Trifluoromethanesulfonic anhydride - ≥98% , CAS No.358-23-6

CAS: 358-23-6 Cat. No.: T106649 Peso molecular: 282.14 Beilstein Registry Number: 1813600 Número EC: 206-616-8
Disponible para pedir
GRADE & PURITY ≥98%
Synonyms
EN300-50306 | MFCD00000408 | trifluoromethylsulfonic acid anhydride | trifluoro methanesulfonic anhydride | trifluoromethanesulfonic acid anhydride | trifluoro-methanesulfonic acid anhydride | trifluoromethane-sulfonic acid anhydride | UNII-8W034LHG1U | 1
Storage
Store at 2-8°C,Argon charged
Shipped In
Wet ice
 ·  off list, applied to all prices below.
Size
Estado
Price
Qty
5g
T106649-5g
1
12,90US$
25g
T106649-25g
1

26,90US$

45,90US$
Guardar 19,00 US$ (41.39%)
50g
T106649-50g
1

47,90US$

79,90US$
Guardar 32,00 US$ (40.05%)
100g
T106649-100g
8-12 wks(?) Production requires sourcing of materials. We appreciate your patience and understanding.

85,90US$

119,90US$
Guardar 34,00 US$ (28.36%)
500g
T106649-500g
1
399,90US$
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Why this grade

≥98% for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

🌡

Storage & shipping

Store at 2-8°C,Argon charged Ships Wet ice Check lot-specific COA for exact specifications.

📋

Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

📚

Literature proof

Cited in 12 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Descripción general

Widely used reagent for the synthesis of alkyl and vinyl triflates. Catalyst for glycosylation for synthesis of polysaccharides Reagent for stereoselective synthesis of mannosazide methyl uronate donors Activator for direct glycosylation with anomeric hydroxy sugars

Specifications

Sinónimos
EN300-50306 | MFCD00000408 | trifluoromethylsulfonic acid anhydride | trifluoro methanesulfonic anhydride | trifluoromethanesulfonic acid anhydride | trifluoro-methanesulfonic acid anhydride | trifluoromethane-sulfonic acid anhydride | UNII-8W034LHG1U | 1
Especificaciones y pureza
≥98%
Condiciones de almacenamiento de almacenamiento
Store at 2-8°C, Argon charged
Enviado en
Wet ice
Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.
Pureza
≥98%
Nombres e identificadores
Sonrisas canónicasC(F)(F)(F)S(=O)(=O)OS(=O)(=O)C(F)(F)F
IUPAC Nametrifluoromethylsulfonyl trifluoromethanesulfonate
InChIKeyWJKHJLXJJJATHN-UHFFFAOYSA-N
INCHI1S/C2F6O5S2/c3-1(4,5)14(9,10)13-15(11,12)2(6,7)8
Isómeros SMILES C(F)(F)(F)S(=O)(=O)OS(=O)(=O)C(F)(F)F
WGK Alemania 3
Número ONU 3265
Grupo de embalaje II
Peso molecular 282.14
Beilstein 1813600
Reaxy-Rn 1813600

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

Download SDS →

✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

Look up COA →

📊 Datasheet

Quick-reference summary of product specifications and applications.

View datasheet →

🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

View spec sheet →

Advanced Data

Taxonomic Classification

Taxonomy Tree

KingdomOrganic compounds
SuperclassOrganic acids and derivatives
ClaseOrganic sulfonic acids and derivatives
SubclassOrganosulfonic acids and derivatives
Intermediate Tree Nodes Alkanesulfonic acids and derivatives - Alkanesulfonic acids
Direct ParentTrifluoromethanesulfonates
Alternative Parents Organosulfonic anhydrides  Sulfonyls  Methanesulfonates  Trihalomethanes  Organofluorides  Organic oxides  Hydrocarbon derivatives  Alkyl fluorides  
Molecular FrameworkAliphatic acyclic compounds
Substituents Trifluoromethanesulfonate - Organosulfonic anhydride - Sulfonyl - Methanesulfonate - Trihalomethane - Organic oxygen compound - Organic oxide - Halomethane - Hydrocarbon derivative - Organosulfur compound - Organofluoride - Organohalogen compound - Alkyl halide - Alkyl fluoride - Aliphatic acyclic compound
DescripciónThis compound belongs to the class of organic compounds known as trifluoromethanesulfonates. These are alkanesulfonic acids, that contain a sulfonate group that is substituted with a trifluoromethyl group.
External Descriptors organosulfonic anhydride
Estructura 3D
Modelo de Estructura Química Interactiva





Certificados (CoA, COO, BSE/TSE y tabla de análisis)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

