GRADE & PURITY ≥98%

Synonyms

Manganese dibromide tetrahydrate | Manganese(2+) dibromide tetrahydrate

Storage

Argon charged,Room temperature

Shipped In

Normal

Specifications

Synonyms

Manganese dibromide tetrahydrate | Manganese(2+) dibromide tetrahydrate

Specifications & Purity

≥98%

Storage

Argon charged, Room temperature

Shipped In

Normal

Purity

≥98%

Names and Identifiers

• Pubchem Sid: 504773769
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504773769
• Molecular Weight: 286.81

Chemical and Physical Properties

• Solubility: Soluble in water, alcohol
• Sensitivity: Moisture sensitive
• Melt Point(°C): 64.3℃

References

1. Sibo Zhao, Hengbin Mao, Weishan Ma, Mingliang Li, Shao Gang, Bingbing Fan, Hailong Wang, Hongliang Xu, Hongxia Lu.  (2023)  Enhanced luminescence stability of high-entropy dual-phase Cs(Pb1/5Mn1/5Ni1/5Zn1/5Cd1/5)Br3/Cs(Pb1/5Mn1/5Ni1/5Zn1/5Cd1/5)2Br5 perovskite nanocrystals coated with SiO2 and EVA.  CERAMICS INTERNATIONAL,      [PMID:] [10.1016/j.ceramint.2023.10.257]

2. Huidong Tang, Yanqiao Xu, Xiaobo Hu, Haijie Chen, Sanhai Wang, Weihui Jiang, Qing Hu, Lianjun Wang, Wan Jiang.  (2023)  Scalable Synthesis of Lead-Free Tetramethylammonium Manganese Halides for Highly Efficient Backlight Displays.  Laser & Photonics Reviews,  18  (1): (2300672).  [PMID:] [10.1002/lpor.202300672]

3. Shiwei Xue, Hengbin Mao, Junhui Li, Xinge Sun, Ziyu Gong, Bingbing Fan, Gang Shao, Hailong Wang, Hongliang Xu, Rui Zhang, Hongxia Lu.  (2023)  One-step synthesis of all-inorganic high-entropy dual-phase Cs‘B’Br3/Cs‘B’2Br5 perovskite nanocrystals by high-energy ball milling.  CERAMICS INTERNATIONAL,      [PMID:] [10.1016/j.ceramint.2023.08.193]

4. Jie Zhang, Kai-Qi Sun, Zhong-Hui Zhang, Ri-Cheng Wang, Zi-Han Lin, Xiao-Wu Lei, Yu-Yin Wang, Ping Ju, Yuan-Chun He.  (2023)  Enhanced stability and tunable photoluminescence in Mn2+-doped one-dimensional hybrid lead halide perovskites for high-performance white light emitting diodes.  RSC Advances,  13  (28): (19039-19045).  [PMID:37362341] [10.1039/D3RA02813E]

5. Xiuqiang Duan, Kun Nie, Xuyi Wang, Chi-An Cheng, Ranran Zhou, Ziyao Hu, Junbao Yan, Lefu Mei, Xiaoxue Ma, Songjun Yao, Luoxin Wang, Hua Wang.  (2023)  Cesium manganese halide perovskite-analogue nanocrystals with highly efficient energy conversion for flexible multifunctional fibers.  Inorganic Chemistry Frontiers,  10  (4): (1338-1347).  [PMID:] [10.1039/D2QI02514K]

6. Liu Xiaoting, Yang Jiapeng, Chen Wenya, Yang Fan, Chen Yihuang, Liang Xiaojuan, Pan Shuang, Xiang Weidong.  (2022)  [(CH3)4N]2Mn0.6Zn0.4Br4: Lead-free MnII-based hybrid halide with high photoluminescence quantum yield for backlight displays.  Nano Research,  16  (4): (5894-5899).  [PMID:] [10.1007/s12274-022-5152-2]

7. Lei Wang, Hengbin Mao, Junhui Li, Yi Li, Mingliang Li, Jinpeng Zhu, Bingbing Fan, Wen Liu, Gang Shao, Hongliang Xu, Hailong Wang, Rui Zhang, Hongxia Lu.  (2022)  Heavy Mn-doped CsPbBr3 nanocrystals synthesized by high energy ball milling with high stability.  NANOTECHNOLOGY,  33  (45): (455703).  [PMID:35850036] [10.1088/1361-6528/ac81d6]

