Triruthenium dodecacarbonyl - ≥99% , CAS No.15243-33-1

CAS: 15243-33-1 Cat. No.: T113584 Peso molecular: 639.33 Número EC: 239-287-4 PubChem CID: 6096991

GRADE & PURITY ≥99%

Synonyms

Umicore DeRu37 | SY009926 | T71827 | Triruthenium dodecacarbonyl, 99% | AKOS015916383 | Q2115937 | Ru3 (CO)12 | DODECACARBONYLTRIRUTHENIUM;DODECACARBONYLTRIRUTHENIUM (0);RUTHENIUM CARBONYL;TRIRUTHENIUM DODECACARBONYL | dodecakis(methanidylidyneoxidanium)

Storage

Room temperature,Desiccated,Cool

Shipped In

Normal

Descripción general

Carbonyl cluster precursor and H-transfer catalyst.

Product class

Homogeneous Catalysts, Electronic Materials, PGM based Electronic Materials, M-(CO)

Reaction type

Carbonylation, Decarboxylation, Hydroamination

Chemical properties

Chemical formula

C12O12Ru3

Empirical formula

Ru3(CO)12

Molecular weight

639.33

Metal

Ru

Theoretical metal content

47

Physical state

crystalline

Color

orange

Specifications

Sinónimos

Umicore DeRu37 | SY009926 | T71827 | Triruthenium dodecacarbonyl, 99% | AKOS015916383 | Q2115937 | Ru3 (CO)12 | DODECACARBONYLTRIRUTHENIUM;DODECACARBONYLTRIRUTHENIUM (0);RUTHENIUM CARBONYL;TRIRUTHENIUM DODECACARBONYL | dodecakis(methanidylidyneoxidanium)

Especificaciones y pureza

≥99%

Condiciones de almacenamiento de almacenamiento

Room temperature, Desiccated, Cool

Enviado en

Normal

Pureza

≥99%

Nombres e identificadores

• Pubchem Sid: 488195667
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/488195667
• Sonrisas canónicas: Ru.Ru.Ru.C-#O+.C-#O+.C-#O+.C-#O+.C-#O+.C-#O+.C-#O+.C-#O+.C-#O+.C-#O+.C-#O+.C-#O+
• InChIKey: NQZFAUXPNWSLBI-UHFFFAOYSA-N
• INCHI: 1S/12CO.3Ru/c12*1-2
• Isómeros SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Ru].[Ru].[Ru]
• WGK Alemania: 3
• PubChem CID: 6096991
• Peso molecular: 639.33
• Reaxy-Rn: 14281346

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic salts
    • Clase Organic metal salts
      • Subclass Organic transition metal salts

• Kingdom: Organic compounds
• Superclass: Organic salts
• Clase: Organic metal salts
• Subclass: Organic transition metal salts
• Intermediate Tree Nodes: Not available
• Direct Parent: Organic transition metal salts
• Alternative Parents: Organic oxygen compounds Hydrocarbon derivatives Organic cations
• Molecular Framework: Not available
• Substituents: Organic transition metal salt - Organic oxygen compound - Hydrocarbon derivative - Organic cation - Aliphatic acyclic compound
• Descripción: This compound belongs to the class of organic compounds known as organic transition metal salts. These are organic salt compounds containing a transition metal atom in its ionic form.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone.
• Punto de fusión (°C): 150°C
• Peso molecular: 639.300 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 0
• Exact Mass: 642.654 Da
• Monoisotopic Mass: 641.652 Da
• Topological Polar Surface Area: 12.000 Ų
• Heavy Atom Count: 27
• Formal Charge: 0
• Complexity: 10.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 15

XLogP3

Referencias

1. Rong Fu, Yan Wang, Guangming Wang, Qingyun Zhan, Lili Zhang, Le Liu.  (2023)  Defective ZrO2−x supported Ru nanoparticles as a Mott–Schottky photocatalyst for efficient ammonia synthesis under ambient conditions.  GREEN CHEMISTRY,  25  (21): (8531-8538).  [PMID:] [10.1039/D3GC02130K]

2. Chen Xinfeng, Peng Chengdong, Dan Wenyan, Yu Long, Wu Yinan, Fei Honghan.  (2022)  Bromo- and iodo-bridged building units in metal-organic frameworks for enhanced carrier transport and CO2 photoreduction by water vapor.  Nature Communications,  13  (1): (1-14).  [PMID:35933476] [10.1038/s41467-022-32367-0]

