Tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene][3-phenyl-1H-inden-1-ylidene]ruthenium(II) dichloride - ≥95% , CAS No.254972-49-1

CAS: 254972-49-1 Cat. No.: T282787 Molecular Weight: 947.07 EC Number: 682-128-2 PubChem CID: 72376331

GRADE & PURITY ≥95%

Synonyms

TRICYCLOHEXYLPHOSPHINE[1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE][3-PHENYL-1H-INDEN-1-YLIDENE]RUTHENIUM (II) DICHLORIDE | Tricyclohexylphosphine [1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene] [3-phenyl-1H-inden-1-ylidene] ruthenium (II) dichlor

Storage

Room temperature

Overview

Application

Umicore Grubbs Catalyst M203 is a homogeneous catalyst useful for alkene metathesis, especially for cross-metathesis, ring-closing metathesis and self-metathesis.

Storage and stability

Do not store above 25°C (77°F). Store in a tightly closed original container under dry inert gas, protected from direct sunlight in a dry, cool and well-ventilated area

Product class
M-P, Homogeneous Catalysts, N-Heterocyclic Carbene Ligands, M-C, Grubbs Catalyst® 2nd Generation, Carbene Ligands, IMes, Phosphorus Ligands - Achiral

Reaction type
Alkene Metathesis, Cross Metathesis, Ring Closing Metathesis, Self Metathesis

Chemical properties

Chemical formula

C54H67Cl2N2PRu

Empirical formula

(IMes)Ru(PCy3)(Ind)Cl2

Molecular weight

947.07

Metal

Ru

Theoretical metal content

11

Physical state

powder

Color

brown

Specifications

Synonyms

TRICYCLOHEXYLPHOSPHINE[1, 3-BIS(2, 4, 6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE][3-PHENYL-1H-INDEN-1-YLIDENE]RUTHENIUM (II) DICHLORIDE | Tricyclohexylphosphine [1, 3-bis(2, 4, 6-trimethylphenyl)imidazol-2-ylidene] [3-phenyl-1H-inden-1-ylidene] ruthenium (II) dichlor

Specifications & Purity

≥95%

Legal Information

Sold in collaboration with Evonik for research purposes only. Patent US 6635768. For use in pharmaceutical applications only. Other uses are unauthorized.

Storage

Room temperature

Purity

≥95%

Names and Identifiers

• Canonical Smiles: CC1=CC(=C(C(=C1)C)N2C=CN(C2=[Ru](=C3C=C(C4=CC=CC=C43)C5=CC=CC=C5)(Cl)Cl)C6=C(C=C(C=C6C)C)C)C.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3
• IUPAC Name: [1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]-dichloro-(3-phenylinden-1-ylidene)ruthenium;tricyclohexylphosphane
• InChIKey: HBNBIWQQLMQFEU-UHFFFAOYSA-L
• INCHI: 1S/C21H24N2.C18H33P.C15H10.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-6-12(7-3-1)15-11-10-13-8-4-5-9-14(13)15;;;/h7-12H,1-6H3;16-18H,1-15H2;1-9,11H;2*1H;/q;;;;;+2/p-2
• Isomeric SMILES: CC1=CC(=C(C(=C1)C)N2C=CN(C2=[Ru](=C3C=C(C4=CC=CC=C43)C5=CC=CC=C5)(Cl)Cl)C6=C(C=C(C=C6C)C)C)C.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3
• WGK Germany: 3
• PubChem CID: 72376331
• Molecular Weight: 947.07

Chemical and Physical Properties

• Melt Point(°C): 230 °C (decomp)