Chloro(triphenylphosphine)gold(I) - ≥98% , CAS No.14243-64-2

CAS: 14243-64-2 Cat. No.: C118793 Molecular Weight: 494.71 EC Number: 238-117-6

GRADE & PURITY ≥98%

Synonyms

(Ph3P)AuCl | chlorogold; triphenylphosphane;CHloro(triphenylphosphine)gold(I) | A807907 | J-007651 | MFCD00009588 | chlorogold;triphenylphosphane | Triphenylphosphinechlorogold | Chloro(triphenylphosphane)gold(I) | Chloro(triphenylphosphine)gold(I), Premi

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Overview

Chloro(triphenylphosphine)gold(I) is a common reagent in gold chemistry. It catalyzes certain rearrangement reactions in organic synthesis. It is also used to prepare 1-methylthyminato-N3-triphenylphosphinegold(I) by reacting with 1-methylthymine. It acts as a precursor for the synthesis of gold(I) and gold(III) organometallic compounds.

Specifications

Synonyms

(Ph3P)AuCl | chlorogold; triphenylphosphane;CHloro(triphenylphosphine)gold(I) | A807907 | J-007651 | MFCD00009588 | chlorogold;triphenylphosphane | Triphenylphosphinechlorogold | Chloro(triphenylphosphane)gold(I) | Chloro(triphenylphosphine)gold(I), Premi

Specifications & Purity

≥98%

Storage

Store at 2-8°C, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥98%

Names and Identifiers

• Canonical Smiles: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Au]
• IUPAC Name: chlorogold;triphenylphosphane
• InChIKey: IFPWCRBNZXUWGC-UHFFFAOYSA-M
• INCHI: 1S/C18H15P.Au.ClH/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h1-15H;;1H/q;+1;/p-1
• Isomeric SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Au]
• WGK Germany: 3
• Molecular Weight: 494.71
• Reaxy-Rn: 14384071

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Class Benzene and substituted derivatives
      • Subclass Phenylphosphines and derivatives

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Class: Benzene and substituted derivatives
• Subclass: Phenylphosphines and derivatives
• Intermediate Tree Nodes: Not available
• Direct Parent: Phenylphosphines and derivatives
• Alternative Parents: Organic phosphines and derivatives Organic transition metal salts Organic metal halides Organopnictogen compounds Organic chloride salts Hydrocarbon derivatives
• Molecular Framework: Aromatic homomonocyclic compounds
• Substituents: Triphenylphosphine - Phenylphosphine - Phosphine - Organic metal halide - Organic transition metal salt - Organopnictogen compound - Hydrocarbon derivative - Organic chloride salt - Organic salt - Organophosphorus compound - Aromatic homomonocyclic compound
• Description: This compound belongs to the class of organic compounds known as phenylphosphines and derivatives. These are compounds containing a phenylphosphine, which consists of phosphine substituent bound to a phenyl group.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Soluble in methylene chloride, acetonitrile, benzene and acetone. Insoluble in water and ethanol.
• Sensitivity: Light sensitive;Moisture sensitive
• Melt Point(°C): 245.0 to 249.0 °C
• Molecular Weight: 494.700 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 494.027 Da
• Monoisotopic Mass: 494.027 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 21
• Formal Charge: 0
• Complexity: 204.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

References

1. Li Huiyong, Hu Dafeng, Zheng Zemin, Jiang Hao, Lu Jiangwei, Geng Xuemin, Zhang Xudong, Wan Yanfen, Yang Peng.  (2020)  Primary growth of binary nanoparticle superlattices with distinct systems contingent on synergy: softness and crystalline anisotropy.  Applied Nanoscience,  10  (5): (1653-1666).  [PMID:] [10.1007/s13204-019-01244-6]

2. Zhang Xudong, Ma Su, Li Aikun, Chen Linya, Lu Jiangwei, Geng Xuemin, Xie Ming, Liang Xiaoyu, Wan Yanfen, Yang Peng.  (2019)  Continuous high-flux synthesis of gold nanoparticles with controllable sizes: a simple microfluidic system.  Applied Nanoscience,  10  (3): (661-669).  [PMID:] [10.1007/s13204-019-01214-y]

3. Xu Yueshan, Wu Daoxiong, Zhang Qinghua, Rao Peng, Deng Peilin, Tang Mangen, Li Jing, Hua Yingjie, Wang Chongtai, Zhong Shengkui, Jia Chunman, Liu Zhongxin, Shen Yijun, Gu Lin, Tian Xinlong, Liu Quanbing.  (2024)  Regulating Au coverage for the direct oxidation of methane to methanol.  Nature Communications,  15  (1): (1-10).  [PMID:38233390] [10.1038/s41467-024-44839-6]