Fenitrothion - analytical standard , CAS No.122-14-5

CAS: 122-14-5 Cat. No.: F294872 Molecular Weight: 277.23 Beilstein Registry Number: 8983553 EC Number: 204-524-2
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GRADE & PURITY Analytical standard ? Analytical standard — certified-purity material for quantitative calibration. Use to prepare calibration standards and validate analytical methods.
Synonyms
Owadophos | Cekutrothion | Verthion | Akotion | Fenitox | Sumithion | Ovadofos | Owadofos | FENITROTHION | Methylnitrophos | Nitrophos | Sumifene | Metathionine | Nuvanol | Metathione | Folithion | Agrothion | Arbogal | Oleosumifene | Accothion | Phenitro
Storage
Store at -20°C
Shipped In
Ice chest + Ice pads
 ·  off list, applied to all prices below.
Size
Status
Price
Qty
250mg
F294872-250mg
5
$79.90
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Why this grade

analytical standard Analytical standard for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

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Storage & shipping

Store at -20°C Ships Ice chest + Ice pads Check lot-specific COA for exact specifications.

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Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

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Literature proof

Cited in 32 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Specifications

Synonyms
Owadophos | Cekutrothion | Verthion | Akotion | Fenitox | Sumithion | Ovadofos | Owadofos | FENITROTHION | Methylnitrophos | Nitrophos | Sumifene | Metathionine | Nuvanol | Metathione | Folithion | Agrothion | Arbogal | Oleosumifene | Accothion | Phenitro
Specifications & Purity
analytical standard
Storage
Store at -20°C
Shipped In
Ice chest + Ice pads
This product requires cold chain shipping. Ground and other economy services are not available.
Grade
Analytical standard
Names and Identifiers
Canonical SmilesCC1=C(C=CC(=C1)OP(=S)(OC)OC)[N+](=O)[O-]
IUPAC Namedimethoxy-(3-methyl-4-nitrophenoxy)-sulfanylidene-λ5-phosphane
InChIKeyZNOLGFHPUIJIMJ-UHFFFAOYSA-N
INCHI1S/C9H12NO5PS/c1-7-6-8(4-5-9(7)10(11)12)15-16(17,13-2)14-3/h4-6H,1-3H3
Isomeric SMILES CC1=C(C=CC(=C1)OP(=S)(OC)OC)[N+](=O)[O-]
UN Number 3017
Packing Group I
Molecular Weight 277.23
Beilstein 8983553
Reaxy-Rn 1887367
Reaxys-RN_link_address https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=1887367&ln=

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

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✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

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📊 Datasheet

Quick-reference summary of product specifications and applications.

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🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

View spec sheet →

Advanced Data

Taxonomic Classification

Taxonomy Tree

KingdomOrganic compounds
SuperclassOrganic acids and derivatives
ClassOrganic thiophosphoric acids and derivatives
SubclassThiophosphoric acid esters
Intermediate Tree Nodes Aryl thiophosphates
Direct ParentPhenyl thiophosphates
Alternative Parents Nitrotoluenes  Nitrobenzenes  Thiophosphate triesters  Phenoxy compounds  Nitroaromatic compounds  Propargyl-type 1,3-dipolar organic compounds  Organic oxoazanium compounds  Organopnictogen compounds  Organooxygen compounds  Organonitrogen compounds  Organic oxides  Hydrocarbon derivatives  
Molecular FrameworkAromatic homomonocyclic compounds
Substituents Phenyl thiophosphate - Nitrobenzene - Nitrotoluene - Phenoxy compound - Nitroaromatic compound - Thiophosphate triester - Toluene - Monocyclic benzene moiety - Benzenoid - C-nitro compound - Organic nitro compound - Organic oxoazanium - Organic 1,3-dipolar compound - Propargyl-type 1,3-dipolar organic compound - Allyl-type 1,3-dipolar organic compound - Organic nitrogen compound - Hydrocarbon derivative - Organooxygen compound - Organonitrogen compound - Organic oxide - Organopnictogen compound - Organic oxygen compound - Aromatic homomonocyclic compound
DescriptionThis compound belongs to the class of organic compounds known as phenyl thiophosphates. These are organothiophosphorus compounds that contain a thiophosphoric acid O-esterified with a phenyl group.
External Descriptors a small molecule
3D Structure
Interactive Chemical Structure Model





