2-(Bromomethyl)naphthalene - ≥96% , CAS No.939-26-4

CAS: 939-26-4 Cat. No.: B102137 Molecular Weight: 221.09 Beilstein Registry Number: 636546 EC Number: 213-359-5

GRADE & PURITY ≥96%

Synonyms

2-BMN | 2-(Bromomethyl)naphthalene, 96% | AC-4571 | SCHEMBL44621 | 17CTW03UJP | FT-0608743 | DTXSID10239864 | Naphthalene, 2-(bromomethyl)- | 2-Bromomethyinaphthalene | 2-Menaphthyl bromide | 2-naphthyl methyl bromide | 2-Bromomethyl naphthalene | 2-Bromo

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Overview

2-(Bromomethyl)naphthalene (2-BMN) can be employed as a starting material in the synthesis of 2-(fluoromethyl)naphthalene , 2-naphthylmethyl azide , 2-naphthalenecarboxaldehyde , diselenide, bis(2-naphthalenylmethyl) , 1H-1,2,3-triazole, 4,4′-(1,4-phenylene)bis1-(2-naphthalenylmethyl).

Specifications

Synonyms

2-BMN | 2-(Bromomethyl)naphthalene, 96% | AC-4571 | SCHEMBL44621 | 17CTW03UJP | FT-0608743 | DTXSID10239864 | Naphthalene, 2-(bromomethyl)- | 2-Bromomethyinaphthalene | 2-Menaphthyl bromide | 2-naphthyl methyl bromide | 2-Bromomethyl naphthalene | 2-Bromo

Specifications & Purity

≥96%

Storage

Store at 2-8°C, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥96%

Names and Identifiers

• Pubchem Sid: 508807961
• Canonical Smiles: C1=CC=C2C=C(C=CC2=C1)CBr
• IUPAC Name: 2-(bromomethyl)naphthalene
• InChIKey: RUHJZSZTSCSTCC-UHFFFAOYSA-N
• INCHI: 1S/C11H9Br/c12-8-9-5-6-10-3-1-2-4-11(10)7-9/h1-7H,8H2
• Isomeric SMILES: C1=CC=C2C=C(C=CC2=C1)CBr
• WGK Germany: 3
• UN Number: 3261
• Molecular Weight: 221.09
• Beilstein: 636546
• Reaxy-Rn: 636546
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=636546&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Class Naphthalenes

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Class: Naphthalenes
• Subclass: Not available
• Intermediate Tree Nodes: Not available
• Direct Parent: Naphthalenes
• Alternative Parents: Organobromides Hydrocarbon derivatives Alkyl bromides
• Molecular Framework: Aromatic homopolycyclic compounds
• Substituents: Naphthalene - Hydrocarbon derivative - Organobromide - Organohalogen compound - Alkyl halide - Alkyl bromide - Aromatic homopolycyclic compound
• Description: This compound belongs to the class of organic compounds known as naphthalenes. These are compounds containing a naphthalene moiety, which consists of two fused benzene rings.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Soluble in water (reacts), and chloroform.
• Sensitivity: Moisture sensitive.heat sensitive
• Flash Point(°F): 230 °F
• Flash Point(°C): >110°C
• Boil Point(°C): 213°C/100mmHg
• Melt Point(°C): 51-54°C
• Molecular Weight: 221.090 g/mol
• XLogP3: 3.700
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 219.989 Da
• Monoisotopic Mass: 219.989 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 12
• Formal Charge: 0
• Complexity: 144.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

References

1. Jiangqin Lu, Shan Lu, Qinghua Cao, Juncheng Huang, Fei Liu, Haining Na, Jin Zhu, Zhen Jia.  (2022)  Dual modification of cellulose with esterification and carbonation in DMSO/DBU/CO2 system as fluorescent additive for pH detection.  CARBOHYDRATE RESEARCH,      [PMID:35820340] [10.1016/j.carres.2022.108630]

2. Cao Qinghua, Dai Jinyue, Bao Xin, Zhang Zhenyu, Liu Fei, Feng Yuhong, Na Haining, Zhu Jin.  (2021)  Preparation of cellulose-based fluorescent materials as coating pigment by use of DMSO/DBU/CO2 system.  CELLULOSE,  28  (16): (10373-10384).  [PMID:] [10.1007/s10570-021-04184-z]

3. Hong Wang, Jiwen Guan, Guangxian Xu, Xavier Mercier, Jinyang Zhang, Haotian Guo, Tongzhu Yu, Huaqiao Gui, Teng Huang, Donald G. Truhlar, Zhandong Wang.  (2025)  Resonance-stabilized radical clustering bridges the gap between gaseous precursors and soot in the inception stage.  PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA,  122  (18): (e2503292122).  [PMID:40299695] [10.1073/pnas.2503292122]