8. Hao Cui, Zhan Su, Yu Ji, Tao Lan, Jian-Bin Zhang, Juan Ma, Liu Yang, Yu-Hui Chen, Hao-Ran Shen, Jiaqian Wang, Lihui Liu, Kun Cao, Wei Shen, Shufen Chen.  (2022)  Healthy and stable lighting via single-component white perovskite nanoplates.  Nanoscale,  14  (32): (11731-11737).  [PMID:35916203] [10.1039/D2NR02702J]

9. Chen Li, Jun'an Lai, Daofu Wu, Qiang Wang, Yanjun Bai, Peng He, Kang An, Xiaosheng Tang.  (2022)  Lead-free scintillators based on pyridine manganese halide for X-ray imaging.  JOURNAL OF LUMINESCENCE,      [PMID:] [10.1016/j.jlumin.2022.119130]

10. Hengbin Mao, Lei Wang, Junhui Li, Xin Jiang, Shiwei Xue, Mingliang Li, Jinpeng Zhu, Bingbing Fan, Tingting Xu, Gang Shao, Hongliang Xu, Hailong Wang, Rui Zhang, Hongxia Lu.  (2022)  High-Entropy Cs(Pb1/3Mn1/3Ni1/3)Br3 Perovskite Nanocrystals Prepared by High Energy Ball Milling and their Luminescence Properties.  PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION,  39  (9): (2200073).  [PMID:] [10.1002/ppsc.202200073]

11. Tao Huang, Qilin Wei, Wenchao Lin, Hui Peng, Shangfei Yao, Bingsuo Zou.  (2022)  High-efficient yellow-green emission in (TDMP)MnBr4 single crystal with modulation of spin-phonon-charge interactions.  Materials Today Physics,      [PMID:] [10.1016/j.mtphys.2022.100703]

12. Weijiang Gan, Bo-Mei Liu, Lin Huang, Sunqi Lou, Jian Zhang, Zhi Zhou, Jing Wang.  (2022)  Manganese Ion-Sensitized Near-Infrared Light in Cs2NaBi1−xErxCl6 Lead-Free Double Perovskite.  Advanced Optical Materials,  10  (9): (2102851).  [PMID:] [10.1002/adom.202102851]

13. Tongtong Kou, Qilin Wei, Wenyong Jia, Tong Chang, Chengyu Peng, Yi Liang, Bingsuo Zou.  (2022)  Light Emission Enhancement of (C3H10N)4Pb1–xMnxBr6 Metal-Halide Powders by the Dielectric Confinement Effect of a Nanosized Water Layer.  ACS Applied Materials & Interfaces,      [PMID:35073040] [10.1021/acsami.1c20584]

14. Tao Huang, Hui Peng, Qilin Wei, Chengyu Peng, Ye Tian, Shangfei Yao, Xinxin Han, Bingsuo Zou.  (2021)  Magnetic polaronic and bipolaronic excitons in Mn(II) doped (TDMP)PbBr4 and their high emission.  Nano Energy,      [PMID:] [10.1016/j.nanoen.2021.106863]

15. Hui Peng, Tao Huang, Bingsuo Zou, Ye Tian, Xinxin Wang, Yongchang Guo, Tiantian Dong, Zongmian Yu, Chunjie Ding, Fan Yang, Jianping Wang.  (2021)  Organic-inorganic hybrid manganese bromine single crystal with dual-band photoluminescence from polaronic and bipolaronic excitons.  Nano Energy,      [PMID:] [10.1016/j.nanoen.2021.106166]

16. Shuai Zhang, Hongli Liu, Xianggao Li, Shirong Wang.  (2020)  Enhancing the efficiency of green perovskite-QDs-based light-emitting devices by controlling interfacial defects with diamine molecules.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2020.126339]

17. Li Lingyan, Li Lei, Li Qianqian, Shen Yiming, Pan Shangke, Pan Jianguo.  (2020)  Synthesis, crystal structure and optical property of manganese (II) halides based on pyridine ionic liquids with high quantum yield.  TRANSITION METAL CHEMISTRY,  45  (6): (413-421).  [PMID:] [10.1007/s11243-020-00393-w]