Associated Targets(Human)
VDR Tclin Vitamin D receptor (26531 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
POLK Tbio DNA polymerase kappa (8653 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Associated Targets(non-human)
Abcc1 Multidrug resistance-associated protein 1 (42 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Musca domestica (713 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Spodoptera litura (1708 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Tribolium castaneum (596 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Nfe2l2 Nuclear factor erythroid 2-related factor 2 (214 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
ffp 4'-phosphopantetheinyl transferase ffp (24982 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Chilo suppressalis (440 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Laodelphax striatellus (278 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Culex pipiens pallens (759 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Cheumatopsyche (45 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Nephotettix cincticeps (805 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Daphnia magna (43 Activities)
Activity TypeRelationActivity valueUnitsAction TypeJournalPubMed IddoiAssay Aladdin ID
Mechanisms of Action
Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

7 results found

Lot NumberCertificate TypeDateItem
F2601327Certificate of AnalysisMay 22, 2026 F294872
E2516632Certificate of AnalysisMay 07, 2025 F294872
K2425427Certificate of AnalysisSep 10, 2024 F294872
G2426432Certificate of AnalysisJul 12, 2024 F294872
G2318783Certificate of AnalysisJun 21, 2023 F294872
D2303982Certificate of AnalysisJan 17, 2023 F294872
G2207227Certificate of AnalysisJun 13, 2022 F294872
Chemical and Physical Properties
Refractive Index1.5528
Flash Point(°C)>100°C
Boil Point(°C)140-145°C
Molecular Weight277.240 g/mol
XLogP33.300
Hydrogen Bond Donor Count0
Hydrogen Bond Acceptor Count6
Rotatable Bond Count4
Exact Mass277.017 Da
Monoisotopic Mass277.017 Da
Topological Polar Surface Area106.000 Ų
Heavy Atom Count17
Formal Charge0
Complexity313.000
Isotope Atom Count0
Defined Atom Stereocenter Count0
Undefined Atom Stereocenter Count0
Defined Bond Stereocenter Count0
Undefined Bond Stereocenter Count0
The total count of all stereochemical bonds0
Covalently-Bonded Unit Count1
Citations of This Product
References
1. Shuhua Li, Jizhong Wu, Shen Zhang, Tianhui Jiao, Jie Wei, Xiaomei Chen, Qingmin Chen, Quansheng Chen.  (2023)  Inner filter effect-based upconversion nanosensor for rapid detection of thiram pesticides using upconversion nanoparticles and dithizone–cadmium complexes.  FOOD CHEMISTRY,      [PMID:37713750] [10.1016/j.foodchem.2023.137438]
2. Li Wang, Yi Pan, Zhengwu Wang, Yuanfeng Wang, Xinlin Wei.  (2023)  Ultrasensitive Fluorescence Platform Based on AgNPs In Situ-Incorporated Zr-MOFs for the Detection of Organophosphorus Pesticides.  ACS Applied Materials & Interfaces,      [PMID:37676637] [10.1021/acsami.3c09354]
