(+)-1-Benzyl-[(3R,4R)-bis(diphenylphosphino)]pyrrolidine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate - ≥98% , CAS No.99143-48-3

CAS: 99143-48-3 Cat. No.: B472689 Molecular Weight: 827.48 EC Number: 635-579-4 PubChem CID: 53485843

GRADE & PURITY ≥98%

Synonyms

(+)-(3R,4R)-Bis(diphenylphosphino)-1-benzylpyrrolidine(1,5-cyclooctadiene)rhodium(i)tetrafluoroborate | BP-12244 | DTXSID20704836 | (+)-1-Benzyl-[(3R,4R)-bis(diphenylphosphino)]pyrrolidine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98% | (+)-1-Benzy

Storage

Room temperature

Overview

sential Elements for Asymmetric Hydrogenations

Specifications

Synonyms

(+)-(3R, 4R)-Bis(diphenylphosphino)-1-benzylpyrrolidine(1, 5-cyclooctadiene)rhodium(i)tetrafluoroborate | BP-12244 | DTXSID20704836 | (+)-1-Benzyl-[(3R, 4R)-bis(diphenylphosphino)]pyrrolidine(1, 5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98% | (+)-1-Benzy

Specifications & Purity

≥98%

Legal Information

catASium is a registered trademark of Evonik Degussa GmbH

Storage

Room temperature

Purity

≥98%

Names and Identifiers

• Canonical Smiles: [B-](F)(F)(F)F.C1CC=CCCC=C1.C1C(C(CN1CC2=CC=CC=C2)P(C3=CC=CC=C3)C4=CC=CC=C4)P(C5=CC=CC=C5)C6=CC=CC=C6.[Rh]
• IUPAC Name: [(3R,4R)-1-benzyl-4-diphenylphosphanylpyrrolidin-3-yl]-diphenylphosphane;cycloocta-1,5-diene;rhodium;tetrafluoroborate
• InChIKey: ZLLQZPNXAHRYIM-MPCJZQQPSA-N
• INCHI: 1S/C35H33NP2.C8H12.BF4.Rh/c1-6-16-29(17-7-1)26-36-27-34(37(30-18-8-2-9-19-30)31-20-10-3-11-21-31)35(28-36)38(32-22-12-4-13-23-32)33-24-14-5-15-25-33;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h1-25,34-35H,26-28H2;1-2,7-8H,3-6H2;;/q;;-1;/t34-,35-;;;/m1.../s1
• Isomeric SMILES: [B-](F)(F)(F)F.C1CC=CCCC=C1.C1[C@H]([C@@H](CN1CC2=CC=CC=C2)P(C3=CC=CC=C3)C4=CC=CC=C4)P(C5=CC=CC=C5)C6=CC=CC=C6.[Rh]
• PubChem CID: 53485843
• Molecular Weight: 827.48

References

1. Wang Xueting, Chang Rui, Ji Zhongyin, Song Jinying, Yuan Fei, Zhang Shijuan.  (2022)  Improved Extraction and Detection Method for Bisphenols Using Stable Isotope Labeling Technique.  Food Analytical Methods,  16  (2): (281-292).  [PMID:] [10.1007/s12161-022-02413-0]