3. Qing Yang, Hanjiao Chen, Jing Hu, Ke Huang, Xiandeng Hou.  (2021)  Simultaneous Detection of Ruthenium and Osmium by Photochemical Vapor Generation-Inductively Coupled Plasma-Mass Spectrometry.  ANALYTICAL CHEMISTRY,      [PMID:34931811] [10.1021/acs.analchem.1c03357]

4. Wenfeng Han, Zhi Li, Huazhang Liu.  (2019)  La2Ce2O7 supported ruthenium as a robust catalyst for ammonia synthesis.  JOURNAL OF RARE EARTHS,      [PMID:] [10.1016/j.jre.2018.09.010]

5. Xiaozhong Zheng, Shuxin Zhang, Xinying Zheng, Zhongbin Zhuang, Mingxia Gao, Yongfeng Liu, Hongge Pan, Wenping Sun.  (2025)  Cluster-Scale Multisite Interface Reinforces Ruthenium-Based Anode Catalysts for Alkaline Anion Exchange Membrane Fuel Cells.  ADVANCED MATERIALS,      [PMID:40051236] [10.1002/adma.202502127]

6. Jin-Jian Pan, Jia Huang, Yuan-Hang Qin, Zhen Chen, Li Yang, Cun-Wen Wang, Xingmao Jiang.  (2024)  Deep eutectic solvent-assisted synthesis of oxygen vacancy-rich BaTiO3 as a support for Ru catalyst in ammonia synthesis at atmospheric pressure.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,      [PMID:] [10.1016/j.ijhydene.2024.05.176]

7. Wenxia Xu, Dan Zhang, Tiantian Wang, Jianping Lai, Lei Wang.  (2024)  Non-platinum-based electrocatalysts for high performance acidic hydrogen evolution reactions in proton exchange membrane water electrolysis.  APPLIED CATALYSIS B-ENVIRONMENTAL,      [PMID:] [10.1016/j.apcatb.2024.124626]

8. Yong Zhou, Yiyang Zhou, Jiamei Liu, Yanan Zhu, Bin Yang, Jian Lv, Bing Li, Xiaoyang Liu.  (2025)  Rapid synthesis of ultrafine Ru nanoparticles loaded on N-doped hollow mesoporous carbon spheres via a microwave method for electrocatalytic hydrogen evolution applications.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2025.162854]

9. Tianhua Zhang, Haihui Hu, Jiaxin Li, Yinglong Gao, Lingling Li, Mingyuan Zhang, Xuanbei Peng, Yanliang Zhou, Jun Ni, Bingyu Lin, Jianxin Lin, Bing Zhu, Dongshuang Wu, Linjie Zhang, Lili Han, Lirong Zheng, Xiuyun Wang, Lilong Jiang.  (2024)  Tuning clusters-metal oxide promoters electronic interaction of Ru-based catalyst for ammonia synthesis under mild conditions.  CHINESE JOURNAL OF CATALYSIS,      [PMID:] [10.1016/S1872-2067(23)64644-3]

10. Fengjuan Liu, Yan Zhang, Tingting Wang, Peng Jiang, Bei Liu, Yunxia Wen, Ning Qu, Jie Kong, Zhenchen Tang, Feng Zeng, Han Lin, Xiaohua Lu, Tuo Ji, Jiahua Zhu.  (2025)  Ru-doped SrXOy/CNT as microwave-responsive catalysts for low-temperature and atmospheric pressure ammonia synthesis.  CHEMICAL ENGINEERING SCIENCE,      [PMID:] [10.1016/j.ces.2025.122196]

11. Jingwei Du, Jinjun Li, Zhixiong You.  (2025)  Efficient catalytic ammonia synthesis using Cs-doped Ru/ZrO2 catalysts prepared via a low eutectic system.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,      [PMID:] [10.1016/j.ijhydene.2025.04.193]

12. Yong Zhou, Bin Yang, Bing Li, Xiaoyang Liu.  (2025)  Enhancing electrocatalytic hydrogen evolution efficiency: tuning catalyst support pore size to optimize hydrogen adsorption–desorption kinetics.  Inorganic Chemistry Frontiers,      [PMID:] [10.1039/D5QI00769K]

13. Yong Zhou, Yiyang Zhou, Jiamei Liu, Bin Yang, Yang Gao, Yingjie Hua, Bing Li, Xiaoyang Liu.  (2026)  Boosting Alkaline Hydrogen Evolution via Synergistic Reverse Hydrogen Spillover and Metal–Support Interactions in Ni–Ru Alloy Clusters on Nitrogen-Doped Carbon.  ACS Sustainable Chemistry & Engineering,      [PMID:] [10.1021/acssuschemeng.5c12448]