Triphenylmethylium Tetrafluoroborate - ≥98% , CAS No.341-02-6

CAS: 341-02-6 Cat. No.: T162513 Molecular Weight: 330.13 EC Number: 206-433-3 PubChem CID: 2723955

GRADE & PURITY ≥98%

Synonyms

Triphenylmethyl fluoroborate | MFCD00013120 | J-019448 | Tritylium tetrafluoroborate | Triphenylmethylium tetrafluoroborate | NSC 176021 | Trityl tetrafluoroborate | SCHEMBL420170 | LS-14699 | Methylium, triphenyl-, tetrafluoroborate(1-) | AKOS024318882 |

Storage

Store at -20°C,Argon charged

Shipped In

Ice chest + Ice pads

Overview

Product Application：
Reactant involved in:Synthesis of substituted dihydroazulene photoswitches;Carbene-based Lewis pairs for hydrogen activation;1,3-Dipolar cycloaddition reactions for preparation of α−amino-β-hydroxy esters;Oxidation of allenic compounds;Mukaiyama aldol addition reactions;Ionic hydrogenation as a counteranion and ligand source

Specifications

Synonyms

Triphenylmethyl fluoroborate | MFCD00013120 | J-019448 | Tritylium tetrafluoroborate | Triphenylmethylium tetrafluoroborate | NSC 176021 | Trityl tetrafluoroborate | SCHEMBL420170 | LS-14699 | Methylium, triphenyl-, tetrafluoroborate(1-) | AKOS024318882 |

Specifications & Purity

≥98%

Storage

Store at -20°C, Argon charged

Shipped In

Ice chest + Ice pads

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥98%

Names and Identifiers

• Pubchem Sid: 488192228
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/488192228
• Canonical Smiles: [B-](F)(F)(F)F.C1=CC=C(C=C1)[C+](C2=CC=CC=C2)C3=CC=CC=C3
• IUPAC Name: diphenylmethylbenzene;tetrafluoroborate
• InChIKey: VQXBOEYKSVVPSP-UHFFFAOYSA-N
• INCHI: 1S/C19H15.BF4/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2-1(3,4)5/h1-15H;/q+1;-1
• Isomeric SMILES: [B-](F)(F)(F)F.C1=CC=C(C=C1)[C+](C2=CC=CC=C2)C3=CC=CC=C3
• WGK Germany: 3
• PubChem CID: 2723955
• Molecular Weight: 330.13
• Reaxy-Rn: 5085649

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Class Benzene and substituted derivatives

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Class: Benzene and substituted derivatives
• Subclass: Not available
• Intermediate Tree Nodes: Not available
• Direct Parent: Benzene and substituted derivatives
• Alternative Parents: Organic metalloid salts Hydrocarbon derivatives
• Molecular Framework: Aromatic homomonocyclic compounds
• Substituents: Monocyclic benzene moiety - Organic metalloid salt - Hydrocarbon derivative - Organic salt - Aromatic homomonocyclic compound
• Description: This compound belongs to the class of organic compounds known as benzene and substituted derivatives. These are aromatic compounds containing one monocyclic ring system consisting of benzene.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Insoluble in water. Soluble in methanol.
• Sensitivity: heat & light & Moisture sensitive
• Melt Point(°C): 205-215°C
• Molecular Weight: 330.100 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 3
• Exact Mass: 330.12 Da
• Monoisotopic Mass: 330.12 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 24
• Formal Charge: 0
• Complexity: 215.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

References

1. Yupo Xu, Lei Wang, Chuanshuang Chen, Pei Huang, Haojie Dai, Wenfeng Jiang, Yongfeng Zhou.  (2023)  Living Cationic Polymerization of ε-Caprolactone Catalyzed by a Metal-free Lewis Acid of Trityl Tetrafluoroborate.  MACROMOLECULES,      [PMID:] [10.1021/acs.macromol.2c02056]