Aluminum fluoride - anhydrous, ≥99.9% metals basis , CAS No.7784-18-1

CAS: 7784-18-1 Cat. No.: A105069 Molecular Weight: 83.98 EC Number: 232-051-1
AVAILABLE TO ORDER
GRADE & PURITY Anhydrous Grade ? Anhydrous grade — water removed and packaged dry for moisture-sensitive chemistry. Use in reactions where even trace water would interfere or quench. ≥99.9% metals basis
Synonyms
Aluminum(III) Fluoride | Trifluoroaluminum
Storage
Argon charged,Room temperature
Shipped In
Normal
 ·  off list, applied to all prices below.
Size
Status
Price
Qty
5g
A105069-5g
9
$9.90
25g
A105069-25g
3
$20.90
100g
A105069-100g
3
$56.90
500g
A105069-500g
2
$191.90
Enter a quantity for the sizes you want to add.
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Why this grade

anhydrous, ≥99.9% metals basis Anhydrous Grade for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

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Storage & shipping

Argon charged,Room temperature Ships Normal Check lot-specific COA for exact specifications.

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Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

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Literature proof

Cited in 57 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Overview

Aluminum fluoride (AlF3) is an inorganic compound used primarily in the production of aluminum. It is also used to inhibit fermentation. It is a sputtering target for preparation of low index films. In ceramics, as flux in metallurgy, in aluminum manufacture, as inhibitor of fermentation, as catalyst in organic reactions.
It has a bitter taste. It is widely used in the preparation of doped fluorinated glasses and as a mixed metal fluoride catalyst in the synthesis of HFC-134a.

Specifications

Synonyms
Aluminum(III) Fluoride | Trifluoroaluminum
Specifications & Purity
anhydrous, ≥99.9% metals basis
Storage
Argon charged, Room temperature
Shipped In
Normal
Grade
Anhydrous Grade
Purity
≥99.9% metals basis
Names and Identifiers
WGK Germany 3
RTECS BD0725000
Molecular Weight 83.98

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

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✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

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📊 Datasheet

Quick-reference summary of product specifications and applications.

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🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

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Advanced Data

Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

42 results found

Lot NumberCertificate TypeDateItem
F2605520Certificate of AnalysisApr 03, 2026 A105069
F2605519Certificate of AnalysisApr 03, 2026 A105069
F2605517Certificate of AnalysisApr 03, 2026 A105069
L2530103Certificate of AnalysisDec 18, 2025 A105069
L2530093Certificate of AnalysisDec 18, 2025 A105069
L2530092Certificate of AnalysisDec 18, 2025 A105069
I2508097Certificate of AnalysisAug 26, 2025 A105069
I2508093Certificate of AnalysisAug 26, 2025 A105069
I2508092Certificate of AnalysisAug 26, 2025 A105069
D2527097Certificate of AnalysisApr 18, 2025 A105069
D2527098Certificate of AnalysisApr 18, 2025 A105069
D2527099Certificate of AnalysisApr 18, 2025 A105069
A2509482Certificate of AnalysisDec 19, 2024 A105069
A2509487Certificate of AnalysisDec 19, 2024 A105069
A2509489Certificate of AnalysisDec 19, 2024 A105069
A2509495Certificate of AnalysisDec 19, 2024 A105069
L2405208Certificate of AnalysisOct 25, 2024 A105069
L2406332Certificate of AnalysisOct 25, 2024 A105069
K2408187Certificate of AnalysisOct 25, 2024 A105069
L2405207Certificate of AnalysisOct 25, 2024 A105069
I2406132Certificate of AnalysisAug 23, 2024 A105069
I2406130Certificate of AnalysisAug 23, 2024 A105069
I2406086Certificate of AnalysisAug 23, 2024 A105069
E2415193Certificate of AnalysisMay 09, 2024 A105069
E2415192Certificate of AnalysisMay 09, 2024 A105069
E2415186Certificate of AnalysisMay 09, 2024 A105069
C2414099Certificate of AnalysisMar 07, 2024 A105069
C2414098Certificate of AnalysisMar 07, 2024 A105069
D2417048Certificate of AnalysisMar 07, 2024 A105069
D2416074Certificate of AnalysisMar 07, 2024 A105069
C2414101Certificate of AnalysisMar 07, 2024 A105069
C2414100Certificate of AnalysisMar 07, 2024 A105069
K2321024Certificate of AnalysisNov 30, 2023 A105069
K2321023Certificate of AnalysisNov 30, 2023 A105069
G2322072Certificate of AnalysisJul 03, 2023 A105069
F2301075Certificate of AnalysisJun 12, 2023 A105069
A2305051Certificate of AnalysisDec 08, 2022 A105069
A2305049Certificate of AnalysisDec 08, 2022 A105069
I2228063Certificate of AnalysisSep 16, 2022 A105069
I2228061Certificate of AnalysisSep 16, 2022 A105069
I2228060Certificate of AnalysisSep 16, 2022 A105069
I2223413Certificate of AnalysisAug 22, 2022 A105069

