(1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II) - ≥97% , CAS No.361346-80-7

CAS: 361346-80-7 Cat. No.: B120935 Molecular Weight: 573.6 EC Number: 632-216-1 PubChem CID: 10120770

GRADE & PURITY ≥97%

Synonyms

B2314 | (R)-AMAC | (1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II) | (1R,2R)-N,N-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) | (E)-3-[[(1R,2R)-2-[[(E)-2-Acetyl-3-oxidobut-2-enylide

Storage

Argon charged,Room temperature

Shipped In

Normal

Overview

Catalyst used for the enantioselective reduction of ketones, hetero Diels-Alder reaction, carbonylene reaction, 1,3-dipolar cycloaddition · Schiff base-cobalt complex catalyst for asymmetric borohydride reduction of carbonyl compounds Catalyst for: Enantioselective borohydride reduction Stereoselective preparation of aryl alcohols via asymmetric reduction of aryl ketones with borohydride Stereoselective borohydride reduction of diketones to diols Stereoselective preparation of optically active deuterated primary alcohols via enantioselective borodeuteride reduction of aldehydes Stereoselective preparation of β-hydroxy esters via dynamic kinetic resolution of alkylketo esters with enantioselective borohydride reduction Chemoselective, diastereoselective, and enantioselective borohydride reduction of 1,3-diketones Asymmetric synthesis of diarylhydroxypropanones by stereoselective reduction of alkyldiaryldiketones

Specifications

Synonyms

B2314 | (R)-AMAC | (1R, 2R)-N, N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1, 2-dimesitylethylenediaminato Cobalt(II) | (1R, 2R)-N, N-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1, 2-DIMESITYLETHYLENEDIAMINATO COBALT(II) | (E)-3-[[(1R, 2R)-2-[[(E)-2-Acetyl-3-oxidobut-2-enylide

Specifications & Purity

≥97%

Storage

Argon charged, Room temperature

Shipped In

Normal

Purity

≥97%

Names and Identifiers

• Canonical Smiles: CC1=CC(=C(C(=C1)C)C(C(C2=C(C=C(C=C2C)C)C)N=CC(=C(C)[O-])C(=O)C)N=CC(=C(C)[O-])C(=O)C)C.[Co+2]
• IUPAC Name: (E)-3-[[(1R,2R)-2-[[(E)-2-acetyl-3-oxidobut-2-enylidene]amino]-1,2-bis(2,4,6-trimethylphenyl)ethyl]iminomethyl]-4-oxopent-2-en-2-olate;cobalt(2+)
• InChIKey: PHCQQLMRNZRDJA-SGIDGJHMSA-L
• INCHI: 1S/C32H40N2O4.Co/c1-17-11-19(3)29(20(4)12-17)31(33-15-27(23(7)35)24(8)36)32(34-16-28(25(9)37)26(10)38)30-21(5)13-18(2)14-22(30)6;/h11-16,31-32,35,37H,1-10H3;/q;+2/p-2/b27-23+,28-25+,33-15?,34-16?;/t31-,32-;/m1./s1
• Isomeric SMILES: CC1=CC(=C(C(=C1)C)[C@@H](N=C/C(=C(\[O-])/C)/C(=O)C)[C@H](N=C/C(=C(\[O-])/C)/C(=O)C)C2=C(C=C(C=C2C)C)C)C.[Co+2]
• WGK Germany: 2
• PubChem CID: 10120770
• Molecular Weight: 573.6

Chemical and Physical Properties

• Sensitivity: Air Sensitive
• Specific Rotation[α]: [α]/D 291°, c = 0.1 in chloroform
• Melt Point(°C): 246-250°C