M-Tolidine - ≥99.5% , CAS No.84-67-3

CAS: 84-67-3 Cat. No.: M1507102 Molecular Weight: 212.3 EC Number: 201-551-1
AVAILABLE TO ORDER
GRADE & PURITY ≥99.5%
Synonyms
4,4'-Diamino-2,2'-dimethylbiphenyl | 2,2'-Dimethylbenzidine
Storage
Room temperature
Shipped In
Normal
 ·  off list, applied to all prices below.
Size
Status
Price
Qty
25g
M1507102-25g
8-12 wks(?) Production requires sourcing of materials. We appreciate your patience and understanding.
$39.90
100g
M1507102-100g
8-12 wks(?) Production requires sourcing of materials. We appreciate your patience and understanding.
$99.90
500g
M1507102-500g
4
$399.90
Enter a quantity for the sizes you want to add.
🧪

Why this grade

≥99.5% for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

🌡

Storage & shipping

Room temperature Ships Normal Check lot-specific COA for exact specifications.

📋

Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

📚

Literature proof

Cited in 9 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Specifications

Synonyms
4, 4'-Diamino-2, 2'-dimethylbiphenyl | 2, 2'-Dimethylbenzidine
Specifications & Purity
≥99.5%
Storage
Room temperature
Shipped In
Normal
Purity
≥99.5%
Names and Identifiers
Canonical SmilesCC1=CC(N)=CC=C1C1=CC=C(N)C=C1C
IUPAC Name2,2'-Dimethyl[1,1'-biphenyl]-4,4'-diamine
InChIKeyQYIMZXITLDTULQ-UHFFFAOYSA-N
INCHIInChI=1S/C14H16N2/c1-9-7-11(15)3-5-13(9)14-6-4-12(16)8-10(14)2/h3-8H,15-16H2,1-2H3
Isomeric SMILES CC1=C(C=CC(=C1)N)C2=C(C=C(C=C2)N)C
Molecular Weight 212.3
Reaxy-Rn 2805670
Reaxys-RN_link_address https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=2805670&ln=

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

Download SDS →

✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

Look up COA →

📊 Datasheet

Quick-reference summary of product specifications and applications.

View datasheet →

🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

View spec sheet →

Advanced Data

Taxonomic Classification

Taxonomy Tree

KingdomOrganic compounds
SuperclassBenzenoids
ClassBenzene and substituted derivatives
SubclassBiphenyls and derivatives
Intermediate Tree Nodes Not available
Direct ParentBenzidines
Alternative Parents Aniline and substituted anilines  Aminotoluenes  Primary amines  Organopnictogen compounds  Hydrocarbon derivatives  
Molecular FrameworkAromatic homomonocyclic compounds
Substituents Benzidine - Aminotoluene - Aniline or substituted anilines - Toluene - Organic nitrogen compound - Organopnictogen compound - Hydrocarbon derivative - Primary amine - Organonitrogen compound - Amine - Aromatic homomonocyclic compound
DescriptionThis compound belongs to the class of organic compounds known as benzidines. These are organic compounds containing the benzidine skeleton, made up of a biphenyl ring system substituted at the 4- and 4'-positions with a unsubstituted amine group.
External Descriptors Not available
3D Structure
Interactive Chemical Structure Model





Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

6 results found

Lot NumberCertificate TypeDateItem
E2613568Certificate of AnalysisMay 11, 2026 M1507102
E2613569Certificate of AnalysisMay 11, 2026 M1507102
E2613572Certificate of AnalysisMay 11, 2026 M1507102
C2606215Certificate of AnalysisMar 02, 2026 M1507102
C2606216Certificate of AnalysisMar 02, 2026 M1507102
C2606217Certificate of AnalysisMar 02, 2026 M1507102
Chemical and Physical Properties
Melt Point(°C)106 °C
Citations of This Product
References
1. Junhao Xin, Xiaowei Zhou, Guolong Huo, Zhiguang Zhang, Yuchen Zhang, Shuanyan Kang, Zhongde Dai, Nanwen Li.  (2023)  Development of high performance carbon molecular sieve membranes via tuning the side groups on PI precursors.  JOURNAL OF MEMBRANE SCIENCE,      [PMID:] [10.1016/j.memsci.2023.122124]
2. Long Ni, Yinfu Luo, Guanchun Wang, Liwei Yan, Haoruo Zhang, Cuiqing Zhou, Shaoyu Qiu, Mei Liang, Shengtai Zhou, Huawei Zou.  (2023)  Lightweight, Radiation-Resistant, and Flexible Polyimide Foams with an Anisotropic Porous Structure for Efficient Thermal Insulation Applications.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/acs.iecr.3c00543]
3. Zixuan Zheng, Guojie Liang, Li Li, Jing Liu, Xinbo Wang, Yi Sun, Kai Li.  (2022)  Carbon Foam-Reinforced Polyimide-Based Carbon Aerogel Composites Prepared via Co-Carbonization as Insulation Material.  Gels,  (5): (308).  [PMID:35621606] [10.3390/gels8050308]
4. Long Ni, Yinfu Luo, Baowei Qiu, Liwei Yan, Huawei Zou, Shengtai Zhou, Mei Liang, Pengbo Liu.  (2022)  Combining Microwave-Assisted Foaming and Post Curing Process to Prepare Lightweight Flexible Polyimide Foams for Thermal Insulation Applications.  MACROMOLECULAR MATERIALS AND ENGINEERING,  307  (7): (2100941).  [PMID:] [10.1002/mame.202100941]
5. Guolong Huo, Shan Xu, Lei Wu, Shuanyan Kang, Zhiguang Zhang, Yanfang Fan, Nanwen Li.  (2021)  Structural engineering on copolyimide membranes for improved gas separation performance.  JOURNAL OF MEMBRANE SCIENCE,      [PMID:] [10.1016/j.memsci.2021.119989]
6. Long Ni, Yinfu Luo, Xionghou Peng, Shengtai Zhou, Huawei Zou, Mei Liang.  (2021)  Investigation of the properties and structure of semi-rigid closed-cellular polyimide foams with different diamine structures.  POLYMER,      [PMID:] [10.1016/j.polymer.2021.123957]
7. Jiadi Ying, Zhen Cui, Lei Tu, Tiancun Liu, Song Lu, Qi Shen, Min Guo, Yeqing Wang, Zhen Yang, Minfeng Zeng, Zhixin Yu, Xingzhong Cao, Yuqing Lin.  (2025)  Polymers with intrinsic microporosity engineered via acid-base pairs for highly selective lithium-ion transport channels.  JOURNAL OF MEMBRANE SCIENCE,      [PMID:] [10.1016/j.memsci.2025.125059]
8. Bo Sheng, Huaiming Zhang, Jiarui Li, Yunlong Wang, Jinzhao Wang, Feng Zhou, Jing Zhang.  (2025)  Side-chain engineering of quinone-amine polymers for high-efficiency H2O2 photosynthesis.  Molecular Catalysis,      [PMID:] [10.1016/j.mcat.2025.115628]
9. Yuan Xi, Junji Wei, Siqi Xu, Ranran Yi, Laili Wang, Li Duan, Jian Liu, Yingzhe Liu.  (2026)  Dielectric properties of high-temperature resistant semi-alicyclic polyimides: Research and application exploration in power devices.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2026.173496]
Solution Calculators
Reviews

Customer Reviews

Shall we send you a message when we have discounts available?

Remind me later

Thank you! Please check your email inbox to confirm.

Oops! Notifications are disabled.