Ruthenium nitrosyl nitrate solution - Ru 1.5% w/v , CAS No.34513-98-9

CAS: 34513-98-9 Cat. No.: R124005 Molecular Weight: 318.1 EC Number: 252-068-8 PubChem CID: 341124221

GRADE & PURITY Ru 1.5% w/v

Synonyms

Ru(NO)(NO3)3 | Ruthenium(III) nitrosyl nitrate solution in dilute nitric acid | Ruthenium nitrosylnitrate

Storage

Room temperature

Shipped In

Normal

Overview

Ruthenium(III) nitrosyl nitrate used as a catalyst in various reactions namely hydrogenation, carbonylation, hydrosilylation, hydrofomylation, C-X coupling (eg Heck, Suzuki, Stille) and chiral catalysis reactions. It is also used in the production of thick-film resistors.

Product class
PGM Solids, Low Chlorine Salts, Nitrates, Precursors for Heterogeneous Catalysts

Chemical properties

Chemical formula

N4O10Ru

Empirical formula

Ru(NO)(NO3)3

Molecular weight

317.09 (anhydrous)

Metal

Ru

Theoretical metal content

31

Physical state

powder

Color

red

Specifications

Synonyms

Ru(NO)(NO3)3 | Ruthenium(III) nitrosyl nitrate solution in dilute nitric acid | Ruthenium nitrosylnitrate

Specifications & Purity

Ru 1.5% w/v

Storage

Room temperature

Shipped In

Normal

Names and Identifiers

• Canonical Smiles: Ru+3N=O.O-N+(O-)=O.O-N+(O-)=O.O-N+(O-)=O
• InChIKey: VAAILMLOAHTPQK-UHFFFAOYSA-N
• INCHI: 1S/3NO3.NO.Ru/c3*2-1(3)4;1-2;/q4*-1;+4
• WGK Germany: 2
• PubChem CID: 341124221
• UN Number: 3264
• Packing Group: II
• Molecular Weight: 318.1

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Mixed metal/non-metal compounds
    • Class Transition metal oxoanionic compounds
      • Subclass Transition metal nitrates

• Kingdom: Inorganic compounds
• Superclass: Mixed metal/non-metal compounds
• Class: Transition metal oxoanionic compounds
• Subclass: Transition metal nitrates
• Intermediate Tree Nodes: Not available
• Direct Parent: Transition metal nitrates
• Alternative Parents: Inorganic salts Inorganic oxides
• Molecular Framework: Not available
• Substituents: Transition metal nitrate - Inorganic oxide - Inorganic salt
• Description: This compound belongs to the class of inorganic compounds known as transition metal nitrates. These are inorganic compounds in which the largest oxoanion is nitrate, and in which the heaviest atom not in an oxoanion is a transition metal.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Miscible with cold water

References

1. Xuanbei Peng, Kailin Su, Hongpeng Fang, Qianjin Sai, Jun Ni, Haifeng Qi, Yanliang Zhou, Lirong Zheng, Jianxin Lin, Lilong Jiang, Xiuyun Wang.  (2023)  Colloid carbonization-stabilized Ru nanoparticle catalyst for efficient ammonia synthesis at mild conditions.  CHEMICAL ENGINEERING SCIENCE,      [PMID:] [10.1016/j.ces.2023.118926]

2. Zhixiang Ren, Ao Li, Xinyu Lei, Zhengwei Yu, Guangying Wang, Hongliang Zhang, Huan Chen, Yin Wang, Hongming Long.  (2023)  Enhancement effect of RuO2 doping on the reduction process of NOx by NH3 via V2O5-WO3/TiO2 particle catalyst under low-temperature: Structure-activity relationship and reaction mechanism.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2023.157160]

3. Lingling Li, Mingyuan Zhang, Tianhua Zhang, Yinglong Gao, Jun Ni, Yanliang Zhou, Jianxin Lin, Xiuyun Wang, Lilong Jiang.  (2023)  Strong Ruδ+–Ce3+ electronic interaction induced by a CeOy overlayer for enhanced low-temperature N2-to-NH3 conversion.  Catalysis Science & Technology,  13  (7): (2134-2141).  [PMID:] [10.1039/D2CY02041F]

4. Kubota Masahiko, Wu Hao, Kim Seong-Yun.  (2022)  Combination of N’-N’-di-n-hexyl-thiodiglycolamide and 2,2’-[(2-ethylhexyl)imino]bis[N,N-bis(2-ethylhexyl) acetamide] for the enhanced adsorption of palladium ions from simulated high-level liquid waste.  JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,  331  (4): (1731-1740).  [PMID:] [10.1007/s10967-022-08230-3]

5. Xuanbei Peng, Han-Xuan Liu, Yangyu Zhang, Zheng-Qing Huang, Linlin Yang, Yafei Jiang, Xiuyun Wang, Lirong Zheng, Chunran Chang, Chak-tong Au, Lilong Jiang, Jun Li.  (2021)  Highly efficient ammonia synthesis at low temperature over a Ru–Co catalyst with dual atomically dispersed active centers.  Chemical Science,  12  (20): (7125-7137).  [PMID:34123340] [10.1039/D1SC00304F]

6. Shichang Zhang, Shunyan Ning, Hefang Liu, Jie Zhou, Siyi Wang, Wei Zhang, Xinpeng Wang, Yuezhou Wei.  (2020)  Highly-efficient separation and recovery of ruthenium from electroplating wastewater by a mesoporous silica-polymer based adsorbent.  MICROPOROUS AND MESOPOROUS MATERIALS,      [PMID:] [10.1016/j.micromeso.2020.110293]

