4,4′-Methylene-bis(2-chloroaniline) - 1000μg/ml,in Purge and Trap Methanol , CAS No.101-14-4

CAS: 101-14-4 Cat. No.: M141213 Molecular Weight: 267.15 Beilstein Registry Number: 1882318 EC Number: 202-918-9
AVAILABLE TO ORDER
GRADE & PURITY 1000μg/ml,in Purge and Trap Methanol
Synonyms
3,3'-Dichloro-4,4'-diaminodiphenylmethane 4,4'-Bis(2-chloroanilino)methane 4,4'-Diamino-3,3'-dichlorodiphenylmethane
Storage
Room temperature
Shipped In
FedEx DG Service
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Size
Status
Price
Qty
1ml
M141213-1ml
5

$117.90

$172.90
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Why this grade

1000μg/ml,in Purge and Trap Methanol for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

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Storage & shipping

Room temperature Ships FedEx DG Service Check lot-specific COA for exact specifications.

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Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

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Literature proof

Cited in 13 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Specifications

Synonyms
3, 3'-Dichloro-4, 4'-diaminodiphenylmethane 4, 4'-Bis(2-chloroanilino)methane 4, 4'-Diamino-3, 3'-dichlorodiphenylmethane
Specifications & Purity
1000μg/ml, in Purge and Trap Methanol
Storage
Room temperature
Shipped In
FedEx DG Service
This product requires cold chain shipping. Ground and other economy services are not available.
Names and Identifiers
Isomeric SMILES C1=CC(=C(C=C1CC2=CC(=C(C=C2)N)Cl)Cl)N
WGK Germany 3
UN Number 3077
Packing Group III
Molecular Weight 267.15
Beilstein 1882318
Reaxy-Rn 1882318
Reaxys-RN_link_address https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=1882318&ln=

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

Download SDS →

✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

Look up COA →

📊 Datasheet

Quick-reference summary of product specifications and applications.

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🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

View spec sheet →

Advanced Data

Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:
Chemical and Physical Properties
Flash Point(°C)113°C
Boil Point(°C)202-214°C
Melt Point(°C)102-107°C
Documents & Articles
Citations of This Product
References
1. Yanjie Zheng, Keli Wang, Lei Sun, Huili Shi, Xia Zhang.  (2022)  Preparation of PFDTS-kaolin/PU superamphiphobic coatings with antibacterial, antifouling and improved durability property.  PROGRESS IN ORGANIC COATINGS,      [PMID:] [10.1016/j.porgcoat.2022.107145]
2. Meng Jia, Fan Zhang, Aimin Sha, Zhe Li, Wentong Wang, Wenxiu Jiao.  (2025)  Structural control and performance evaluation of polyurethane-based solid–solid phase change materials for thermal regulation of asphalt pavements in high-temperature climate conditions.  Journal of Energy Storage,      [PMID:] [10.1016/j.est.2025.118182]
3. Lijing Lu, Haoyue Ning, Jipeng Guo, Chuang Guo, Liao Pan, Lixin Lu.  (2023)  Synthesis, Evaluation, and Electrochemical Detection Application of Magnetic Molecularly Imprinted Polymers for 4,4-Methylenedianiline from Food-Contact Materials.  ADVANCES IN POLYMER TECHNOLOGY,      [PMID:] [10.1155/2023/9306542]
4. Tianhong Yang, Zhaoyi He, Gang Huang, Yongli Zhao, Jianwei Fu, Hao Xiang, Yingju Zhou.  (2023)  Study on materials composition and process parameters of polyurethane-modified asphalt synthesized in-situ by the one-shot process.  CONSTRUCTION AND BUILDING MATERIALS,      [PMID:] [10.1016/j.conbuildmat.2023.130661]
5. Wenxiu Jiao, Aimin Sha, Jin Zhang, Meng Jia, Wei Jiang, Liqun Hu.  (2023)  Design and properties of polyurethane solid–solid phase-change granular temperature regulation asphalt mixtures.  SOLAR ENERGY,      [PMID:] [10.1016/j.solener.2023.02.008]
6. Yaochen Zheng, Peng Song, Shaoxiang Liu, Mengqing Wu, Hui Xu, Chenghui Qiao, Jian Liu, Zhengguo Gao, Qingfu Ban.  (2021)  Transparent and toughening epoxy thermosets modified by linear telechelic polymer containing rigid spiroacetal moieties: Uncovering the relationship between the heterogeneous crosslinked network and thermoset performances.  JOURNAL OF POLYMER SCIENCE,  59  (13): (1390-1398).  [PMID:] [10.1002/pol.20210178]
7. Xiongwei Wang, Peiyi Wu.  (2019)  3D Vertically Aligned BNNS Network with Long-Range Continuous Channels for Achieving a Highly Thermally Conductive Composite.  ACS Applied Materials & Interfaces,      [PMID:31361947] [10.1021/acsami.9b09398]
8. Ziming Shen, Jiachun Feng.  (2019)  Preparation of Thermally Conductive Polymer Composites with Good Electromagnetic Interference Shielding Efficiency Based on Natural Wood-Derived Carbon Scaffolds.  ACS Sustainable Chemistry & Engineering,      [PMID:] [10.1021/acssuschemeng.8b06661]
9. Ziming Shen, Jiachun Feng.  (2018)  Achieving vertically aligned SiC microwires networks in a uniform cold environment for polymer composites with high through-plane thermal conductivity enhancement.  COMPOSITES SCIENCE AND TECHNOLOGY,      [PMID:] [10.1016/j.compscitech.2018.11.036]
10. Shusheng Chen, Bin Chen, Jiashu Fan, Jiachun Feng.  (2015)  Exploring the Application of Sustainable Poly(propylene carbonate) Copolymer in Toughening Epoxy Thermosets.  ACS Sustainable Chemistry & Engineering,      [PMID:] [10.1021/acssuschemeng.5b00343]
11. Jiading Wang, Shaoyun Guo, Xianlong Zhang.  (2024)  Broken Chain Self-Reconnection Strategy Enables Radiation Ultraresistance of Polyurethane.  MACROMOLECULES,      [PMID:] [10.1021/acs.macromol.4c02557]
12. Yan Zhou, Weibo Liu, Yu Feng, Pengfei Shi, Liqiang Wan, Xufeng Hao, Farong Huang, Jianhua Qian, Zuozhen Liu.  (2025)  The Effect of the Structure of Aromatic Diamine on High-Performance Epoxy Resins.  Journal of Composites Science,  (8): (416).  [PMID:] [10.3390/jcs9080416]
13. Jiao Yuchen, Zhou Ming, Pu Bo, Yang Xiaoling, Li Chenyiting, Xia Liangliang, Deng Guilin, Wei Yunyao, Zhong Jing, Wu Zheng, Chen Shi, Wang Jian, Zhou Yujun.  (2026)  Preparation of room-temperature self-healing recyclable polyurethane elastomers based on a multiple hydrogen/nitrogen coordination boro-oxygen bonds system.  JOURNAL OF POLYMER RESEARCH,  33  (3): (114).  [PMID:] [10.1007/s10965-025-04746-w]
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