58 results found

Lot NumberCertificate TypeFechaArticulo
H2423140Certificate of AnalysisJun 09, 2026 T106649
A2623273Certificate of AnalysisJan 16, 2026 T106649
A2623274Certificate of AnalysisJan 16, 2026 T106649
A2623292Certificate of AnalysisJan 16, 2026 T106649
A2623293Certificate of AnalysisJan 16, 2026 T106649
K2503227Certificate of AnalysisOct 22, 2025 T106649
J2531596Certificate of AnalysisOct 22, 2025 T106649
J2531595Certificate of AnalysisOct 22, 2025 T106649
J2531594Certificate of AnalysisOct 22, 2025 T106649
J2531475Certificate of AnalysisOct 22, 2025 T106649
H2504704Certificate of AnalysisJul 25, 2025 T106649
H2504702Certificate of AnalysisJul 25, 2025 T106649
H2504703Certificate of AnalysisJul 25, 2025 T106649
H2504705Certificate of AnalysisJul 25, 2025 T106649
H2504706Certificate of AnalysisJul 25, 2025 T106649
G2504055Certificate of AnalysisMay 21, 2025 T106649
G2504054Certificate of AnalysisMay 21, 2025 T106649
G2504052Certificate of AnalysisMay 21, 2025 T106649
F2506691Certificate of AnalysisMay 21, 2025 T106649
F2506690Certificate of AnalysisMay 21, 2025 T106649
F2506689Certificate of AnalysisMay 21, 2025 T106649
F2506688Certificate of AnalysisMay 21, 2025 T106649
F2506658Certificate of AnalysisMay 21, 2025 T106649
F2511026Certificate of AnalysisMar 19, 2025 T106649
C2528553Certificate of AnalysisMar 19, 2025 T106649
C2528552Certificate of AnalysisMar 19, 2025 T106649
C2528551Certificate of AnalysisMar 19, 2025 T106649
C2528550Certificate of AnalysisMar 19, 2025 T106649
C2528549Certificate of AnalysisMar 19, 2025 T106649
B2510637Certificate of AnalysisJan 21, 2025 T106649
B2510638Certificate of AnalysisJan 21, 2025 T106649
B2510636Certificate of AnalysisJan 21, 2025 T106649
B2510634Certificate of AnalysisJan 21, 2025 T106649
B2510632Certificate of AnalysisJan 21, 2025 T106649
B2510649Certificate of AnalysisJan 21, 2025 T106649
B2510631Certificate of AnalysisJan 21, 2025 T106649
B2510630Certificate of AnalysisJan 21, 2025 T106649
B2510629Certificate of AnalysisJan 21, 2025 T106649
B2510628Certificate of AnalysisJan 21, 2025 T106649
K2420153Certificate of AnalysisAug 15, 2024 T106649
A2509064Certificate of AnalysisAug 15, 2024 T106649
H2423142Certificate of AnalysisAug 15, 2024 T106649
H2423141Certificate of AnalysisAug 15, 2024 T106649
H2423143Certificate of AnalysisAug 15, 2024 T106649
H2423139Certificate of AnalysisAug 15, 2024 T106649
G2102266Certificate of AnalysisJan 04, 2024 T106649
I2311016Certificate of AnalysisJul 15, 2022 T106649
K2328100Certificate of AnalysisJul 15, 2022 T106649
K2328098Certificate of AnalysisJul 15, 2022 T106649
E2304506Certificate of AnalysisJul 15, 2022 T106649
A2422186Certificate of AnalysisJul 15, 2022 T106649
I2202948Certificate of AnalysisJul 15, 2022 T106649
I2202947Certificate of AnalysisJul 15, 2022 T106649
I2202946Certificate of AnalysisJul 15, 2022 T106649
I2202945Certificate of AnalysisJul 15, 2022 T106649
I2202944Certificate of AnalysisJul 15, 2022 T106649
F2230301Certificate of AnalysisJul 13, 2022 T106649
F2230298Certificate of AnalysisJul 07, 2022 T106649