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Chemical and Physical Properties
SolubilitySparingly soluble in acids and alkalies. Insoluble in Acetone.
SensitivityHygroscopic.
Boil Point(°C)1537℃
Melt Point(°C)1291℃
Documents & Articles
Citations of This Product
References
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15. Liyu Chen, Jiaxin Yang, Youjian Yang, Yifan Zhang, Zhaowen Wang.  (2022)  Thermodynamics, kinetics and mechanism analysis of aluminothermic reduction for preparing Al-Zr alloy.  Materials Today Communications,      [PMID:] [10.1016/j.mtcomm.2022.103714]
16. Meng Gao, Weibing Zhang, Binchang Wu, Yining Dai, Chengdong Peng, Yuexiao Pan.  (2022)  Acetate-triggered morphology evolution and improved photoluminescence performance of K2NaInF6:Mn4+ crystals for wide applications.  JOURNAL OF LUMINESCENCE,      [PMID:] [10.1016/j.jlumin.2022.119011]
17. Jinzhao Guan, Kaiyu Xie, Aimin Liu, Zhongning Shi, Gong Chen, Miroslav Boca.  (2021)  Study on the mechanism of Al-Si alloy preparation via aluminothermic reduction–molten salt electrolysis in KF–AlF3 molten salt.  Materials Today Communications,      [PMID:] [10.1016/j.mtcomm.2021.102959]
18. Yang Jiaxin, Tao Wenju, Chen Liyu, He Jingui, Zhang Yifan, Yu Jiangyu, Wang Zhaowen.  (2021)  Electrochemical Reduction of Silicon Oxide and Codeposition of Al-Si Alloy from Cryolite Molten Salt.  JOM,  73  (12): (3727-3733).  [PMID:] [10.1007/s11837-021-04849-x]
19. Hongkun Liu, Bingbing Zhang, Ling Li, Ying Wang.  (2021)  Exploring Deep-UV Nonlinear Optical Materials with Enhanced Second Harmonic Generation Response and Birefringence in Fluoroaluminoborate Crystals.  ACS Applied Materials & Interfaces,      [PMID:34157839] [10.1021/acsami.1c07442]
20. Xuyang Zhang, Jingbo Yu, Lili Hu, Jinjun Ren.  (2021)  Clarifying a Competitive Crystallization Mechanism of Upconversion Luminescent Oxyfluoride Glass Ceramics by Solid-State NMR Spectroscopy.  INORGANIC CHEMISTRY,      [PMID:33691066] [10.1021/acs.inorgchem.1c00116]
21. Zaisheng Wang, Zhenming Xu, Xiaojing Jin, Jianhui Li, Qingshuai Xu, Yanan Chong, Changchun Ye, Weishan Li, Daiqi Ye, Yingying Lu, Yongcai Qiu.  (2020)  Dendrite-free and air-stable lithium metal batteries enabled by electroless plating with aluminum fluoride.  Journal of Materials Chemistry A,  (18): (9218-9227).  [PMID:] [10.1039/D0TA02410D]
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48. Yanhui Zhang, Jiajia Li, Yaqing Ding, Kaitong Liu, Xiaofeng Gu.  (2025)  BaAlPO4F2:Structure and Properties of the First Barium Fluoroaluminophosphate with Mixed Anion Group [Al2PO8F5].  DALTON TRANSACTIONS,      [PMID:41222580] [10.1039/D5DT02249E]
