Tetrabutylammonium hexafluorophosphate(TBAPF6) - ≥98% , CAS No.3109-63-5

CAS: 3109-63-5 Cat. No.: T106724 Molecular Weight: 387.43 Beilstein Registry Number: 4056584 EC Number: 221-472-6 PubChem CID: 165075
AVAILABLE TO ORDER
GRADE & PURITY ≥98%
Synonyms
tetra-n-butylammonium hexafluorophosphate | Tetrabutylammonium hexafluorophosphate | tetrabutylazanium;hexafluorophosphate | Tetrabutylammonium hexafluorophosphate(V) | tetrabutylammoniumhexafluorophosphate | MFCD00011748
Storage
Argon charged,Room temperature
Shipped In
Normal
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Size
Status
Price
Qty
5g
T106724-5g
4
$9.90
10g
T106724-10g
3
$10.90
25g
T106724-25g
≥10
$14.90
100g
T106724-100g
9

$23.90

$35.90
Save $12.00 (33.43%)
250g
T106724-250g
1

$52.90

$79.90
Save $27.00 (33.79%)
500g
T106724-500g
1

$94.90

$142.90
Save $48.00 (33.59%)
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Why this grade

≥98% for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

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Storage & shipping

Argon charged,Room temperature Ships Normal Check lot-specific COA for exact specifications.

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Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

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Literature proof

Cited in 136 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Overview

Tetrabutylammonium hexafluorophosphate can be used as a supporting electrolyte for the formation of cyclic disulfide moiety of 3,5-diimido-1,2-dithiolane derivatives by S-S coupling of dithioanilides.
Tetrabutylammonium hexafluorophosphate (TBAPF6) can be used:
As a catalyst in the synthesis of 3,4-dihydropyrimidin-2(1H)-one and 3,4-dihydropyrimidine-2(1H)-thione derivatives via Biginelli reaction.
Along with 1-ethyl-3-methyl imidazolium hexafluorophosphate as a supporting electrolyte in non-aqueous redox flow batteries.
As a supporting electrolyte in the electropolymerisation.

Specifications

Synonyms
tetra-n-butylammonium hexafluorophosphate | Tetrabutylammonium hexafluorophosphate | tetrabutylazanium;hexafluorophosphate | Tetrabutylammonium hexafluorophosphate(V) | tetrabutylammoniumhexafluorophosphate | MFCD00011748
Specifications & Purity
≥98%
Storage
Argon charged, Room temperature
Shipped In
Normal
Purity
≥98%
Names and Identifiers
Pubchem Sid488188378
Pubchem Sid Urlhttps://pubchem.ncbi.nlm.nih.gov/substance/488188378
Canonical SmilesCCCC[N+](CCCC)(CCCC)CCCC.F[P-](F)(F)(F)(F)F
IUPAC Nametetrabutylazanium;hexafluorophosphate
InChIKeyBKBKEFQIOUYLBC-UHFFFAOYSA-N
INCHI1S/C16H36N.F6P/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-7(2,3,4,5)6/h5-16H2,1-4H3;/q+1;-1
Isomeric SMILES CCCC[N+](CCCC)(CCCC)CCCC.F[P-](F)(F)(F)(F)F
WGK Germany 3
PubChem CID 165075
UN Number 1759
Molecular Weight 387.43
Beilstein 4056584
Reaxy-Rn 4056584

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

Download SDS →

✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

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📊 Datasheet

Quick-reference summary of product specifications and applications.

