Bicyclo[2.2.1]hepta-2,5-diene-rhodium chloride dimer - ≥96% , CAS No.12257-42-0

CAS: 12257-42-0 Cat. No.: B118536 Molecular Weight: 460.99 EC Number: 235-510-4 PubChem CID: 114600

GRADE & PURITY ≥96%

Synonyms

Chiralyst P461 | EINECS 235-510-4 | (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER | DTXSID10924203 | bicyclo[2.2.1]hepta-2,5-diene;rhodium(2+);dichloride | FT-0696287 | Bis((2,3,5,6-eta)-bicyclo(2.2.1)hepta-2,5-diene)di-mu-chlorodirhodium | Rhodiu

Storage

Room temperature,Argon charged

Shipped In

Normal

Overview

Precatalysts for Asymmetric and Cross-Coupling Catalysis，Hydrosilylation Catalysts

Catalyst for valence isomerization and N-heterocyclization; incombination with phosphorus ligands are catalysts for hydrogenationof many functional groups and hydroformylation; withchiral ligands are catalysts for asymmetric hydrogenation.

Product class
M-C, Homogeneous Catalysts, Diene/Dienyl Ligands

Reaction type
Hydrogenation, Asymmetric Reactions, CH-Activation, Hydroformylation, Asymmetric Hydrogenation, Hydrosilylation, Isomerization

Chemical properties

Chemical formula

C14H16Cl2Rh2

Empirical formula

[Rh(nbd)Cl]2

Molecular weight

461.00

Metal

Rh

Theoretical metal content

45

Physical state

crystalline

Color

orange

Specifications

Synonyms

Chiralyst P461 | EINECS 235-510-4 | (BICYCLO[2.2.1]HEPTA-2, 5-DIENE)CHLORORHODIUM(I) DIMER | DTXSID10924203 | bicyclo[2.2.1]hepta-2, 5-diene;rhodium(2+);dichloride | FT-0696287 | Bis((2, 3, 5, 6-eta)-bicyclo(2.2.1)hepta-2, 5-diene)di-mu-chlorodirhodium | Rhodiu

Specifications & Purity

≥96%

Storage

Room temperature, Argon charged

Shipped In

Normal

Purity

≥96%

Names and Identifiers

• Canonical Smiles: C1C2C=CC1C=C2.C1C2C=CC1C=C2.[Cl-].[Cl-].[Rh+2]
• IUPAC Name: bicyclo[2.2.1]hepta-2,5-diene;rhodium(2+);dichloride
• InChIKey: HCZNBZKRJTYNCE-UHFFFAOYSA-L
• INCHI: 1S/2C7H8.2ClH.Rh/c2*1-2-7-4-3-6(1)5-7;;;/h2*1-4,6-7H,5H2;2*1H;/q;;;;+2/p-2
• Isomeric SMILES: C1C2C=CC1C=C2.C1C2C=CC1C=C2.[Cl-].[Cl-].[Rh+2]
• WGK Germany: 3
• PubChem CID: 114600
• Molecular Weight: 460.99
• Reaxy-Rn: 16998692

Chemical and Physical Properties

• Solubility: Slightly soluble in acetone, chloroform, methanol and insoluble in water.
• Sensitivity: Moisture sensitive.Air sensitive

References

1. Huimin Duan, Lijie Yin, Tao Chen, Dongming Qi, Dongyue Zhang.  (2022)  A “metal ions-induced poisoning behavior of biomolecules” inspired polymeric probe for Cu2+ selective detection on basis of coil to helix conformation transition.  EUROPEAN POLYMER JOURNAL,      [PMID:] [10.1016/j.eurpolymj.2022.111070]