3. Xiaoyu Su, Kaiyi Zheng, Xiaoyu Tian, Xuan Zhou, Xiaobo Zou, Xuechao Xu, Zongbao Sun, Wen Zhang.  (2023)  An advanced ratiometric molecularly imprinted sensor based on metal ion reoxidation for indirect and ultrasensitive glyphosate detection in fruit.  FOOD CHEMISTRY,      [PMID:37481984] [10.1016/j.foodchem.2023.136927]
4. Yanping Li, Qiong Hu, Jihui Zhang, Hong Zhou, Na Wang, Yishan Fang, Bo Cui.  (2023)  T4PPVB-COP composite-driven innovative electrochemiluminescence aptasensor for ultra-sensitive detection of chlorpyrifos.  FOOD CHEMISTRY,      [PMID:37390738] [10.1016/j.foodchem.2023.136713]
5. Lei Jiang, Lin Yuan, Shan Gao, Yingying Xiang, Fei Song, Wensi Ma, Jing Wan, Xiuling Ji, Yujiao Tu.  (2023)  Facile hydrothermal synthesis of N-doped fluorescent carbon dots for selective detection of insecticide parathion.  Analytical Methods,  15  (19): (2376-2381).  [PMID:37132329] [10.1039/D3AY00124E]
6. Wanqi Jiang, Zan Yang, Fei Tong, Siyu Zhang, Lu Zhu, Lei Wang, Lunjing Huang, Kang Liu, Mingming Zheng, Yibin Zhou, Ruyan Hou, Yingnan Liu.  (2023)  Two birds with one stone: An enzyme-regulated ratiometric fluorescent and photothermal dual-mode probe for organophosphorus pesticide detection.  BIOSENSORS & BIOELECTRONICS,      [PMID:36638562] [10.1016/j.bios.2023.115074]
7. Shang Shuqi, Wang Dongwei, Wang Jiasheng.  (2022)  Electrochemical determination of acetamiprid using PEDOT sensing coating functionalized with carbon quantum dots and Prussian blue nanoparticles.  MICROCHIMICA ACTA,  189  (9): (1-9).  [PMID:35997821] [10.1007/s00604-022-05434-y]
8. Shaofeng Yuan, Fangwei Yang, Hang Yu, Yunfei Xie, Yahui Guo, Weirong Yao.  (2022)  Ultrasonic stimulation of milk fermentation: effects on degradation of pesticides and physiochemical, antioxidant, and flavor properties of yogurt.  JOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE,  102  (14): (6612-6622).  [PMID:35596658] [10.1002/jsfa.12028]
9. Xiudan Hou, Rong Ding, Shihai Yan, Haiyan Zhao, Qingli Yang, Wei Wu.  (2021)  ZrO2 Nanoparticles and Poly(diallyldimethylammonium chloride)-Doped Graphene Oxide Aerogel-Coated Stainless-Steel Mesh for the Effective Adsorption of Organophosphorus Pesticides.  Foods,  10  (7): (1616).  [PMID:34359486] [10.3390/foods10071616]
10. Shaofeng Yuan, Changjian Li, Hang Yu, Yunfei Xie, Yahui Guo, Weirong Yao.  (2021)  Selective uptake determines the variation in degradation of organophosphorus pesticides by Lactobacillus plantarum.  FOOD CHEMISTRY,      [PMID:34034058] [10.1016/j.foodchem.2021.130106]
11. Linfeng Chen, Xike Tian, Yong Li, Liqiang Lu, Yulun Nie, Yanxin Wang.  (2020)  Broad-spectrum pesticide screening by multiple cholinesterases and thiocholine sensors assembled high-throughput optical array system.  JOURNAL OF HAZARDOUS MATERIALS,      [PMID:33254811] [10.1016/j.jhazmat.2020.123830]
12. Qiong Jiang, Qin Liu, Qiliang Chen, Wenjie Zhao, Guoqiang Xiang, Lijun He, Xiuming Jiang, Shusheng Zhang.  (2016)  Dicationic polymeric ionic-liquid-based magnetic material as an adsorbent for the magnetic solid-phase extraction of organophosphate pesticides and polycyclic aromatic hydrocarbons.  JOURNAL OF SEPARATION SCIENCE,  39  (16): (3221-3229).  [PMID:27357486] [10.1002/jssc.201600267]
