[(S)-(−)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride , CAS No.215597-19-6

CAS: 215597-19-6 Cat. No.: S486889 Molecular Weight: 856.1 PubChem CID: 11814861

Synonyms

[(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl]palladium(II) chloride | [(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl]palladium(II)chloride | Palladium, [1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-bis(4-methylphenyl)phosphine-kappaP]

Storage

Room temperature

Overview

Description

Catalyst for:Stereoselective preparation of hydroxymethyldihydronaphthalenone via alkylative ring opening of oxabenzonorbornadiene with (PhMe2SiCH2)2Zn followed by hydrogenation and Tamao-Fleming oxidationAsymmetric synthesis of cyclopentylindanes via cyclization of bromo- and trifluoromethanesulfonyloxyphenylheptenylmalonate

Specifications

Synonyms

[(R)-(+)-2, 2'-Bis(di-p-tolylphosphino)-1, 1'-binaphthyl]palladium(II) chloride | [(R)-(+)-2, 2'-Bis(di-p-tolylphosphino)-1, 1'-binaphthyl]palladium(II)chloride | Palladium, [1, 1'-(1R)-[1, 1'-binaphthalene]-2, 2'-diylbis[1, 1-bis(4-methylphenyl)phosphine-kappaP]

Storage

Room temperature

Names and Identifiers

• Isomeric SMILES: CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=C(C=C7)C)C8=CC=C(C=C8)C.Cl[Pd]Cl
• WGK Germany: 3
• PubChem CID: 11814861
• Molecular Weight: 856.1