18. Zhen Li, Li Li, Huali Liu, Fei Li, Jiaqi Zhao, Yu Wang.  (2020)  Strongly quantum-confined Mn2+-doped CsPbBr3 nanocrystals in MCM-41 with pure blue emission.  NEW JOURNAL OF CHEMISTRY,  44  (7): (2980-2985).  [PMID:] [10.1039/C9NJ06053G]

19. Zi-Lin He, Jun-Hua Wei, Jian-Bin Luo, Zhi-Zhong Zhang, Jing-Hua Chen, Xiu-Xian Guo, Dai-Bin Kuang.  (2024)  Guanidinium-Based Manganese(II) Bromide with High Glass-Forming Ability for Thermoplastic Curved X-ray Imaging.  Laser & Photonics Reviews,      [PMID:] [10.1002/lpor.202301249]

20. Ying Sun, Qian Ma, Dongheng Zhao, Pan Gao, Qi Wang, Zeyu Guo, Xiaomei Jiang.  (2024)  Modulation of halogens in organic manganese halides for high-resolution and large-area flexible X-ray imaging.  Inorganic Chemistry Frontiers,      [PMID:] [10.1039/D4QI02522A]

21. Jie Zhang, Meng-Ping Ren, Man Xu, Zhonghui Zhang, Mingxue An, Yang Lu, Xiao-Wu Lei, Zhongliang Gong, Cheng-Yang Yue.  (2024)  Ultrafast Visual Detection of a Trace Amount of Water by Highly Efficient Hybrid Manganese Halides.  ACS Applied Materials & Interfaces,      [PMID:38961579] [10.1021/acsami.4c05411]

22. Yongbao Xiao, Chong Wang.  (2025)  Hydrogen Bonding-Driven Structural Modulation in Narrowband Green-Emitting Mn2+ Hybrids for Enhanced X-ray Imaging Performance.  Journal of Materials Chemistry C,      [PMID:] [10.1039/D5TC01804H]

23. Liting Xu, Ruping Lu, Tingting Wang, Wei Liu, Yi Li, Yonggang Yang.  (2025)  Broadband Circularly Polarized Luminescence with a High Dissymmetry Factor.  INORGANIC CHEMISTRY,      [PMID:40737454] [10.1021/acs.inorgchem.5c01916]

24. Xiangyan Yun, Yujie Xie, Yukang Lu, Hanlin Hu, Yumeng Shi, Henan Li.  (2025)  Multimodal Luminescence in Antimony(III)-Doped Hybrid Manganese(II)-Based Compounds for Dynamic Anticounterfeiting Encryption and Optical Thermometry.  CHEMISTRY OF MATERIALS,      [PMID:] [10.1021/acs.chemmater.5c01141]

25. Zi-Lin He, Wen-Guang Li, Jing-Hua Chen, Jian-Bin Luo, Jun-Hua Wei, Qing-Peng Peng, Dai-Bin Kuang.  (2025)  Melt-Processing Enabled Flexible Metal Halide-Nylon Luminescent Films with Enhanced Optical Transmission for Curved X-Ray Imaging.  ADVANCED FUNCTIONAL MATERIALS,  35  (40): (2503523).  [PMID:] [10.1002/adfm.202503523]

26. Qing-Peng Peng, Zi-Lin He, Jing-Hua Chen, Jun-Hua Wei, Jian-Bin Luo, Tian-Chi Wang, Kong-Lan Chen, Dai-Bin Kuang.  (2025)  Organic-inorganic metal halide glass optical fibers for ultralow-loss and bendable photonic applications.  Matter,      [PMID:] [10.1016/j.matt.2025.102277]

27. Wei Liao, Xinquan Zhou, Jiance Jin, Yuzhen Wang, Zhiguo Xia.  (2024)  Screening Thermochromic Luminescent Materials in Cs-Cd-Br Ternary Phase Diagram for Temperature Visualization Applications.  Laser & Photonics Reviews,      [PMID:] [10.1002/lpor.202400194]

