(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I) - ≥99.95% metals basis , CAS No.12245-39-5

CAS: 12245-39-5 Cat. No.: A284018 Molecular Weight: 310.19 EC Number: 634-150-9 PubChem CID: 10935795

GRADE & PURITY ≥99.95% metals basis

Synonyms

Rh(acac)(COD)|Acetylacetonato(1,5-cyclooctadiene)rhodium(I)|(1Z,5Z)-cycloocta-1,5-diene;(Z)-4-hydroxypent-3-en-2-one;rhodium|(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I)|(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I), 99%|AKOS025117565|AKOS037646062|A

Storage

Room temperature

Shipped In

Normal

Overview

Application

Catalyst/precursor for enantioselective/asymmetric hydrogenations, isomerization/hydroformylations, carbozincation reactions, and silylation of aryl electrophiles

Product class
M-O, Homogeneous Catalysts, M-C, Diene/Dienyl Ligands, Acetylacetonate Ligands

Reaction type
Hydrogenation, Asymmetric Reactions, CH-Activation, Hydroformylation, Asymmetric Hydrogenation, Isomerization

Chemical properties

Chemical formula

C13H19O2Rh

Empirical formula

Rh(cod)(acac)

Molecular weight

310.20

Metal

Rh

Theoretical metal content

33

Physical state

crystalline

Color

yellow

Metal purity

99.95

Specifications

Synonyms

Rh(acac)(COD) | Acetylacetonato(1, 5-cyclooctadiene)rhodium(I) | (1Z, 5Z)-cycloocta-1, 5-diene;(Z)-4-hydroxypent-3-en-2-one;rhodium | (Acetylacetonato)(1, 5-cyclooctadiene)rhodium(I) | (Acetylacetonato)(1, 5-cyclooctadiene)rhodium(I), 99% | AKOS025117565 | AKOS037646062 | A

Specifications & Purity

≥99.95% metals basis

Legal Information

Product of Umicore

Storage

Room temperature

Shipped In

Normal

Purity

≥99.95% metals basis

Names and Identifiers

• Canonical Smiles: CC(=CC(=O)C)O.C1CC=CCCC=C1.[Rh]
• IUPAC Name: (1Z,5Z)-cycloocta-1,5-diene;(Z)-4-hydroxypent-3-en-2-one;rhodium
• InChIKey: BUYVJWVYKPKZEX-DWVXZKBMSA-N
• INCHI: 1S/C8H12.C5H8O2.Rh/c1-2-4-6-8-7-5-3-1;1-4(6)3-5(2)7;/h1-2,7-8H,3-6H2;3,6H,1-2H3;/b2-1-,8-7-;4-3-
• Isomeric SMILES: C/C(=C/C(=O)C)/O.C1/C=C\CC/C=C\C1.[Rh]
• WGK Germany: 3
• RTECS: VI9292000
• PubChem CID: 10935795
• Molecular Weight: 310.19

Chemical and Physical Properties

• Sensitivity: Air sensitive.
• Melt Point(°C): 138-140 °C (lit.)