Dichloro(dimethylamino)phosphine - ≥98% , CAS No.683-85-2

CAS: 683-85-2 Cat. No.: D154283 Molecular Weight: 145.95 EC Number: 624-644-2

GRADE & PURITY ≥98%

Synonyms

Dimethylphosphoramidous dichloride, 97% | Dimethylphosphoramidous dichloride | N,N-Dimethylphosphoramidous dichloride | (CH3)2NPCl2 | N-dichlorophosphanyl-N-methylmethanamine | FT-0632796 | (Dimethylamino)phosphonous Dichloride | DTXSID90218455 | 1,1-Dich

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Overview

Dimethylphosphoramidous dichloride (dimethylaminodichlorophosphine) is a phosphorus chloride derivative. It exists in two stable isomers, a gauche-conformer with C1 symmetry and anti-conformer with Cs symmetry. Its synthesis has been reported. Molecular conformation has been investigated through correlation between the 35Cl NQR frequencies and charge on the chlorine atoms. Its vibrational spectra has been studied. Its reaction with SO2 has been investigated. It participates in the synthesis of [(dimethylamino)phosphoryl] bis(difluoromethylene)phosphonate.

application：

Dimethylphosphoramidous dichloride (N,N-dimethylamidodichlorophosphite) may be used in the synthesis of the following:
N,N-dimethylamidotetrachlorophosphorane
O-propylchloroformimino-N,N-dimethylamidochlorophosphate
1,3-bisarylsulphonyl-1,3,2,4-diazadiphosphetidines

Specifications

Synonyms

Dimethylphosphoramidous dichloride, 97% | Dimethylphosphoramidous dichloride | N, N-Dimethylphosphoramidous dichloride | (CH3)2NPCl2 | N-dichlorophosphanyl-N-methylmethanamine | FT-0632796 | (Dimethylamino)phosphonous Dichloride | DTXSID90218455 | 1, 1-Dich

Specifications & Purity

≥98%

Storage

Store at 2-8°C, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥98%

Names and Identifiers

• Canonical Smiles: CN(C)P(Cl)Cl
• IUPAC Name: N-dichlorophosphanyl-N-methylmethanamine
• InChIKey: XPWWDZRSNFSLRQ-UHFFFAOYSA-N
• INCHI: 1S/C2H6Cl2NP/c1-5(2)6(3)4/h1-2H3
• Isomeric SMILES: CN(C)P(Cl)Cl
• WGK Germany: 3
• Molecular Weight: 145.95
• Reaxy-Rn: 1733157
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=1733157&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic nitrogen compounds
    • Class Organonitrogen compounds

• Kingdom: Organic compounds
• Superclass: Organic nitrogen compounds
• Class: Organonitrogen compounds
• Subclass: Not available
• Intermediate Tree Nodes: Not available
• Direct Parent: Organonitrogen compounds
• Alternative Parents: Organopnictogen compounds Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Organopnictogen compound - Hydrocarbon derivative - Organonitrogen compound - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as organonitrogen compounds. These are organic compounds containing a nitrogen atom.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Reacts with water.
• Sensitivity: Moisture Sensitive,Heat Sensitive
• Refractive Index: 1.5
• Flash Point(°F): -9.4 °F
• Flash Point(°C): -23°C(lit.)
• Boil Point(°C): 150°C(lit.)
• Molecular Weight: 145.950 g/mol
• XLogP3: 1.700
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 144.961 Da
• Monoisotopic Mass: 144.961 Da
• Topological Polar Surface Area: 3.200 Ų
• Heavy Atom Count: 6
• Formal Charge: 0
• Complexity: 38.500
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1