49. Zhiwei Liu, Qi Tan, Cong Wang, Bingliang Gao.  (2025)  Separation and recovery of valuable elements from spent aluminum electrolyte via aluminum sulfate roasting-leaching process.  SEPARATION AND PURIFICATION TECHNOLOGY,      [PMID:] [10.1016/j.seppur.2025.136061]
50. Jiaming Li, Jiaxin Yang, Zhaowen Wang.  (2025)  Electrochemical study on the recovery of LiFePO4 battery cathode material in fluoride molten salt.  SEPARATION AND PURIFICATION TECHNOLOGY,      [PMID:] [10.1016/j.seppur.2025.136071]
51. Yongkang Yang, Anrui Wang, Yulong Zhou, Xin Li, Rui Zhao, Shuxin Niu, Xiqing Xu.  (2025)  In-situ grown mullite whiskers zippering the printing layers in silica-based ceramic cores through vat photopolymerization 3D printing.  CERAMICS INTERNATIONAL,  51  (10): (12622-12633).  [PMID:] [10.1016/j.ceramint.2025.01.102]
52. Qi Yang, Pengfei Ren, Guangming Cai.  (2025)  Thermally welded fluorine-rich hybrid interface enables high-performance sulfide-based all-solid-state lithium batteries.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2025.171253]
53. Weijie Zhu, Weichao Wang.  (2025)  Mixed-cation effect for enhanced L-band spectral broadening in Er3+/Yb3+ co-doped fluoro-sulfo-phosphate glasses.  CERAMICS INTERNATIONAL,  51  (26): (47599-47610).  [PMID:] [10.1016/j.ceramint.2025.08.017]
54. Qiao Yun-ze, Hua Yu, Wu Guang-xin, Shi Chen-yang, Huang Ying-de, Yang Wen-jie.  (2025)  Electrochemical behavior of NiCu anode in cryolite and the synergistic effect of Al2O3 on corrosion resistance.  JOURNAL OF SOLID STATE ELECTROCHEMISTRY,      [PMID:] [10.1007/s10008-025-06481-0]
55. Zhipeng Jing, Aimin Liu, Yongjun Wang, Yuankun Zhang, Fengguo Liu, Chengdan He, Xianwei Hu, Jin Wang, Zhenkun He, Zhongning Shi.  (2025)  Aluminum and oxygen production by electrolysis after aluminothermic reduction of lunar soil simulant in cryolite melts.  SEPARATION AND PURIFICATION TECHNOLOGY,      [PMID:] [10.1016/j.seppur.2025.136676]
56. Chao Li, Zhichao Zeng, Wenshuo Zhang, Xiaomeng Shi, Yaping Du.  (2026)  Pliable LaCl3-Based Lithium Superionic Conductor.  CHEMISTRY OF MATERIALS,      [PMID:] [10.1021/acs.chemmater.5c02682]
57. Xiaohao Chen, Su Zhang, Ran Pang, Jiarao Shi, Xuexia Chen.  (2026)  Ce3+-activated BaAlSi5N7O2: A novel cyan-emitting phosphor with superior thermal stability for full-visible-spectrum LED lighting.  JOURNAL OF LUMINESCENCE,      [PMID:] [10.1016/j.jlumin.2026.121827]
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