Hexarhodium(0) hexadecacarbonyl - Rh 57-60 % , CAS No.28407-51-4

CAS: 28407-51-4 Cat. No.: H485521 Molecular Weight: 1065.59 EC Number: 249-009-3

GRADE & PURITY Rh 57-60 %

Synonyms

Rhodium, tetra-.mu.3-carbonyldodecacarbonylhexa-, octahedro | Rhodium, tetra-m3-carbonyldodecacarbonylhexa-,octahedro | SZQABOJVTZVBHE-UHFFFAOYSA-N | hexarhodiumhexadecacarbonyl(0) | Hexarhodium(0) hexadecacarbonyl | Q1092934 | FT-0688491 | rh6(co)16 | HE

Storage

Protected from light,Room temperature,Argon charged

Shipped In

Normal

Overview

Description

Catalyst for hydrogenation of alkenes, hydroformylations ofalkenes; reducing agent for aldehydes, ketones, and nitro groups; catalyst for carbenoid reactions of diazo compoundsWidely used organometallic catalyst. Applications include the hydroformylation of olefins.

Specifications

Synonyms

Rhodium, tetra-.mu.3-carbonyldodecacarbonylhexa-, octahedro | Rhodium, tetra-m3-carbonyldodecacarbonylhexa-, octahedro | SZQABOJVTZVBHE-UHFFFAOYSA-N | hexarhodiumhexadecacarbonyl(0) | Hexarhodium(0) hexadecacarbonyl | Q1092934 | FT-0688491 | rh6(co)16 | HE

Specifications & Purity

Rh 57-60 %

Storage

Protected from light, Room temperature, Argon charged

Shipped In

Normal

Names and Identifiers

• Canonical Smiles: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Rh].[Rh].[Rh].[Rh].[Rh].[Rh]
• IUPAC Name: carbon monoxide;rhodium
• InChIKey: SZQABOJVTZVBHE-UHFFFAOYSA-N
• INCHI: 1S/16CO.6Rh/c16*1-2
• Isomeric SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Rh].[Rh].[Rh].[Rh].[Rh].[Rh]
• WGK Germany: 3
• Molecular Weight: 1065.59
• Reaxy-Rn: 14748138
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=14748138&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic salts
    • Class Organic metal salts
      • Subclass Organic transition metal salts

• Kingdom: Organic compounds
• Superclass: Organic salts
• Class: Organic metal salts
• Subclass: Organic transition metal salts
• Intermediate Tree Nodes: Not available
• Direct Parent: Organic transition metal salts
• Alternative Parents: Organic oxygen compounds Hydrocarbon derivatives Organic cations
• Molecular Framework: Not available
• Substituents: Organic transition metal salt - Organic oxygen compound - Hydrocarbon derivative - Organic cation - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as organic transition metal salts. These are organic salt compounds containing a transition metal atom in its ionic form.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Sensitivity: Air sensitive；light sensitive; air sensitive
• Molecular Weight: 1065.590 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 16
• Rotatable Bond Count: 0
• Exact Mass: 1065.35 Da
• Monoisotopic Mass: 1065.35 Da
• Topological Polar Surface Area: 16.000 Ų
• Heavy Atom Count: 38
• Formal Charge: 0
• Complexity: 10.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 22

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