7. Ranlei Shao, Lu Zhang, Luyuan Wang, Jianmei Wang, Xingyu Zhang, Shiwang Han, Xingxing Cheng, Zhiqiang Wang.  (2024)  Construction of ruthenium catalysts based on Ce-Al composite supports for hydrogen production from ammonia decomposition: Mechanism exploration via DFT calculations.  FUEL,      [PMID:] [10.1016/j.fuel.2024.134043]

8. Min Chen, Longgang Liu, Xueyan Chen, Xiaoxiao Qin, Kunlin Li, Jianghao Zhang, Xiaolei Bao, Lingjuan Ma, Changbin Zhang.  (2024)  Effects of Ru particle size over TiO2 on the catalytic performance of CO2 hydrogenation.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2024.159460]

9. Liying Ren.  (2024)  Fluorescence porous organic polymers synthesized via transition metal-free thiol‑yne click chemistry for fluorescence sensing bismuth triiodide.  JOURNAL OF MOLECULAR STRUCTURE,      [PMID:] [10.1016/j.molstruc.2024.140951]

10. Xuan Bie, Yukun Pan, Xiaowei Wang, Shiyu Zhang, Jiahui Hu, Xiaoxiao Yang, Qinghai Li, Yanguo Zhang, Robert E. Przekop, Yayun Zhang, Hui Zhou.  (2025)  NH3-Induced Challenges in CO2 Hydrogenation over the Cu/ZnO/Al2O3 Catalyst.  JACS Au,      [PMID:40151266] [10.1021/jacsau.4c01097]

11. Shichang Zhang, Qunying Huang, Lifeng Chen, Yilai Zhong, Fengtao Hu, Kun Wu, Xiangbiao Yin, Mohammed F. Hamza, Yuezhou Wei, Shunyan Ning.  (2024)  Phosphination of amino-modified mesoporous silica for the selective separation of strontium.  JOURNAL OF HAZARDOUS MATERIALS,      [PMID:38341887] [10.1016/j.jhazmat.2024.133741]

12. Xuanbei Peng, Yongjin Luo, Tianhua Zhang, Jinxiu Deng, Yanliang Zhou, Jiaxin Li, Jun Ni, Bingyu Lin, Jianxin Lin, Dongshuang Wu, Lirong Zheng, Xiuyun Wang, Lilong Jiang.  (2024)  Potassium promoter regulates electronic structure and hydrogen spillover of ultrasmall Ru nanoclusters catalyst for ammonia synthesis.  CHEMICAL ENGINEERING SCIENCE,      [PMID:] [10.1016/j.ces.2024.120021]

13. Yunyun Huang, Hongju Ren, Huihuang Fang, Dong Ouyang, Chongqi Chen, Yu Luo, Li Lin, Dabiao Wang, Lilong Jiang.  (2024)  Ru nanoparticles embedded in Ru/SiO2@N-CS for boosting hydrogen production via ammonia decomposition with robust lifespan.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2024.160517]

14. Chen Min, Liu Longgang, Chen Xueyan, Qin Xiaoxiao, Zhang Jianghao, Xie Shaohua, Liu Fudong, He Hong, Zhang Changbin.  (2024)  Sulfate residuals on Ru catalysts switch CO2 reduction from methanation to reverse water-gas shift reaction.  Nature Communications,  15  (1): (1-9).  [PMID:39488527] [10.1038/s41467-024-53909-8]

15. Meng Ye, Li Chen, Xiaolong Liu, Wenqing Xu, Tingyu Zhu, Guanyi Chen.  (2018)  Catalytic Oxidation of Chlorobenzene over Ruthenium-Ceria Bimetallic Catalysts.  Catalysts,  8  (3): (116).  [PMID:] [10.3390/catal8030116]

16. Kaiyu Fang, Yang Tong, Yuting Zhu, Guodong Yao, Xu Zeng, Yecheng Xue, Yangyuan Zhou, Jianfu Zhao, Siqing Xia.  (2025)  Efficient Conversion of Municipal Sludge to Practical Carbon Source via N/MxOy in Catalytic Wet Air Oxidation.  WATER RESEARCH,      [PMID:40408991] [10.1016/j.watres.2025.123859]

17. Xiaolong Tan, Xiangguo Zhang, Yushi He, Zeyi Jiang, Cheng Bao, Nien-Chu Lai.  (2025)  Strong metal-support interaction engineering in Ru/TiO2 mesostructures: Achieving ultra-deep CO removal below 1 ppm.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,      [PMID:] [10.1016/j.ijhydene.2025.152176]

18. Xin Hu, Wei Cheng, Xin Zhang, Tianyi Wang, Shaoheng Cheng, Nan Gao, Hongdong Li.  (2025)  One-Step Exsolution Strategy for the Reconstruction of the RuO2/La0.9Fe0.92Ru0.08O3 Composite for the Enhanced Oxygen Evolution Reaction.  Journal of Physical Chemistry Letters,      [PMID:40728387] [10.1021/acs.jpclett.5c01769]

19. Chen Yuqing, Wu Xuan, Yan Taihong, Wang Wentao, Liu Junjie, Wang Hui.  (2025)  Selective separation of Pu(IV) from nitric acid media using a novel silica-polymer based adsorbent NTAamide(C8)/SiO2-P.  SEPARATION AND PURIFICATION TECHNOLOGY,      [PMID:] [10.1016/j.seppur.2025.136595]

20. Junjie Jiang, Yang Zou, Xue Li, Yongqi Zhao, Ziwei Zhao, Xiaolong Liu, Tingyu Zhu.  (2025)  The influence of H2O and SO2 on the mechanism of CO oxidation over low noble metal loading catalysts.  Catalysis Science & Technology,      [PMID:] [10.1039/D5CY01213A]