3-Phenyl-1H-inden-1-ylidene[bis(i-butylphobane)]ruthenium(II) dichloride - ≥95% , CAS No.894423-99-5

CAS: 894423-99-5 Cat. No.: P282788 Molecular Weight: 758.78 EC Number: 664-481-4 PubChem CID: 124202843

GRADE & PURITY ≥95%

Synonyms

Umicore Grubbs Catalyst M110 | Dichloro(3-phenyl-1H-inden-1-ylidene)bis(isobutylphobane)ruthenium(II), Dichlorobis(9-isobutyl-9-phosphabicyclo[3.3.1]nonane)(3-phenyl-1H-inden-1-ylidene)ruthenium(II), Grubbs Catalyst® M11

Storage

Room temperature

Overview

Product class
M-P, Homogeneous Catalysts, Grubbs Catalyst® 1st Generation, Phosphorus Ligands - Achiral

Reaction type
Alkene Metathesis, Cross Metathesis, Enyne Metathesis, Ring Closing Metathesis, Ring Opening Metathesis Polymerization, Self Metathesis

Chemical properties

Chemical formula

C39H56Cl2P2Ru

Empirical formula

Ru(iBu-phobane)2(Ind)Cl2

Molecular weight

758.79

Metal

Ru

Theoretical metal content

13

Physical state

powder

Color

brown

Applications & references

Total synthesis of macrocyclic HCV protease inhibitor with RCM as key step.

Reference: US2009 0163706

Ring opening metathesis polymerization.

Reference: Adv. Synth. Catal. 2010, 352, 1934 (DOI: 10.1002/adsc.201000207)

Ring closing metathesis forming heterocycles.

Reference: J. Org. Chem. 2008, 73, 259 (DOI: 10.1021/jo702169p)

Enyne cycloisomerization.

Reference: J. Org. Chem. 2008, 73, 259 (DOI: 10.1021/jo702169p)

Ethenolysis of methyl oleate.

Reference: Chem. Comm. 2008, 2726 (DOI: 10.1039/B718287B)

Self metathesis of terminal alkenes.

Reference: J. Org. Chem. 2008, 73, 259 (DOI: 10.1021/jo702169p)

Specifications

Synonyms

Umicore Grubbs Catalyst M110 | Dichloro(3-phenyl-1H-inden-1-ylidene)bis(isobutylphobane)ruthenium(II), Dichlorobis(9-isobutyl-9-phosphabicyclo[3.3.1]nonane)(3-phenyl-1H-inden-1-ylidene)ruthenium(II), Grubbs Catalyst® M11

Specifications & Purity

≥95%

Legal Information

Sold in collaboration with Umicore for research purposes only. Patent US 10, 518, 716.

Storage

Room temperature

Purity

≥95%

Names and Identifiers

• Canonical Smiles: CC(C)CP1C2CCCC1CCC2.CC(C)CP1C2CCCC1CCC2.C1=CC=C(C=C1)C2=CC(=[Ru](Cl)Cl)C3=CC=CC=C32
• IUPAC Name: dichloro-(3-phenylinden-1-ylidene)ruthenium;9-(2-methylpropyl)-9-phosphabicyclo[3.3.1]nonane
• InChIKey: CCCYSKLUNSOBHP-UHFFFAOYSA-L
• INCHI: 1S/C15H10.2C12H23P.2ClH.Ru/c1-2-6-12(7-3-1)15-11-10-13-8-4-5-9-14(13)15;2*1-10(2)9-13-11-5-3-6-12(13)8-4-7-11;;;/h1-9,11H;2*10-12H,3-9H2,1-2H3;2*1H;/q;;;;;+2/p-2
• WGK Germany: 3
• PubChem CID: 124202843
• Molecular Weight: 758.78