Formaldehyde-sodium bisulfite adduct - ≥97% , CAS No.870-72-4

CAS: 870-72-4 Cat. No.: F121963 Molecular Weight: 134.09 EC Number: 212-800-9
AVAILABLE TO ORDER
GRADE & PURITY ≥97%
Synonyms
PN | Sodium hydroxymethylsulfonate | EINECS 212-800-9 | Hydroxymethanesulfonic Acid Sodium Salt | SODIUM FORMALDEHYDE BISULFITE [HSDB] | 1-Hydroxymethanesulfonic acid sodium salt (1:1) | SCHEMBL317360 | I566KHA05F | Methanesulfonic acid, hydroxy-, sodium
Storage
Argon charged
Shipped In
Normal
 ·  off list, applied to all prices below.
Size
Status
Price
Qty
25g
F121963-25g
2

$13.90

$20.90
Save $7.00 (33.49%)
100g
F121963-100g
3

$17.90

$26.90
Save $9.00 (33.46%)
500g
F121963-500g
2

$21.90

$32.90
Save $11.00 (33.43%)
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Why this grade

≥97% for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

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Storage & shipping

Argon charged Ships Normal Check lot-specific COA for exact specifications.

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Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

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Literature proof

Cited in 1 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Overview

Formaldehyde-sodium bisulfite adduct is used as a standard in the synthesis of 3-Hydroxypropionaldehyde (3HPA). It can be assayed by HPLC with fluorometric detection in selected foods

Specifications

Synonyms
PN | Sodium hydroxymethylsulfonate | EINECS 212-800-9 | Hydroxymethanesulfonic Acid Sodium Salt | SODIUM FORMALDEHYDE BISULFITE [HSDB] | 1-Hydroxymethanesulfonic acid sodium salt (1:1) | SCHEMBL317360 | I566KHA05F | Methanesulfonic acid, hydroxy-, sodium
Specifications & Purity
≥97%
Storage
Argon charged
Shipped In
Normal
Purity
≥97%
Names and Identifiers
Pubchem Sid504760817
Pubchem Sid Urlhttps://pubchem.ncbi.nlm.nih.gov/substance/504760817
Canonical SmilesC(O)S(=O)(=O)[O-].[Na+]
IUPAC Namesodium;hydroxymethanesulfonate
InChIKeyUOULCEYHQNCFFH-UHFFFAOYSA-M
INCHI1S/CH4O4S.Na/c2-1-6(3,4)5;/h2H,1H2,(H,3,4,5);/q;+1/p-1
Isomeric SMILES C(O)S(=O)(=O)[O-].[Na+]
WGK Germany 3
RTECS PB2200000
Molecular Weight 134.09
Reaxy-Rn 1099078
Reaxys-RN_link_address https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=1099078&ln=

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

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✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

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📊 Datasheet

Quick-reference summary of product specifications and applications.

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🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

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Advanced Data

Taxonomic Classification

Taxonomy Tree

KingdomOrganic compounds
SuperclassOrganic acids and derivatives
ClassOrganic sulfonic acids and derivatives
SubclassOrganosulfonic acids and derivatives
Intermediate Tree Nodes Not available
Direct ParentOrganosulfonic acids
Alternative Parents Sulfonyls  Alkanesulfonic acids  Organooxygen compounds  Organic sodium salts  Organic oxides  Hydrocarbon derivatives  
Molecular FrameworkAliphatic acyclic compounds
Substituents Alkanesulfonic acid - Sulfonyl - Organosulfonic acid - Organic alkali metal salt - Organic oxygen compound - Organic oxide - Hydrocarbon derivative - Organic sodium salt - Organic salt - Organosulfur compound - Organooxygen compound - Aliphatic acyclic compound
DescriptionThis compound belongs to the class of organic compounds known as organosulfonic acids. These are compounds containing the sulfonic acid group, which has the general structure RS(=O)2OH (R is not a hydrogen atom).
External Descriptors Not available
3D Structure
Interactive Chemical Structure Model





Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

8 results found

Lot NumberCertificate TypeDateItem
H2202301Certificate of AnalysisFeb 04, 2026 F121963
B2506011Certificate of AnalysisFeb 08, 2025 F121963
H1623041Certificate of AnalysisDec 18, 2023 F121963
D2122254Certificate of AnalysisJan 17, 2023 F121963
D2122253Certificate of AnalysisJan 17, 2023 F121963
A2305175Certificate of AnalysisMay 05, 2021 F121963
D2122255Certificate of AnalysisMay 05, 2021 F121963
J2327269Certificate of AnalysisMay 05, 2021 F121963
Chemical and Physical Properties
SolubilityIt is soluble in water.
SensitivityMoisture sensitive
Melt Point(°C)200°C
Molecular Weight134.090 g/mol
XLogP3
Hydrogen Bond Donor Count1
Hydrogen Bond Acceptor Count4
Rotatable Bond Count1
Exact Mass133.965 Da
Monoisotopic Mass133.965 Da
Topological Polar Surface Area85.800 Ų
Heavy Atom Count7
Formal Charge0
Complexity108.000
Isotope Atom Count0
Defined Atom Stereocenter Count0
Undefined Atom Stereocenter Count0
Defined Bond Stereocenter Count0
Undefined Bond Stereocenter Count0
The total count of all stereochemical bonds0
Covalently-Bonded Unit Count2
Citations of This Product
References
1. Tianwen Xu, Li Yang, Xin Zhang, Guo Lu, Zhongchen Bai.  (2023)  A highly sensitive electrochemical sensor by growing Ag nanoparticles on the surface of PPy@PEDOT:PSS film for detecting sodium hydroxymethanesulfinate molecules.  Food Chemistry-X,      [PMID:37397227] [10.1016/j.fochx.2023.100701]
Solution Calculators
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