Synonyms

DTXSID1061071 | EINECS 212-042-9 | AMY1250 | (trimethylsilyl)ethene | V0067 | Vinyltrimethylsilane, >=99.5% | MFCD00008606 | NSC 93553 | BP-21122 | NSC-115430 | C.I. Disperse Blue 73 | NSC93553 | NSC-93553 | hydroxyisocaproic acid | J-525108 | A851124 | N

Specifications & Purity

20 wt. % suspension in THF

Storage

Room temperature, Desiccated, Cool

Shipped In

Normal

Names and Identifiers

• Canonical Smiles: C[Si](C)(C)C=C
• IUPAC Name: ethenyl(trimethyl)silane
• InChIKey: GCSJLQSCSDMKTP-UHFFFAOYSA-N
• INCHI: 1S/C5H12Si/c1-5-6(2,3)4/h5H,1H2,2-4H3
• Isomeric SMILES: C[Si](C)(C)C=C
• WGK Germany: 3
• Alternate CAS: 41114-59-4
• Molecular Weight: 456.14
• Reaxy-Rn: 956572
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=956572&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organometallic compounds
    • Class Organometalloid compounds
      • Subclass Organosilicon compounds
        • Level5 Alkylsilanes
          • Level6 Trialkylsilanes

• Kingdom: Organic compounds
• Superclass: Organometallic compounds
• Class: Organometalloid compounds
• Subclass: Organosilicon compounds
• Intermediate Tree Nodes: Alkylsilanes
• Direct Parent: Trialkylsilanes
• Alternative Parents: Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Trialkylsilane - Hydrocarbon derivative - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as trialkylsilanes. These are organosilicon compounds containing exactly one alkyl chain attached to the silicon atom.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Sensitivity: Air & Moisture Sensitive
• Flash Point(°F): -14.8 °F
• Flash Point(°C): -26°C
• Molecular Weight: 100.230 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 100.071 Da
• Monoisotopic Mass: 100.071 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 6
• Formal Charge: 0
• Complexity: 49.400
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3