Trirutenio dodecacarbonilo - ≥99,95% metales base , CAS No.15243-33-1

CAS: 15243-33-1 Cat. No.: T294758 Peso molecular: 639.33 Número EC: 239-287-4 PubChem CID: 6096991

GRADE & PURITY ≥99.95% metals basis

Synonyms

Umicore DeRu37 | SY009926 | T71827 | Triruthenium dodecacarbonyl, 99% | AKOS015916383 | Q2115937 | Ru3 (CO)12 | DODECACARBONYLTRIRUTHENIUM;DODECACARBONYLTRIRUTHENIUM (0);RUTHENIUM CARBONYL;TRIRUTHENIUM DODECACARBONYL | dodecakis(methanidylidyneoxidanium)

Storage

Temperatura ambiente

Shipped In

Normal

Descripción general

Precursor de clústeres de carbonilo y catalizador de transferencia de H.

Clase de producto

Catalizadores homogéneos, materiales electrónicos, materiales electrónicos basados en PGM, M-(CO)

Tipo de reacción

Carbonilación, Descarboxilación, Hidroaminación

Specifications

Sinónimos

Umicore DeRu37 | SY009926 | T71827 | Triruthenium dodecacarbonyl, 99% | AKOS015916383 | Q2115937 | Ru3 (CO)12 | DODECACARBONYLTRIRUTHENIUM;DODECACARBONYLTRIRUTHENIUM (0);RUTHENIUM CARBONYL;TRIRUTHENIUM DODECACARBONYL | dodecakis(methanidylidyneoxidanium)

Especificaciones y pureza

≥99, 95% metales base

Información jurídica

Producto de Umicore

Condiciones de almacenamiento de almacenamiento

Temperatura ambiente

Enviado en

Normal

Pureza

≥99.95% metals basis

Nombres e identificadores

• Pubchem Sid: 504764009
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504764009
• Sonrisas canónicas: Ru.Ru.Ru.C-#O+.C-#O+.C-#O+.C-#O+.C-#O+.C-#O+.C-#O+.C-#O+.C-#O+.C-#O+.C-#O+.C-#O+
• InChIKey: NQZFAUXPNWSLBI-UHFFFAOYSA-N
• INCHI: 1S/12CO.3Ru/c12*1-2
• Isómeros SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Ru].[Ru].[Ru]
• WGK Alemania: 3
• PubChem CID: 6096991
• Peso molecular: 639.33
• Reaxy-Rn: 14281346

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic salts
    • Clase Organic metal salts
      • Subclass Organic transition metal salts

• Kingdom: Organic compounds
• Superclass: Organic salts
• Clase: Organic metal salts
• Subclass: Organic transition metal salts
• Intermediate Tree Nodes: Not available
• Direct Parent: Organic transition metal salts
• Alternative Parents: Organic oxygen compounds Hydrocarbon derivatives Organic cations
• Molecular Framework: Not available
• Substituents: Organic transition metal salt - Organic oxygen compound - Hydrocarbon derivative - Organic cation - Aliphatic acyclic compound
• Descripción: This compound belongs to the class of organic compounds known as organic transition metal salts. These are organic salt compounds containing a transition metal atom in its ionic form.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone.
• Punto de fusión (°C): 150°C
• Peso molecular: 639.300 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 0
• Exact Mass: 642.654 Da
• Monoisotopic Mass: 641.652 Da
• Topological Polar Surface Area: 12.000 Ų
• Heavy Atom Count: 27
• Formal Charge: 0
• Complexity: 10.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 15

XLogP3

Referencias

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2. Chen Xinfeng, Peng Chengdong, Dan Wenyan, Yu Long, Wu Yinan, Fei Honghan.  (2022)  Bromo- and iodo-bridged building units in metal-organic frameworks for enhanced carrier transport and CO2 photoreduction by water vapor.  Nature Communications,  13  (1): (1-14).  [PMID:35933476] [10.1038/s41467-022-32367-0]

3. Qing Yang, Hanjiao Chen, Jing Hu, Ke Huang, Xiandeng Hou.  (2021)  Simultaneous Detection of Ruthenium and Osmium by Photochemical Vapor Generation-Inductively Coupled Plasma-Mass Spectrometry.  ANALYTICAL CHEMISTRY,      [PMID:34931811] [10.1021/acs.analchem.1c03357]

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