[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium - Pd 14.5% , CAS No.72287-26-4

CAS: 72287-26-4 Cat. No.: D107566 Molecular Weight: 731.7 EC Number: 615-748-9

GRADE & PURITY Pd 14.5%

Synonyms

Umicore CX93 | Pd(dppf)Cl2

Storage

Room temperature,Argon charged

Shipped In

Normal

Overview

A catalyst for Suzuki and Stille couplings

Catalyst for C-C and C-N coupling reaction.

Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions:

· Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity. 

· Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives. 

· Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.

Product class

M-P, Homogeneous Catalysts, Bidentate Ligands, Ferrocenyl Ligands - Achiral

Reaction type

Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, C-H Activation, Carbonylation, Negishi Coupling Reaction, Stille Reaction, Suzuki-Miyaura Coupling Reaction, Oxidation

Chemical properties

Chemical formula

C34H28Cl2FeP2Pd

Empirical formula

[Pd(dppf)Cl2]

Molecular weight

731.71

Metal

Pd

Theoretical metal content

14

Physical state

crystalline

Color

red

Applications & references

Reductive carbonylation of aryl halides as an alternative and mild route for the introduction of aldehyde functionality, which is mostly desired for fine chemical and pharmaceutical intermediates to open up the wide range of further possible transformations.

Reference: Org. Proc. Res. Dev. 2007, 11, 39. (DOI: 10.1021/op060193w), Synthesis 1996, 470 (DOI: 10.1055/s-1996-4246)

High yielding Palladium catalyzed C-H arylation of electron-enriched heteroarenes with aryl bromides.

Reference: J. Org. Chem. 2010, 75, 6998. (DOI: 10.1021/jo101433g)

Specifications

Synonyms

Umicore CX93 | Pd(dppf)Cl2

Specifications & Purity

Pd 14.5%

Storage

Room temperature, Argon charged

Shipped In

Normal

Names and Identifiers

• WGK Germany: 3
• Molecular Weight: 731.7

Chemical and Physical Properties

• Solubility: Soluble in dichloromethane.
• Sensitivity: Air & Moisture sensitive.
• Melt Point(°C): 275-280°C

References

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