1.0 M in methylene chloride for sensitive chromatographic and analytical workflows requiring minimal baseline interference.
Store at 2-8°C,Argon charged Ships Wet ice Check lot-specific COA for exact specifications.
SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.
Cited in 4 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.
Diisobutylaluminum hydride is a reducing agent for many functional groups commonly used in organic synthesis.
Application
Diisobutylaluminum hydride solution (1 M in dichloromethane) has been used in the conversion of esters into α-fluoro-α,β-unsaturated esters in the presence of fluorocarboalkoxy-substituted dialkyl phosphonate anions via Horner-Wadsworth-Emmons reaction. It can be used in the multi-step synthesis of ( S )-2-methyl tetrahydropyridine- N -oxide, a key structural moiety of bio-active compounds like himbacine and solenopsin-A. Used in Pd-catalyzed reductive debromination of secondary alkyl bromides. O -Debenzylation and ring opening of perbenzylated furanosides. Convenient in situ generation of HZrCp 2 Cl from ZrCp 2 Cl 2 and DIBAL-H.
| Isomeric SMILES | C(CN(C(=O)C1=C(C(=C(C(=C1I)C(=O)NCC(CN(CC(CO)O)C(=O)C2=C(C(=C(C(=C2I)C(=O)NCC(CO)O)I)NC(=O)CO)I)O)I)NC(=O)CO)I)O)CO |
|---|---|
| WGK Germany | 2 |
| PubChem CID | 87569325 |
| Molecular Weight | 142.22 |
| Beilstein | 4123663 |
Comprehensive hazard, handling, storage, and regulatory compliance document.
Download SDS →Lot-specific quality data. Enter your lot number to retrieve the exact COA.
Look up COA →Full quality attributes and acceptance criteria for this grade.
View spec sheet →| Sensitivity | Moisture sensitive |
|---|---|
| Flash Point(°F) | 39.2 °F |
| Flash Point(°C) | -18 °C |
| Boil Point(°C) | 116-118 °C |
| 1. Jing Ren, Fangbing Wang, Miao Wu, Ya Cheng, Guoyue Shi. (2023) A high-throughput femtosecond laser-engineered 3D microfluidic chip for efficient chemical transformation of carbon dioxide to value-added chemicals. CHEMICAL ENGINEERING JOURNAL, [PMID:] [10.1016/j.cej.2023.146758] |
| 2. Dongyang Chen, Hongli Shen, Dongchu Chen, Nanjie Chen, Yuezhong Meng. (2023) Highly Soluble Dimethoxymethyl Tetrathiafulvalene with Excellent Stability for Non-Aqueous Redox Flow Batteries. ACS Applied Materials & Interfaces, [PMID:37341213] [10.1021/acsami.3c05387] |
| 3. Li Dong, Xiangdong Liu, Zhengrong Xiong, Dekun Sheng, Yan Zhou, Changhong Lin, Yuming Yang. (2017) Design of UV-absorbing PVDF membrane via surface-initiated AGET ATRP. APPLIED SURFACE SCIENCE, [PMID:] [10.1016/j.apsusc.2017.11.135] |
| 4. Xing Long, Ya-Shuo Chen, Qian Zheng, Xing-Xiao Xie, Hao Tang, Li-Ping Jiang, Juan-Tao Jiang, Jian-Hua Qiu. (2019) Removal of iodine from aqueous solution by PVDF/ZIF-8 nanocomposite membranes. SEPARATION AND PURIFICATION TECHNOLOGY, [PMID:] [10.1016/j.seppur.2019.116488] |
A2616078