The store will not work correctly when cookies are disabled.
JavaScript seems to be disabled in your browser. For the best experience on our site, be sure to turn on Javascript in your browser.
· · COA & SDS available for every product · Same-day shipping on in-stock items Bis(norbornadiene)rhodium(I) tetrafluoroborate - ≥99.95% metals basis , CAS No.36620-11-8
Synonyms
Bis(norbornadiene)rhodium(I) tetrafluoroborate|36620-11-8|Bis[eta-(2,5-norbornadiene)]rhodium(I) Tetrafluoroborate|[rh(nbd)2]bf4|bicyclo[2.2.1]hepta-2,5-diene;rhodium;tetrafluoroborate|Rh(nbd)2BF4|Chiralyst P374|MFCD00671775|DTXSID30448239|ZWPWNBFOFVFMPP-
Storage
Room temperature,Argon charged
🧪
Why this grade ≥99.95% metals basis for sensitive chromatographic and analytical workflows requiring minimal baseline interference.
🌡
Storage & shipping Room temperature,Argon charged Ships Normal Check lot-specific COA for exact specifications.
📋
Quality documents SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.
📚
Literature proof Cited in 0 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.
Overview Application
Precatalysts for Asymmetric and Cross-Coupling Catalysis
Bis(norbornadiene)rhodium(I) tetrafluoroborate can be used as a catalyst for the synthesis of:
• Lactones via the 1,4-addition of arylboronic acids to butenolide.
• Chiral β-aryl-substituted ketones and esters.
• β-aryloxycarboxylic esters from β-aryloxy-α,γ-unsaturated esters.
Product class
M-C, Homogeneous Catalysts, Diene/Dienyl Ligands
Reaction type
Hydrogenation, Asymmetric Reactions, CH-Activation, Asymmetric Hydrogenation, Isomerization
Chemical properties
Theoretical metal content
Specifications Synonyms
Bis(norbornadiene)rhodium(I) tetrafluoroborate | 36620-11-8 | Bis[eta-(2, 5-norbornadiene)]rhodium(I) Tetrafluoroborate | [rh(nbd)2]bf4 | bicyclo[2.2.1]hepta-2, 5-diene;rhodium;tetrafluoroborate | Rh(nbd)2BF4 | Chiralyst P374 | MFCD00671775 | DTXSID30448239 | ZWPWNBFOFVFMPP-
Specifications & Purity
≥99.95% metals basis
Legal Information
Product of Umicore
Storage
Room temperature, Argon charged
Purity
≥99.95% metals basis
Names and Identifiers Canonical Smiles [B-](F)(F)(F)F.C1C2C=CC1C=C2.C1C2C=CC1C=C2.[Rh] IUPAC Name bicyclo[2.2.1]hepta-2,5-diene;rhodium;tetrafluoroborate InChIKey ZWPWNBFOFVFMPP-UHFFFAOYSA-N INCHI 1S/2C7H8.BF4.Rh/c2*1-2-7-4-3-6(1)5-7;2-1(3,4)5;/h2*1-4,6-7H,5H2;;/q;;-1; Isomeric SMILES [B-](F)(F)(F)F.C1C2C=CC1C=C2.C1C2C=CC1C=C2.[Rh] WGK Germany 3 PubChem CID 10915722 UN Number 1759 Molecular Weight 373.99
Documentation 📋 Safety Data Sheet (SDS) Comprehensive hazard, handling, storage, and regulatory compliance document.
Download SDS → ✅ Certificate of Analysis (COA) Lot-specific quality data. Enter your lot number to retrieve the exact COA.
Look up COA → 📊 Datasheet Quick-reference summary of product specifications and applications.
View datasheet → 🔬 Specification Sheet Full quality attributes and acceptance criteria for this grade.
View spec sheet →
Advanced Data Taxonomic Classification Kingdom Organic compounds Superclass Hydrocarbons Class Polycyclic hydrocarbons Subclass Not available Intermediate Tree Nodes Not available Direct Parent Polycyclic hydrocarbons Alternative Parents Organic transition metal salts Organic metalloid salts Unsaturated aliphatic hydrocarbons Olefins Hydrocarbon derivatives Organic anions Molecular Framework Not available Substituents Polycyclic hydrocarbon - Organic metalloid salt - Organic transition metal salt - Unsaturated aliphatic hydrocarbon - Unsaturated hydrocarbon - Hydrocarbon derivative - Olefin - Organic anion - Aliphatic homopolycyclic compound Description This compound belongs to the class of organic compounds known as polycyclic hydrocarbons. These are polycyclic organic compounds made up only of carbon and hydrogen atoms. External Descriptors Not available Data sources 1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.
3D Structure Certificates（CoA,COO,BSE/TSE and Analysis Chart) Chemical and Physical Properties Sensitivity Air Sensitive Melt Point(°C) 136.9-139.9 °C Molecular Weight 373.990 g/mol XLogP3 Hydrogen Bond Donor Count 0 Hydrogen Bond Acceptor Count 5 Rotatable Bond Count 0 Exact Mass 374.034 Da Monoisotopic Mass 374.034 Da Topological Polar Surface Area 0.000 Ų Heavy Atom Count 20 Formal Charge -1 Complexity 122.000 Isotope Atom Count 0 Defined Atom Stereocenter Count 0 Undefined Atom Stereocenter Count 0 Defined Bond Stereocenter Count 0 Undefined Bond Stereocenter Count 0 The total count of all stereochemical bonds 0 Covalently-Bonded Unit Count 4
Documents & Articles Solution Calculators Molarity Calculator Determine the necessary mass, volume, or concentration for preparing a solution.
Dilution Calculator Determine the dilution needed to prepare a stock solution.
Reconstitution Calculator Reviews
We use cookies to ensure the website functions properly and, where permitted, to improve your experience. You can manage your preferences at any time in Settings. Learn more in our
Cookie Policy. Settings Agree All Decline
Shall we send you a message when we have discounts available?
Remind me later Allow
Thank you! Please check your email inbox to confirm.
Oops! Notifications are disabled.
Products are supplied to verified businesses, institutions, and qualified professionals for research and development use only. Not for use in humans, animals, diagnosis, or therapy.
Copyright © 2023–present Aladdin Scientific Corp. All rights reserved.
