Iron(III) perchlorate hydrate - Reagent grade, low chloride , CAS No.15201-61-3

CAS: 15201-61-3 Cat. No.: I305690 Molecular Weight: 354.20 (anhydrous basis) EC Number: 677-720-2 PubChem CID: 9799594

GRADE & PURITY Reagent Grade, low chloride

Synonyms

Iron(III) perchlorate hydrate | iron(3+);triperchlorate;hydrate | Iron(III) perchlorate hydrate (yellow) | DTXSID80430922 | Iron(III) perchlorate hydrate (purple) | Iron(III) perchlorate hydrate, crystalline | MFCD00149705 | Iron(III) perchlorate hydrate

Storage

Room temperature,Argon charged

Shipped In

Normal

Overview

Catalyst for synthesis of: 

· Fullerene-fused lactones 

· α-Carbonyl furans via one-pot cyclization

· Fullerodioxolanes via heterocyclization

· Dialylated indoles via double alkylation

· Aryl esters via oxidative esterification

Used as chemical actinometer based on photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution

Specifications

Synonyms

Iron(III) perchlorate hydrate | iron(3+);triperchlorate;hydrate | Iron(III) perchlorate hydrate (yellow) | DTXSID80430922 | Iron(III) perchlorate hydrate (purple) | Iron(III) perchlorate hydrate, crystalline | MFCD00149705 | Iron(III) perchlorate hydrate

Specifications & Purity

Reagent grade, low chloride

Storage

Room temperature, Argon charged

Shipped In

Normal

Grade

Reagent Grade

Names and Identifiers

• Canonical Smiles: O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Fe+3]
• IUPAC Name: iron(3+);triperchlorate;hydrate
• InChIKey: PFPIMAZLJXJVAN-UHFFFAOYSA-K
• INCHI: 1S/3ClHO4.Fe.H2O/c3*2-1(3,4)5;;/h3*(H,2,3,4,5);;1H2/q;;;+3;/p-3
• Isomeric SMILES: O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Fe+3]
• WGK Germany: 3
• PubChem CID: 9799594
• UN Number: 1481
• Molecular Weight: 354.20 (anhydrous basis)

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Mixed metal/non-metal compounds
    • Class Transition metal oxoanionic compounds
      • Subclass Transition metal perchlorates

• Kingdom: Inorganic compounds
• Superclass: Mixed metal/non-metal compounds
• Class: Transition metal oxoanionic compounds
• Subclass: Transition metal perchlorates
• Intermediate Tree Nodes: Not available
• Direct Parent: Transition metal perchlorates
• Alternative Parents: Inorganic salts Inorganic oxides
• Molecular Framework: Not available
• Substituents: Transition metal perchlorate - Inorganic oxide - Inorganic salt
• Description: This compound belongs to the class of inorganic compounds known as transition metal perchlorates. These are inorganic compounds in which the largest oxoanion is perchlorate, and in which the heaviest atom not in an oxoanion is a transition metal.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Soluble in water
• Sensitivity: Hygroscopic
• Molecular Weight: 372.210 g/mol
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 13
• Rotatable Bond Count: 0
• Exact Mass: 370.791 Da
• Monoisotopic Mass: 370.791 Da
• Topological Polar Surface Area: 224.000 Ų
• Heavy Atom Count: 17
• Formal Charge: 0
• Complexity: 95.800
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 5

XLogP3

References

1. Jinzhao Wang, Di Huang, Fengxia Chen, Jianhua Chen, Hongyu Jiang, Yifan Zhu, Chuncheng Chen, Jincai Zhao.  (2023)  Rapid Redox Cycling of Fe(II)/Fe(III) in Microdroplets during Iron–Citric Acid Photochemistry.  ENVIRONMENTAL SCIENCE & TECHNOLOGY,      [PMID:36883325] [10.1021/acs.est.2c07897]

2. Xiaoyu Jiao, Rui Zeng, Guangcai Lan, Siyu Zuo, Jun He, Chengjun Wang.  (2022)  Mechanistic study on photochemical generation of I•/I2•− radicals in coastal atmospheric aqueous aerosol.  SCIENCE OF THE TOTAL ENVIRONMENT,      [PMID:35218835] [10.1016/j.scitotenv.2022.154080]

3. Pan Shuihong, Feng Chuchu, Lin Jialu, Cheng Lidong, Wang Chengjun, Zuo Yuegang.  (2017)  Occurrence and photodegradation of methylmercury in surface water of Wen-Rui-Tang River network, Wenzhou, China.  ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH,  24  (12): (11289-11298).  [PMID:28299570] [10.1007/s11356-017-8708-z]

4. Zhenfu Huang, Yuting Ye, Shun Zhu, Yuyuan Yao, Wangyang Lu, Wenxing Chen.  (2014)  Enhanced catalytic decoloration of Rhodamine B based on 4-aminopyridine iron coupled with cellulose fibers.  JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY,  90  (6): (1144-1151).  [PMID:] [10.1002/jctb.4504]

5. Xu Jing, Gu Kaiye, Wang Peifang, Cheng Pengfei, Che Huinan, Tang Chunmei, Zhang Kan, Ao Yanhui.  (2025)  Piezo-catalytic in-site H2O2 generation and activation across wide pH range to drive hydroxyl radical-mediated pollutant degradation.  Nature Communications,  16  (1): (1-11).  [PMID:40854902] [10.1038/s41467-025-63337-x]

6. Xia Jiang, Zijiao Yang, Jingyao Zhang, Huan Liang, Hongge Wang, Jiong Lu.  (2024)  Preparation and characterization of photosensitive methacrylate-grafted sodium carboxymethyl cellulose as an injectable material to fabricate hydrogels for biomedical applications.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:38360247] [10.1016/j.ijbiomac.2024.130190]

7. Bo Sheng, Yuhan Lin, Haiqing Xu, Jing Zhang.  (2025)  Accelerating reduction of ferric iron by tourmaline for efficient H2O2 activation in removing aqueous organic pollutants.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:41176864] [10.1016/j.jcis.2025.139349]

8. Jiayi Wang, Rui Zeng, Jun He, Chengjun Wang.  (2025)  Water-soluble matter mediated phototransformation of guaiacol leading to formation of aqueous secondary organic aerosol: Mechanism and kinetics.  Journal of Environmental Sciences,      [PMID:] [10.1016/j.jes.2025.11.050]

9. Dian Zhang, Yang Zi, Jinhong Dai, Lu Guo, Danling Tang, Xiao Su, Zhongyi Jiang, Fuming Chen.  (2025)  Simultaneous seawater desalination and electrical-power generation using low-temperature heat sources.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2025.162649]

10. Wei Fang, Zeping Ou, Yifan Wang, Xiaoxue Lin, Hao Yang, Yujie Zheng, Jing Li, Lei Wang, Lijun Hu, Chen Li, Jianyong Ouyang, Kuan Sun.  (2025)  Intrinsically high-performance n-type copper(Ⅰ/Ⅱ) chloride thermocells.  Materials Reports: Energy,      [PMID:] [10.1016/j.matre.2025.100402]