≥99.95% metals basis for sensitive chromatographic and analytical workflows requiring minimal baseline interference.
Room temperature,Argon charged Ships Normal Check lot-specific COA for exact specifications.
SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.
Cited in 1 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.
(Acetylacetonato)dicarbonylrhodium(I) is used in in situ formation of a fluorous-soluble hydroformylation catalyst of interest in molecular engineering. It is also used as a catalyst for various carbonylation reactions, silylcarbocyclizations,conjugate additions to enones, carbamoylstannation,and reduction of aromatic nitro compounds.
A catalyst for various carbonylation reactions
Product class
M-O, Homogeneous Catalysts, Acetylacetonate Ligands
Reaction type
Carbonylation, Hydroformylation, Reduction
Chemical properties
C7H7O4Rh
Rh(CO)2(acac)
258.04
Rh
40
crystalline
green
99.95
| Pubchem Sid | 488202386 |
|---|---|
| Pubchem Sid Url | https://pubchem.ncbi.nlm.nih.gov/substance/488202386 |
| Canonical Smiles | [C-]#[O+].[C-]#[O+].CC(=O)\C=C(\C)O[Rh] |
| InChIKey | BZCAWKOPWNIDOC-FGSKAQBVSA-M |
| INCHI | 1S/C5H8O2.2CO.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;; |
| Isomeric SMILES | CC(=[OH+])CC(=[OH+])C.[C-]#[O+].[C-]#[O+].[Rh] |
| WGK Germany | 3 |
| UN Number | 3467 |
| Packing Group | II |
| Molecular Weight | 258.03 |
| Reaxy-Rn | 20671103 |
| Reaxys-RN_link_address | https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=20671103&ln= |
Comprehensive hazard, handling, storage, and regulatory compliance document.
Download SDS →Lot-specific quality data. Enter your lot number to retrieve the exact COA.
Look up COA →Full quality attributes and acceptance criteria for this grade.
View spec sheet →Find and download the COA for your product by matching the lot number on the packaging.
| Lot Number | Certificate Type | Date | Item |
|---|---|---|---|
 J2510012 | Certificate of Analysis | Oct 15, 2022 | A293954 |
| K2215265 | Certificate of Analysis | Oct 15, 2022 | A293954 |
| K2215296 | Certificate of Analysis | Oct 15, 2022 | A293954 |
| D2213008 | Certificate of Analysis | Mar 24, 2022 | A293954 |
| Solubility | Solubility in water: insoluble in water;Soluble in acetone |
|---|---|
| Sensitivity | Air Sensitive |
| Melt Point(°C) | 154-156°C |
| 1. Jian Ruan, Youkai Jiang, Yaheng Zhang, Luhaibo Zhao, Jie Zhang, Zhiyong Tang. (2022) Towards more efficient hydroformylation of long-chain alkenes in aqueous biphasic system using microbubbles. Asia-Pacific Journal of Chemical Engineering, 18 (1): (e2842). [PMID:] [10.1002/apj.2842] |