13. Yuan Tan, Israr Ahmad, Tian-Xin Wei.  (2015)  Detection of parathion methyl using a surface plasmon resonance sensor combined with molecularly imprinted films.  CHINESE CHEMICAL LETTERS,      [PMID:] [10.1016/j.cclet.2015.04.001]
14. Fei Yan, Yayun He, Longhua Ding, Bin Su.  (2015)  Highly Ordered Binary Assembly of Silica Mesochannels and Surfactant Micelles for Extraction and Electrochemical Analysis of Trace Nitroaromatic Explosives and Pesticides.  ANALYTICAL CHEMISTRY,      [PMID:25815534] [10.1021/acs.analchem.5b00433]
15. Qianqian Lu, Lingling Guo, Xinxin Xu, Hua Kuang, Liqiang Liu, Chuanlai Xu, Maozhong Sun.  (2025)  A multiplex fluorescent microsphere immunochromatography assay for simultaneous detection of phorate, fenthion, and profenofos.  FOOD CHEMISTRY,      [PMID:39808984] [10.1016/j.foodchem.2025.142850]
16. Zirou Wang, Sitian Gu, Yu Ma, Huixiao Duo, Wei Wu, Qingli Yang, Xiudan Hou.  (2024)  An efficient PCN-224/graphene aerogel-based extraction method for monitoring the degradation of organophosphorus pesticides in juice.  JOURNAL OF CHROMATOGRAPHY A,      [PMID:39509855] [10.1016/j.chroma.2024.465500]
17. Yaqing Zhao, Yaming Sun, Chenchen Song, Hailiang Zhao, Shiqi Chai, Xuemeng Xu, Lijun He.  (2025)  Defect-rich Co/N-doped hierarchically porous carbons for rapid and highly efficient adsorption of organophosphorus pesticides from environmental water.  JOURNAL OF CHROMATOGRAPHY A,      [PMID:39855024] [10.1016/j.chroma.2025.465700]
18. Qianji Li, Zejia Hao, Chenchen Zhang, Shanhong Ni, Ping Jiang, Pengfei Fan, Lei Li.  (2025)  Dual-Mode Detection of Glyphosate Based on DNAzyme-Mediated Click Chemistry and DNAzyme-Regulated CeO2 Peroxidase-like Activity.  JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY,      [PMID:40091824] [10.1021/acs.jafc.4c12499]
19. Li Wang, Kang Wei, Yi Pan, Yang Wei, Zhengwu Wang, Lurong Xu, Yuanfeng Wang, Xinlin Wei.  (2025)  Facile fabrication of novel magnetic MOFs for highly efficient adsorption and determination of organophosphorus pesticides.  FOOD CHEMISTRY,      [PMID:40154063] [10.1016/j.foodchem.2025.143978]
20. Ying Huang, Xiangrong Liu, Tiantian Shen, Wang Li, Jiali Ren, Haiyan Zhong.  (2025)  Portable iron-organic frameworks hydrogel for glyphosate detection based on competitive coordination with iron.  FOOD CHEMISTRY,      [PMID:39908810] [10.1016/j.foodchem.2025.143156]
21. Shuqin Chen, Wanfu Lan, Dapeng Yang, Jingying Xu, Yikun Hu, Hetong Lin, Liang Feng.  (2024)  Self-powered photoelectrochemical sensor based on molecularly imprinted polymer-coupled CBFO photocathode and Ag2S/SnS2 photoanode for ultrasensitive dimethoate sensing.  ANALYTICA CHIMICA ACTA,      [PMID:39800512] [10.1016/j.aca.2024.343556]
22. Xinyu Luo, Ziyi Liu, Linfan Wang, Liwei Gao, Dingfeng Wang, Ting Zhang, Da Chen.  (2024)  Smartphone-assisted sensing platform based on dual-responsive nitrogen-doped carbon dots for enzyme-free and visual quantitative detection of Cu2+ and glyphosate.  MICROCHEMICAL JOURNAL,      [PMID:] [10.1016/j.microc.2024.112166]
