4,8-Dimethyl-2-phosphabicyclo[3.3.1]nonane - ≥90% , CAS No.328952-85-8

CAS: 328952-85-8 Cat. No.: D282254 Molecular Weight: 170.2

GRADE & PURITY ≥90%

Synonyms

SCHEMBL5737867 | 4,8-dimethyl-2-phosphabicyclo[3.3.1]nonane | 2-Phosphabicyclo[3.3.1]nonane, 4,8-dimethyl- | MFCD32697139 | DTXSID40627558

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Overview

4,8-Dimethyl-2-phosphabicyclo[3.3.1]nonane is a clear, colorless, air-sensitive liquid with a lemon-like odor and a boiling point of 120 °C. 4,8-Dimethyl-2 phosphabicyclo[3.3.1]nonane is a powerful reducing agent and must be handled under an inert atmosphere.
4,8-Dimethyl-2-phosphabicyclo[3.3.1]nonane  finds application mainly as a building block for other phosphine derivatives, which are used as ligands in various homogeneous catalytic processes.

Purpose：

1. 4,8-Dimethyl-2-phosphabicyclo[3.3.1]nonane is used to synthesize hindered tertiary phosphines via the addition of an olefin using free radical initiators.
2. These tertiary phosphines have been used as ligands for cobalt-catalyzed hydroformylation.
3. 4,8-Dimethyl-2-phosphabicyclo[3.3.1]nonane can also be used to make bidentate phosphine ligands by its’ reaction with dihaloorganics, such as dibromo-oxylene, the palladium complexes of these ligands finding utility as catalysts.

Specifications

Synonyms

SCHEMBL5737867 | 4, 8-dimethyl-2-phosphabicyclo[3.3.1]nonane | 2-Phosphabicyclo[3.3.1]nonane, 4, 8-dimethyl- | MFCD32697139 | DTXSID40627558

Specifications & Purity

≥90%

Legal Information

Sold in collaboration with Solvay.

Storage

Store at 2-8°C, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥90%

Names and Identifiers

• Canonical Smiles: CC1CCC2CC1PCC2C
• IUPAC Name: 4,8-dimethyl-2-phosphabicyclo[3.3.1]nonane
• InChIKey: ZFQDZRKZDDYFJO-UHFFFAOYSA-N
• INCHI: 1S/C10H19P/c1-7-3-4-9-5-10(7)11-6-8(9)2/h7-11H,3-6H2,1-2H3
• Isomeric SMILES: CC1CCC2CC1PCC2C
• Molecular Weight: 170.2
• Reaxy-Rn: 33036810
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=33036810&ln=

Chemical and Physical Properties

• Sensitivity: air sensitive, moisture sensitive
• Flash Point(°C): 221°F
• Boil Point(°C): 120°C
• Melt Point(°C): -22°C