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Propiedades químicas y físicas
SolubilidadMiscible with dichloromethane. Immiscible with hydrocarbons.
SensibilidadHeat sensitive,Hygroscopic
Índice de refracción1.32-1.323
Punto de inflamación (°C)110°C
Punto de ebullición (°C)81~84℃
Punto de fusión (°C)-80°C
Peso molecular282.140 g/mol
XLogP31.600
Hydrogen Bond Donor Count0
Hydrogen Bond Acceptor Count11
Rotatable Bond Count2
Exact Mass281.909 Da
Monoisotopic Mass281.909 Da
Topological Polar Surface Area94.300 Ų
Heavy Atom Count15
Formal Charge0
Complexity370.000
Isotope Atom Count0
Defined Atom Stereocenter Count0
Undefined Atom Stereocenter Count0
Defined Bond Stereocenter Count0
Undefined Bond Stereocenter Count0
The total count of all stereochemical bonds0
Covalently-Bonded Unit Count1
Preguntas frecuentes y artículos
Citations of This Product
Referencias
1. Bohong Yu, Yubo Liu, Yingxi Zhang, Linyi Xu, Kai Jin, Andi Sun, Xiuli Zhao, Yongjun Wang, Hongzhuo Liu.  (2023)  An SS31-rapamycin conjugate via RBC hitchhiking for reversing acute kidney injury.  BIOMATERIALS,      [PMID:37939640] [10.1016/j.biomaterials.2023.122383]
2. Zhang Yu, Zheng Jianzhi, Li Xijuan, Wu Ying, Zhang Ke.  (2023)  Stoichiometric Imbalance-promoted Step-growth Polymerization Based on Self-accelerating Three-component Reaction.  CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,  39  (5): (822-828).  [PMID:] [10.1007/s40242-023-3173-3]
3. Tao Sun, Qinjun Chen, Zheng Zhou, Chao Li, Teng Yu, Chen Jiang.  (2023)  A chemiluminescent reporter assisted by in-situ neutrophils for imaging O2− at inflammatory sites.  JOURNAL OF CONTROLLED RELEASE,      [PMID:37100207] [10.1016/j.jconrel.2023.04.035]
4. Chenfang Sun, Guangyuan Feng, Yaru Song, Shanshan Cheng, Shengbin Lei, Wenping Hu.  (2022)  Single Molecule Level and Label-Free Determination of Multibiomarkers with an Organic Field-Effect Transistor Platform in Early Cancer Diagnosis.  ANALYTICAL CHEMISTRY,      [PMID:35446018] [10.1021/acs.analchem.2c00897]
5. Rui Li, Xiaoqing Yin, Shiyi Zhang, Jinchu Yang, Mingqin Zhao.  (2021)  Preparation and pyrolysis of two Amadori analogues as flavor precursors.  JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS,      [PMID:] [10.1016/j.jaap.2021.105357]
6. Yudi Feng, Ke Jin, Jia Guo, Changchun Wang.  (2021)  All-carbocycle hydrocarbon thermosets with high thermal stability and robust mechanical strength for low-k interlayer dielectrics.  Polymer Chemistry,  12  (33): (4812-4821).  [PMID:] [10.1039/D1PY00877C]
7. Hua-Ming Xiao, Shuai Zhao, Ru-Ting Fan, Dilshad Hussain, Xian Wang.  (2021)  Simultaneous determination of short-chain fatty alcohols in aged oil and biodiesels by stable isotope labeling assisted liquid chromatography-mass spectrometry.  TALANTA,      [PMID:33838765] [10.1016/j.talanta.2021.122223]
8. Qingping Xin, Tianyu Liu, Zhao Li, Shaofei Wang, Yifan Li, Zhen Li, Jingyi Ouyang, Zhongyi Jiang, Hong Wu.  (2015)  Mixed matrix membranes composed of sulfonated poly(ether ether ketone) and a sulfonated metal–organic framework for gas separation.  JOURNAL OF MEMBRANE SCIENCE,      [PMID:] [10.1016/j.memsci.2015.03.060]
9. Zhen Li, Guangwei He, Yuning Zhao, Ying Cao, Hong Wu, Yifan Li, Zhongyi Jiang.  (2014)  Enhanced proton conductivity of proton exchange membranes by incorporating sulfonated metal-organic frameworks.  JOURNAL OF POWER SOURCES,      [PMID:] [10.1016/j.jpowsour.2014.03.123]
10. Yuanqing Fu, Shan Hong, Duo Li, Songbai Liu.  (2013)  Novel Chemical Synthesis of Ginkgolic Acid (13:0) and Evaluation of Its Tyrosinase Inhibitory Activity.  JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY,      [PMID:23701207] [10.1021/jf4012642]
11. Na Li, Jian Gao, Hongzhe Ni, Jialin Zhao, Kuirong Feng, Jingyi Wu, Yijia Lei, Yan Wang, Jiayao Yang, Shiyao Sun, Zhe Wang.  (2024)  Fluorinated Poly(thiophene-based aryl piperidinium) Anion-Exchange Membranes Containing Dual Cation–Dipole Interactions for Alkaline Fuel Cells.  ACS Sustainable Chemistry & Engineering,      [PMID:] [10.1021/acssuschemeng.4c02735]
12. Liu Mu-Han, Sun Wei-Ting, Yang An-Qi, Wang Zhi, Chang Zong, Wang Ai-E, Huang Pei-Qiang.  (2025)  Streamlined synthesis of α-keto-, α-hydroxy- and α,α-difluorophosphonates from amides via electrophilic activation with trifluoromethanesulfonic anhydride.  Science China-Chemistry,      [PMID:] [10.1007/s11426-025-2935-3]
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