Tetramethyl-1,4-benzoquinone（DQ）

Product Manager:Nick Wilde

See also:1,4-Benzoquinone, BQ

Recent Literature

The use of a palladium catalyst paired with a bidentate phosphine ligand and duroquinone facilitates an intermolecular oxidative amination process for unactivated olefins and primary aliphatic amines, yielding a variety of secondary allylic amines in high yields and with remarkable regio- and stereoselectivity. This reaction mechanism involves allylic C(sp3)-H activation followed by nucleophilic amination.
M. Li, Y. Jin, Y. Chen, W. Wu, H. Jiang, J. Am. Chem. Soc., 2023, 145, 9448-9453.

https://doi.org/10.1021/jacs.3c02114

Quoted from:

https://www.organic-chemistry.org/chemicals/oxidations/duroquinone.shtm

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