Tetrakis(triphenylphosphine)platinum(0) - Pt 15.2% , CAS No.14221-02-4

CAS: 14221-02-4 Cat. No.: T107487 Molecular Weight: 1244.22 EC Number: 238-087-4 PubChem CID: 11979705

GRADE & PURITY Pt 15.2%

Synonyms

Pt(PPh3)4 | platinum;triphenylphosphane | Pt(PPh3)4 | Tetrakis(triphenylphosphine)platinum (0) | SY005470 | Tetrakis(triphenylphosphine)platinum | J-524886 | Platinum tetratriphenylphosphine | PLATINUM(0)-TETRAKIS(TRIPHENYLPHOSPHINE);PT(PPH3)4;TETRAKIS(TR

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Overview

Used as a precursor to platinum complexes.

Specifications

Synonyms

Pt(PPh3)4 | platinum;triphenylphosphane | Pt(PPh3)4 | Tetrakis(triphenylphosphine)platinum (0) | SY005470 | Tetrakis(triphenylphosphine)platinum | J-524886 | Platinum tetratriphenylphosphine | PLATINUM(0)-TETRAKIS(TRIPHENYLPHOSPHINE);PT(PPH3)4;TETRAKIS(TR

Specifications & Purity

Pt 15.2%

Storage

Store at 2-8°C, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Names and Identifiers

• Pubchem Sid: 504766858
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504766858
• Canonical Smiles: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Pt]
• IUPAC Name: platinum;triphenylphosphane
• InChIKey: SYKXNRFLNZUGAJ-UHFFFAOYSA-N
• INCHI: 1S/4C18H15P.Pt/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H
• Isomeric SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Pt]
• WGK Germany: 3
• PubChem CID: 11979705
• Molecular Weight: 1244.22
• Reaxy-Rn: 13326331

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Class Benzene and substituted derivatives
      • Subclass Phenylphosphines and derivatives

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Class: Benzene and substituted derivatives
• Subclass: Phenylphosphines and derivatives
• Intermediate Tree Nodes: Not available
• Direct Parent: Phenylphosphines and derivatives
• Alternative Parents: Organic phosphines and derivatives Organic transition metal salts Hydrocarbon derivatives
• Molecular Framework: Not available
• Substituents: Triphenylphosphine - Phenylphosphine - Phosphine - Organic transition metal salt - Hydrocarbon derivative - Organophosphorus compound - Aromatic homomonocyclic compound
• Description: This compound belongs to the class of organic compounds known as phenylphosphines and derivatives. These are compounds containing a phenylphosphine, which consists of phosphine substituent bound to a phenyl group.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Sensitivity: heat sensitive, air sensitive,light sensitive
• Molecular Weight: 1244.200 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 12
• Exact Mass: 1243.33 Da
• Monoisotopic Mass: 1243.33 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 77
• Formal Charge: 0
• Complexity: 202.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 5

XLogP3

References

1. Pengzhong Shi, Jiawei Wang, Zhiyong Guo.  (2022)  A one-dimensional covalent organic framework film for near-infrared electrochromism.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2022.139082]

2. Jianai Chen, Sijie Tan, Yue Yu, Shitong Zhang, Weijun Li, Qingbao Song, Yujie Dong, Cheng Zhang, Wai-Yeung Wong.  (2021)  Direct observation of excited state conversion in solid state from a TICT-Type mechanochromic luminogen.  JOURNAL OF LUMINESCENCE,      [PMID:] [10.1016/j.jlumin.2021.118179]

3. Mingyi Guan, Hui Li, Man Tu, Chenchen Fu, Xiyu Yang, Feng Wang.  (2024)  A novel fluorescent “Off-On” probe based on phenanthro[9,10-d]imidazole conjugated polymers (PIPF) for Cr3+ detection with high selectivity and sensitivity.  SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,      [PMID:38324948] [10.1016/j.saa.2024.123988]

4. Jianai Chen, Mingjiao Sun, Yujie Dong, Weijun Li, Fener Chen.  (2024)  Dual-response signal under mechanical stimulation: Alkyl substituent effect on the fine-tuning of molecular packing.  JOURNAL OF LUMINESCENCE,      [PMID:] [10.1016/j.jlumin.2024.120866]