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🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

View spec sheet →

Advanced Data

Taxonomic Classification

Taxonomy Tree

KingdomOrganic compounds
SuperclassOrganic nitrogen compounds
ClassOrganonitrogen compounds
SubclassQuaternary ammonium salts
Intermediate Tree Nodes Not available
Direct ParentTetraalkylammonium salts
Alternative Parents Organopnictogen compounds  Organic salts  Hydrocarbon derivatives  Amines  
Molecular FrameworkAliphatic acyclic compounds
Substituents Tetraalkylammonium salt - Organopnictogen compound - Hydrocarbon derivative - Organic salt - Amine - Aliphatic acyclic compound
DescriptionThis compound belongs to the class of organic compounds known as tetraalkylammonium salts. These are organonitrogen compounds containing a quaternary ammonium substituted with four alkyl chains.
External Descriptors Not available
3D Structure
Interactive Chemical Structure Model





Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

52 results found

Lot NumberCertificate TypeDateItem
L2518614Certificate of AnalysisDec 06, 2025 T106724
L2518613Certificate of AnalysisDec 06, 2025 T106724
L2518612Certificate of AnalysisDec 06, 2025 T106724
L2518611Certificate of AnalysisDec 06, 2025 T106724
L2518610Certificate of AnalysisDec 06, 2025 T106724
L2518609Certificate of AnalysisDec 06, 2025 T106724
L2518608Certificate of AnalysisDec 06, 2025 T106724
F2602061Certificate of AnalysisDec 06, 2025 T106724
E2509477Certificate of AnalysisApr 26, 2025 T106724
K2528114Certificate of AnalysisApr 26, 2025 T106724
I2522084Certificate of AnalysisApr 26, 2025 T106724
E2509479Certificate of AnalysisApr 26, 2025 T106724
E2509478Certificate of AnalysisApr 26, 2025 T106724
E2509476Certificate of AnalysisApr 26, 2025 T106724
E2509447Certificate of AnalysisApr 26, 2025 T106724
E2509446Certificate of AnalysisApr 26, 2025 T106724
C2514618Certificate of AnalysisMar 06, 2025 T106724
C2514619Certificate of AnalysisMar 06, 2025 T106724
C2514623Certificate of AnalysisMar 06, 2025 T106724
C2514624Certificate of AnalysisMar 06, 2025 T106724
L2512056Certificate of AnalysisMar 06, 2025 T106724
C2514617Certificate of AnalysisMar 06, 2025 T106724
G2531058Certificate of AnalysisMar 06, 2025 T106724
H2415361Certificate of AnalysisAug 02, 2024 T106724
J2430713Certificate of AnalysisAug 02, 2024 T106724
H2415366Certificate of AnalysisAug 02, 2024 T106724
H2415365Certificate of AnalysisAug 02, 2024 T106724
H2415364Certificate of AnalysisAug 02, 2024 T106724
H2415363Certificate of AnalysisAug 02, 2024 T106724
H2415362Certificate of AnalysisAug 02, 2024 T106724
E2416447Certificate of AnalysisMar 25, 2024 T106724
E2416448Certificate of AnalysisMar 25, 2024 T106724
G2412146Certificate of AnalysisMar 25, 2024 T106724
C2012174Certificate of AnalysisJan 22, 2024 T106724
A2304587Certificate of AnalysisNov 07, 2022 T106724
A2304588Certificate of AnalysisNov 07, 2022 T106724
A2304586Certificate of AnalysisNov 07, 2022 T106724
A2304589Certificate of AnalysisNov 07, 2022 T106724
A2304590Certificate of AnalysisNov 07, 2022 T106724
A2304591Certificate of AnalysisNov 07, 2022 T106724
A2304592Certificate of AnalysisNov 07, 2022 T106724
A2304593Certificate of AnalysisNov 07, 2022 T106724
A2304594Certificate of AnalysisNov 07, 2022 T106724
K2317054Certificate of AnalysisDec 15, 2021 T106724
G2304016Certificate of AnalysisDec 15, 2021 T106724
B2223214Certificate of AnalysisDec 15, 2021 T106724
A2411082Certificate of AnalysisDec 15, 2021 T106724
B2223251Certificate of AnalysisDec 15, 2021 T106724
B2223246Certificate of AnalysisDec 15, 2021 T106724
B2223235Certificate of AnalysisDec 15, 2021 T106724
B2223228Certificate of AnalysisDec 15, 2021 T106724
H2104387Certificate of AnalysisJun 25, 2021 T106724

