The use of a palladium catalyst paired with a bidentate phosphine ligand and duroquinone facilitates an intermolecular oxidative amination process for unactivated olefins and primary aliphatic amines, yielding a variety of secondary allylic amines in high yields and with remarkable regio- and stereoselectivity. This reaction mechanism involves allylic C(sp3)-H activation followed by nucleophilic amination. M. Li, Y. Jin, Y. Chen, W. Wu, H. Jiang, J. Am. Chem. Soc., 2023, 145, 9448-9453.
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