2-Cyanobenzylzinc bromide solution - 0.5M in THF , CAS No.199465-66-2

CAS: 199465-66-2 Cat. No.: C465908 Molecular Weight: 261.43 PubChem CID: 5073752

GRADE & PURITY 0.5M in THF

Storage

Store at 2-8°C

Shipped In

Wet ice

Overview

Description

2-Cyanobenzylzinc bromide can be used as a reactant:In the metal-catalyzed Negishi cross-coupling reactions to prepare aryl or heteroaryl derivatives via carbon-carbon bond formation.To synthesize 4-(2-Cyanobenzyl)-3′-(trifluoromethyl)biphenyl by reacting with aryl nonaflate in the presence of Pd(dba)2as a catalyst.To prepare 2-[(2-cyanophenyl)methyl] benzamide by treating with 2-iodobenzamide using a nickel catalyst.

Specifications

Specifications & Purity

0.5M in THF

Legal Information

Rieke® Metals, Inc. 产品 ®Rieke Metals, Inc. 的注册商标

Storage

Store at 2-8°C

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Names and Identifiers

• Canonical Smiles: [CH2-]C1=CC=CC=C1C#N.[Zn+]Br
• IUPAC Name: bromozinc(1+);2-methanidylbenzonitrile
• InChIKey: FRRLGGRYFJXNSD-UHFFFAOYSA-M
• INCHI: 1S/C8H6N.BrH.Zn/c1-7-4-2-3-5-8(7)6-9;;/h2-5H,1H2;1H;/q-1;;+2/p-1
• Isomeric SMILES: [CH2-]C1=CC=CC=C1C#N.[Zn+]Br
• WGK Germany: 3
• PubChem CID: 5073752
• Molecular Weight: 261.43

Chemical and Physical Properties

• Flash Point(°F): 1.4 °F
• Flash Point(°C): -17 °C