Sodium phosphomolybadate hydrate - AR, used for Reactant for synthesis of: Supramolecular hydrogen-bonded Archimedean cages with encapsulated organic and inorganic species Reactant for: Temperature programmed reduction and hydrogen-isotope exchange Passiv

CAS: 1313-30-0 Cat. No.: S101321 Summenformel: Na₃PO₄·12MoO₃•xH₂O Molekulargewicht: 1891.20 (anhydrous basis) EG-Nummer: 215-206-8

GRADE & PURITY AR

Synonyms

Sodium phosphomolybdate | MOLYBDATE(3-), TETRACOSA-.MU.-OXODODECAOXO(.MU.12-(PHOSPHATO(3-)-.KAPPA.O:.KAPPA.O:.KAPPA.O:.KAPPA.O':.KAPPA.O':.KAPPA.O':.KAPPA.O'':.KAPPA.O'':.KAPPA.O'':.KAPPA.O''':.KAPPA.O''':.KAPPA.O'''))DODECA-, SODIUM (1:3) | SODIUM PHOSPH

Storage

Room temperature

Shipped In

Normal

Specifications

Synonyme

Sodium phosphomolybdate | MOLYBDATE(3-), TETRACOSA-.MU.-OXODODECAOXO(.MU.12-(PHOSPHATO(3-)-.KAPPA.O:.KAPPA.O:.KAPPA.O:.KAPPA.O':.KAPPA.O':.KAPPA.O':.KAPPA.O'':.KAPPA.O'':.KAPPA.O'':.KAPPA.O''':.KAPPA.O''':.KAPPA.O'''))DODECA-, SODIUM (1:3) | SODIUM PHOSPH

Spezifikationen & Reinheit

AR

Anmeldung

Reactant for synthesis of: Supramolecular hydrogen-bonded Archimedean cages with encapsulated organic and inorganic species Reactant for: Temperature programmed reduction and hydrogen-isotope exchange Passivation of stainless steel Used for: Plastic membr

Storage

Room temperature

Verschickt in

Normal

Note

AR

Namen und Kennungen

• Pubchem Sid: 488202508
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/488202508
• Kanonisches Lächeln: [O-]P(=O)([O-])[O-].O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.[Na+].[Na+].[Na+]
• IUPAC Name: trisodium;trioxomolybdenum;phosphate
• InChIKey: TXYKAWLFCATKDB-UHFFFAOYSA-K
• INCHI: 1S/12Mo.3Na.H3O4P.36O/c;;;;;;;;;;;;;;;1-5(2,3)4;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/h;;;;;;;;;;;;;;;(H3,1,2,3,4);;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/q;;;;;;;;;;;;3*+1;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/p-3
• Isomere SMILES: [O-]P(=O)([O-])[O-].O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.[Na+].[Na+].[Na+]
• WGK Deutschland: 2
• RTECS: WD6600000
• UN-Nummer: 3084
• Molekulargewicht: 1891.20 (anhydrous basis)

Chemische und physikalische Eigenschaften

• Löslichkeit: Easily soluble in water.
• Empfindlichkeit: light sensitive
• Schmelzpunkt (°C): 98°C

Referenzen

1. Kaixin Li, Lizhen Huang, Yao Zhang, Ziteng Zhu, Jun Zhao, Guang-Jie Xia, Yonggang Min.  (2023)  Ionic Liquid/Polyoxometalate Hybrid Catalyst with Tunable Functionalities for Boosting the Selectively Oxidative Transformation of Biobased Carbohydrates.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/acs.iecr.3c02496]

2. Zhiyong Zhou, Haotian Liu, Jiahui Fan, Xueting Liu, Yafei Hu, Yulei Hu, Yong Wang, Zhongqi Ren.  (2019)  Selective Extraction of Lithium Ion from Aqueous Solution with Sodium Phosphomolybdate As a Coextraction Agent.  ACS Sustainable Chemistry & Engineering,      [PMID:] [10.1021/acssuschemeng.9b00898]

3. Sheng Zhu, Xiaoxin Yang, Lan Li, Xiao Wang, Gaoyi Han.  (2024)  Confined grotthuss proton-conduction along polyoxometalate chains inside carbon nanotubes for high-rate charge storage.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.150744]

4. He Xun, Yao Yongchao, Zhang Min, Zhou Yilei, Zhang Limei, Ren Yuchun, Dong Kai, Tang Hong, Nan Jue, Zhou Xingli, Luo Han, Ying Binwu, Yu Qi, Luo Fengming, Tang Bo, Sun Xuping.  (2025)  Engineered PW12-polyoxometalate docked Fe sites on CoFe hydroxide anode for durable seawater electrolysis.  Nature Communications,  16  (1): (1-11).  [PMID:40593508] [10.1038/s41467-025-60620-9]