23. Liang Hao, Jingfei Luan.  (2024)  Visible Light-Driven Direct Z-Scheme Ho2SmSbO7/YbDyBiNbO7 Heterojunction Photocatalyst for Efficient Degradation of Fenitrothion.  MOLECULES,  29  (24): (5930).  [PMID:39770019] [10.3390/molecules29245930]
24. Zhangchi Xiao, Yong Li, Yulun Nie, Liqiang Lu, Chao Yang.  (2025)  A Cu2+-triggered turn-on fluorescence non-enzymatic probe based on covalent organic framework for the detection of methyl parathion.  ANALYTICA CHIMICA ACTA,      [PMID:40021329] [10.1016/j.aca.2025.343775]
25. Xinyue Huang, Lei Jiang, Lin Yuan, Wensi Ma, Xintao Cui, Jiaxuan Liu, Xiuling Ji, YujiaoTu.  (2025)  Orange ratiometric fluorescent probe for sensitive detection of phoxim.  SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,      [PMID:40795714] [10.1016/j.saa.2025.126785]
26. Yunjing Zang, Huifeng Zhang, Dawei Zhang, Qiong Jia.  (2025)  Fluorescent Detection of Fenitrothion Combined with Portable Smartphone-Integrated Hydrogel Platform Based on Arg/MTU-AuNCs.  JOURNAL OF FOOD COMPOSITION AND ANALYSIS,      [PMID:] [10.1016/j.jfca.2025.108577]
27. Yujie Liu, Xinyu Zhang, Haomin Chen, Ziling Yuan, Xiujuan Tian, Nan Xu, Ruihua Liu, Chao Yang.  (2025)  Creating a novel halotolerant whole-cell biosensor for efficient degradation and precise quantification of p-nitrophenol-substituted organophosphate pesticides in hypersaline ecosystems.  BIOSENSORS & BIOELECTRONICS,      [PMID:41285662] [10.1016/j.bios.2025.118240]
28. Shuhua Li, Shen Zhang, Dong Li, Tianhui Jiao, Jie Wei, Xiaomei Chen, Qingmin Chen, Quansheng Chen.  (2025)  Aptamer-driven upconversion fluorescence detection of dual pesticide residues in tea.  FOOD CHEMISTRY,      [PMID:41349407] [10.1016/j.foodchem.2025.147350]
29. Yufei Liu, Sitian Gu, Wenli Zhu, Man Gong, Qingli Yang, Xiudan Hou.  (2025)  The adsorption determination of organophosphate pesticides on microplastics in aquatic and juice samples using a Zr-COF-based magnetic solid-phase extraction.  JOURNAL OF CHROMATOGRAPHY A,      [PMID:41483548] [10.1016/j.chroma.2025.466666]
30. Jiatong Li, Shiyu Ou, Yaxuan Luo, Qing Han, Yongxin Li, Hui Huang.  (2026)  Smartphone-assisted detection of organophosphorus pesticides (OPs) in juice drinks and fruits based on cerium-based nanozyme.  MICROCHEMICAL JOURNAL,      [PMID:] [10.1016/j.microc.2026.116900]
31. Longying Zhao, Jiayu Chen, Donglin Xiang, Mierban Dawuti, Laping He, Yuangen Wu, Han Tao.  (2026)  Electrochemical Sensing of Organophosphorus Pesticides Based on Plant Esterase-Triggered Silver Deposition with CuNi-DAC Signal Amplification.  ELECTROCHIMICA ACTA,      [PMID:] [10.1016/j.electacta.2026.148562]
32. Shi Fan, Hu Xiaojuan, Han Xiao, Li Juntong, Li Xiaojiao, Mohan Brij, Sun Wei.  (2026)  Electrochemical sentinels: freestanding MnOx–laser-induced graphene electrodes for sensitive fenitrothion monitoring in food.  MICROCHIMICA ACTA,  193  (4): (252).  [PMID:] [10.1007/s00604-026-07990-z]
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