Rhenium pentacarbonyl chloride - ≥98% , CAS No.14099-01-5

CAS: 14099-01-5 Cat. No.: R283081 Molecular Weight: 361.71 EC Number: 237-948-1 PubChem CID: 6096982

GRADE & PURITY ≥98%

Synonyms

Rhenium(I) pentacarbonyl chloride

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Overview

Application: Used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands and also to prepare [3]-ferrocenophane complexes. Employed in preparation of a series of mixed-valence compounds of rhenium and iron these compounds find application in the study of charge-transfer processes.

Specifications

Synonyms

Rhenium(I) pentacarbonyl chloride

Specifications & Purity

≥98%

Storage

Store at 2-8°C, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥98%

Names and Identifiers

• Canonical Smiles: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].Cl[Re]
• IUPAC Name: carbon monoxide;chlororhenium
• InChIKey: JQUUAHKBIXPQAP-UHFFFAOYSA-M
• INCHI: 1S/5CO.ClH.Re/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
• Isomeric SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].Cl[Re]
• PubChem CID: 6096982
• Molecular Weight: 361.71

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic salts
    • Class Organic metal salts
      • Subclass Organic transition metal salts

• Kingdom: Organic compounds
• Superclass: Organic salts
• Class: Organic metal salts
• Subclass: Organic transition metal salts
• Intermediate Tree Nodes: Not available
• Direct Parent: Organic transition metal salts
• Alternative Parents: Organic oxygen compounds Hydrocarbon derivatives Organic cations
• Molecular Framework: Not available
• Substituents: Organic transition metal salt - Organic oxygen compound - Hydrocarbon derivative - Organic cation - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as organic transition metal salts. These are organic salt compounds containing a transition metal atom in its ionic form.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Insoluble in water.
• Sensitivity: Moisture & Air sensitive
• Molecular Weight: 361.710 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 361.899 Da
• Monoisotopic Mass: 361.899 Da
• Topological Polar Surface Area: 5.000 Ų
• Heavy Atom Count: 12
• Formal Charge: 0
• Complexity: 12.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 6

XLogP3

References

1. Yu-Yi Ling, Qing-Hua Shen, Liang Hao, Zhi-Yuan Li, Long-Bo Yu, Xiao-Xiao Chen, Cai-Ping Tan.  (2025)  Theranostic Rhenium Complexes as Suborganelle-Targeted Copper Ionophores To Stimulate Cuproptosis for Cancer Immunotherapy.  ACS Applied Materials & Interfaces,      [PMID:40025808] [10.1021/acsami.5c01443]