Trimethylsilyl trimethylsiloxyacetate - ≥95% , CAS No.33581-77-0

CAS: 33581-77-0 Cat. No.: T341257 Molecular Weight: 220.41 EC Number: 251-580-9 PubChem CID: 118503

GRADE & PURITY ≥95%

Synonyms

Glycolic acid, 2TMS derivative | POTASSIUM PHOSPHATE, MONOBASIC [JAN] | trimethylsilyl 2-((trimethylsilyl)oxy)acetate | trimethylsilyl 2-(trimethylsilyloxy)acetate | trimethylsilyl trimethylsiloxy glycolate | trimethylsilyl2-((trimethylsilyl)oxy)acetate |

Storage

Room temperature

Shipped In

Normal

Overview

Application：

Trimethylsilyl trimethylsiloxyacetate has been used in the synthesis of zirconium(IV) carboxylato complexes [LOEtZr(OCOCH2OH)(O2CCH2O)]2.

Specifications

Synonyms

Glycolic acid, 2TMS derivative | POTASSIUM PHOSPHATE, MONOBASIC [JAN] | trimethylsilyl 2-((trimethylsilyl)oxy)acetate | trimethylsilyl 2-(trimethylsilyloxy)acetate | trimethylsilyl trimethylsiloxy glycolate | trimethylsilyl2-((trimethylsilyl)oxy)acetate |

Specifications & Purity

≥95%

Storage

Room temperature

Shipped In

Normal

Purity

≥95%

Names and Identifiers

• Pubchem Sid: 488187579
• Canonical Smiles: C[Si](C)(C)OCC(=O)O[Si](C)(C)C
• IUPAC Name: trimethylsilyl 2-trimethylsilyloxyacetate
• InChIKey: MAEQOWMWOCEXKP-UHFFFAOYSA-N
• INCHI: 1S/C8H20O3Si2/c1-12(2,3)10-7-8(9)11-13(4,5)6/h7H2,1-6H3
• Isomeric SMILES: C[Si](C)(C)OCC(=O)O[Si](C)(C)C
• PubChem CID: 118503
• Molecular Weight: 220.41

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organometallic compounds
    • Class Organometalloid compounds
      • Subclass Organosilicon compounds

• Kingdom: Organic compounds
• Superclass: Organometallic compounds
• Class: Organometalloid compounds
• Subclass: Organosilicon compounds
• Intermediate Tree Nodes: Not available
• Direct Parent: Trimethylsilyl esters
• Alternative Parents: Trialkylheterosilanes Silyl ethers Carboxylic acid salts Organic metalloid salts Monocarboxylic acids and derivatives Organic oxides Hydrocarbon derivatives Carbonyl compounds
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Trimethylsilyl ester - Trialkylheterosilane - Silyl ether - Carboxylic acid salt - Organoheterosilane - Organic metalloid salt - Monocarboxylic acid or derivatives - Carboxylic acid derivative - Organic oxygen compound - Organic oxide - Hydrocarbon derivative - Organic salt - Organooxygen compound - Carbonyl group - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as trimethylsilyl esters. These are organoheterosilanes, bearing a silicon atom that is linked to three methyl groups and is O-esterified.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Sensitivity: Moisture sensitive
• Refractive Index: 1.411 (lit.)
• Boil Point(°C): 82-83° C at 20 hPa
• Molecular Weight: 220.410 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 5
• Exact Mass: 220.095 Da
• Monoisotopic Mass: 220.095 Da
• Topological Polar Surface Area: 35.500 Ų
• Heavy Atom Count: 13
• Formal Charge: 0
• Complexity: 179.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

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