tert-Butyldimethylsilyl (S)-(+)-glycidyl ether - ≥98% , CAS No.123237-62-7

CAS: 123237-62-7 Cat. No.: B123082 Molecular Weight: 188.34 EC Number: 602-924-5

GRADE & PURITY ≥98%

Synonyms

J-004901 | s25165 | SCHEMBL590696 | AKOS025294206 | tert-butyl-dimethyl-((S)-1-oxiranylmethoxy)-silane | (2S)-1-O-(tert-Butyldimethylsilyl)glycidol; tert-Butyldimethyl[((2S)-oxiran-2-yl)methoxy]silane | AS-72024 | tert-Butyldimethylsilyl (S)-(+)-glycidyl

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Specifications

Synonyms

J-004901 | s25165 | SCHEMBL590696 | AKOS025294206 | tert-butyl-dimethyl-((S)-1-oxiranylmethoxy)-silane | (2S)-1-O-(tert-Butyldimethylsilyl)glycidol; tert-Butyldimethyl[((2S)-oxiran-2-yl)methoxy]silane | AS-72024 | tert-Butyldimethylsilyl (S)-(+)-glycidyl

Specifications & Purity

≥98%

Storage

Store at 2-8°C, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥98%

Names and Identifiers

• Canonical Smiles: CC(C)(C)[Si](C)(C)OCC1CO1
• IUPAC Name: tert-butyl-dimethyl-[[(2S)-oxiran-2-yl]methoxy]silane
• InChIKey: YANSSVVGZPNSKD-QMMMGPOBSA-N
• INCHI: 1S/C9H20O2Si/c1-9(2,3)12(4,5)11-7-8-6-10-8/h8H,6-7H2,1-5H3/t8-/m0/s1
• Isomeric SMILES: CC(C)(C)[Si](C)(C)OC[C@@H]1CO1
• WGK Germany: 3
• Molecular Weight: 188.34
• Reaxy-Rn: 4367074
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=4367074&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organometallic compounds
    • Class Organometalloid compounds
      • Subclass Organosilicon compounds
        • Level5 Organoheterosilanes
          • Level6 Trialkylheterosilanes

• Kingdom: Organic compounds
• Superclass: Organometallic compounds
• Class: Organometalloid compounds
• Subclass: Organosilicon compounds
• Intermediate Tree Nodes: Organoheterosilanes
• Direct Parent: Trialkylheterosilanes
• Alternative Parents: Silyl ethers Oxacyclic compounds Organic metalloid salts Epoxides Dialkyl ethers Hydrocarbon derivatives
• Molecular Framework: Aliphatic heteromonocyclic compounds
• Substituents: Trialkylheterosilane - Silyl ether - Oxacycle - Organic metalloid salt - Organoheterocyclic compound - Ether - Oxirane - Dialkyl ether - Organic oxygen compound - Hydrocarbon derivative - Organooxygen compound - Aliphatic heteromonocyclic compound
• Description: This compound belongs to the class of organic compounds known as trialkylheterosilanes. These are organoheterosilanes, bearing a silicon atom linked to three alkyl groups and one heteroatom.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Sensitivity: Moisture & Heat & Air sensitive
• Refractive Index: 1.432
• Specific Rotation[α]: +6.5°,neat
• Flash Point(°C): 73 °C
• Boil Point(°C): 197-199°C/760mmHg
• Molecular Weight: 188.340 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 188.123 Da
• Monoisotopic Mass: 188.123 Da
• Topological Polar Surface Area: 21.800 Ų
• Heavy Atom Count: 12
• Formal Charge: 0
• Complexity: 160.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 1
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

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