28. Meiqing Yan, Jiapeng Yang, Enrou Mei, Ye He, Zhaoping Chen, Weiwei Huan, Xiaojuan Liang, Weidong Xiang.  (2025)  Zn-Doped Organic–Inorganic Hybrid Mn(II) Halides with Ultra-High PLQY and Stability for Eco-Friendly Display Backlights.  ACS Sustainable Chemistry & Engineering,      [PMID:] [10.1021/acssuschemeng.4c08832]

29. Zi-Lin He, Jian-Bin Luo, Jing-Hua Chen, Jun-Hua Wei, Xiao-He Miao, Zhi-Zhong Zhang, Qing-Peng Peng, Xiu-Xian Guo, Dai-Bin Kuang.  (2025)  A universal strategy toward two-component organic-inorganic metal halide luminescent glasses and glass-crystal composites.  Science Advances,  11  (22):   [PMID:40435246] [10.1126/sciadv.adu1982]

30. Mengyu Guan, Ranran Bu, Haizhen Song, Changyuan Xu, Yichao Wang, Yan Zhang, Hongming Yin.  (2025)  Study on the effect of different crystal forms of benzamide on the luminescence properties of Mn2+ in organic-inorganic hybrid metal halides.  CURRENT APPLIED PHYSICS,      [PMID:] [10.1016/j.cap.2025.06.007]

31. Linyuan Lian, Daming Xiong, Jibin Zhang, Mochen Jia, Ying Liu, Zhuangzhuang Ma, Xu Chen, Yanbing Han, Yongtao Tian, Xinjian Li, Jianbing Zhang, Zhifeng Shi.  (2025)  Solubility-Driven Rapid and Large-Scale Synthesis of Solvatochromic Luminescent Organic–Inorganic Manganese(II)-Based Halides for Advanced Anti-Counterfeiting.  Laser & Photonics Reviews,      [PMID:] [10.1002/lpor.202500509]

32. Qingkun Kong, Xiaochen Wang, Wuyang Fan, Yangqing Wu, Xin Xu, Junsheng Chen.  (2025)  Cesium Alloying-Enhanced Stimuli-Responsive Photoluminescence in CsxRb2–xMnBr4(H2O)2 for Information Encryption.  ACS Applied Electronic Materials,      [PMID:] [10.1021/acsaelm.5c00773]

33. Zhe Feng, Haixia Cui, Yurou Yan, Shujuan Liu, Qiang Zhao.  (2025)  Flexible Mn(II)-Based Halide Scintillation Screen for High-Resolution X-Ray Imaging of Nonplanar Objects.  Laser & Photonics Reviews,      [PMID:] [10.1002/lpor.202500885]

34. Jia Liu, Long Yu, Xiaoyun Yi, Xin Li, Ziqing Liu, He Wang, Linwei Yang, Xin Yang, Suhua Wang.  (2025)  Polarity-enhanced cationic π-conjugation in Mn(II)-based metal halide luminescent materials: boosting quantum yield and enabling anti-counterfeiting.  Inorganic Chemistry Frontiers,      [PMID:] [10.1039/D5QI01981H]

35. Fuwei Shang, Youkui Xu, Feifei Chai, Xiushan Wang, Xingxuan Zuo, Mengge Zhao, Lin Zheng, ZhenHua Li, Zhun Yao.  (2026)  Extended Dual-Functional Engineering for High-Performance 2D Dion–Jacobson CsPbI3 Perovskite Solar Cells with Enhanced Stability.  CHEMISTRY OF MATERIALS,      [PMID:] [10.1021/acs.chemmater.5c02724]

36. Li Sisi, Luo Kaitong, Zhou Yali, Wang Junhao, Zhang Zhen, Liu Zhao-Qing, Chen Yibo.  (2026)  Substitution of free halide ions unlocks responsive photoluminescence switching in manganese-based metal halides.  Light-Science & Applications,  15  (1): (105).  [PMID:41639042] [10.1038/s41377-025-02161-w]

37. Jinwei Li, Yuling Jin, Zhihuang Xu, Liwang Ye, Diwai Wu, Kailun Yan, Xinxin Zhuang.  (2026)  Mn(Ⅱ)-doped zero-dimensional hybrid Cd bromide with efficient green emission.  NEW JOURNAL OF CHEMISTRY,      [PMID:] [10.1039/D6NJ00543H]