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Chemical and Physical Properties
SolubilitySoluble in acetone, acetonitrile and tetrhydrofuran.
SensitivityMoisture sensitive.
Melt Point(°C)244-246 °C
Molecular Weight387.430 g/mol
XLogP3
Hydrogen Bond Donor Count0
Hydrogen Bond Acceptor Count7
Rotatable Bond Count12
Exact Mass387.249 Da
Monoisotopic Mass387.249 Da
Topological Polar Surface Area0.000 Ų
Heavy Atom Count24
Formal Charge0
Complexity179.000
Isotope Atom Count0
Defined Atom Stereocenter Count0
Undefined Atom Stereocenter Count0
Defined Bond Stereocenter Count0
Undefined Bond Stereocenter Count0
The total count of all stereochemical bonds0
Covalently-Bonded Unit Count2
Citations of This Product
References
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120. Yi Lu, Ahmed Mahmoud Idris, Ping Lu, Xinyan Jiang, Jin Wang, Hao Zheng, Xiandan Liang, Sheng Li, Zhengquan Li.  (2025)  Synergistic electronic modulation of active sites in CsCuCl3 via Zn doping for photocatalytic oxidation of toluene to benzaldehyde.  JOURNAL OF CATALYSIS,      [PMID:] [10.1016/j.jcat.2025.116104]
121. Wei Wen, Jianru Gao, Man Zhao, Qinyun Yan, Liwu Qiang, Shuai He, Peipei Zhao, Chunmei Liu, Jiamin Ma, Li Zhang, Junming Zhang, He Xiao, Jianfeng Jia.  (2025)  Electric field-assisted synthesis of multivalent WO3-x coupling with carbon nanotubes for promoting (photo-)electrocatalytic oxygen evolution reaction.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,      [PMID:] [10.1016/j.ijhydene.2025.04.180]
122. Lejing Qin, Fangyu Gong, Zi Ma, Kai Li, Linzheng Ma, Wei Chen.  (2025)  Self-Powered Photoelectrochemical Aptasensor with a TiO2/CdTe/PEDOT-Sensitized Photoanode and a RGO-Enhanced Sensing Cathode for Thrombin Detection.  ACS Applied Nano Materials,      [PMID:] [10.1021/acsanm.5c00888]
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124. Yajun Wang, Tursun Abdiryim, Ruxangul Jamal, Feng Xu, Qilong Zhang, Yiming Liu.  (2025)  Achieving high-performance flexible UV photodetectors: modulating oxygen vacancies via hydroxymethylated PEDOT and surface functionalities of N-doped graphene quantum dots.  CARBON,      [PMID:] [10.1016/j.carbon.2025.120470]
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129. Li-Yuan Wu, Fei Zhang, Ming-Zhe Cai, Min Zhang, Tong-Bu Lu, Ping Li, Yong-Hua Chen.  (2025)  A direct Z-scheme heterojunction of CsPbBr3/SnS2 nanosheets for visible light-driven photocatalytic CO2 reduction.  Journal of Materials Chemistry A,      [PMID:] [10.1039/D5TA08691D]
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132. Wanwan Wu, Linjie Song, Yinqi Qiao, Yan Bai, Xue Liu, Haiyan Li, Dongbin Dang.  (2026)  In-situ grown lead-free perovskite Cs3Bi2Br9 on porous Ta2O5 for boosted gas–solid phase CO2 photocatalytic conversion.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2026.166174]
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134. Yingxuan Zhao, Chenyang Shen, Qing Liu, Siyuan Zhao, Ruiyao Zhao, Xiangke Guo, Nianhua Xue, Luming Peng, Xuefeng Guo, Yan Zhu, Weiping Ding.  (2026)  Electrocatalytic oxidation or amidation of olefins by asymmetric electrolytes steering carbocation pathways.  GREEN CHEMISTRY,      [PMID:] [10.1039/D5GC07050C]
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