D-(+)-Glyceraldehyde - ≥80% , CAS No.453-17-8

CAS: 453-17-8 Cat. No.: D134978 Molecular Weight: 90.08 Beilstein Registry Number: 1720474 EC Number: 207-217-1

GRADE & PURITY ≥80%

Synonyms

DTXSID70196464 | GLYCERALDEHYDE; (2R)-2,3-DIHYDROXYPROPANAL | DB02536 | NSC 91534 | 1-(4-bromo-phenyl)-pentan-1-one | L-Leucyl-L-alanine hydrate | (2R)-2,3-DIHYDROXYPROPANAL | 3GR | 41A680M0WB | D-2,3-dihydroxypropanal | AKOS016844136 | BDBM16443 | EINECS

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Overview

D-(+)-Glyceraldehyde is the R enantiomer of the triose monosaccharide glyceraldehyde. Glyceraldehyde is the simplest of all common aldoses and is an intermediate compound in carbohydrate metabolism.
An intermediate in carbohydrate metabolism

Specifications

Synonyms

DTXSID70196464 | GLYCERALDEHYDE; (2R)-2, 3-DIHYDROXYPROPANAL | DB02536 | NSC 91534 | 1-(4-bromo-phenyl)-pentan-1-one | L-Leucyl-L-alanine hydrate | (2R)-2, 3-DIHYDROXYPROPANAL | 3GR | 41A680M0WB | D-2, 3-dihydroxypropanal | AKOS016844136 | BDBM16443 | EINECS

Specifications & Purity

≥80%

Storage

Store at 2-8°C, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥80%

Names and Identifiers

• Canonical Smiles: C(C(C=O)O)O
• IUPAC Name: (2R)-2,3-dihydroxypropanal
• InChIKey: MNQZXJOMYWMBOU-VKHMYHEASA-N
• INCHI: 1S/C3H6O3/c4-1-3(6)2-5/h1,3,5-6H,2H2/t3-/m0/s1
• Isomeric SMILES: C([C@H](C=O)O)O
• WGK Germany: 3
• Molecular Weight: 90.08
• Beilstein: 1720474
• Reaxy-Rn: 635844
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=635844&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic oxygen compounds
    • Class Organooxygen compounds
      • Subclass Carbohydrates and carbohydrate conjugates

• Kingdom: Organic compounds
• Superclass: Organic oxygen compounds
• Class: Organooxygen compounds
• Subclass: Carbohydrates and carbohydrate conjugates
• Intermediate Tree Nodes: Not available
• Direct Parent: Monosaccharides
• Alternative Parents: Alpha-hydroxyaldehydes Secondary alcohols 1,2-diols Short-chain aldehydes Primary alcohols Organic oxides Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Monosaccharide - Alpha-hydroxyaldehyde - Secondary alcohol - 1,2-diol - Organic oxide - Hydrocarbon derivative - Short-chain aldehyde - Primary alcohol - Carbonyl group - Aldehyde - Alcohol - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as monosaccharides. These are compounds containing one carbohydrate unit not glycosidically linked to another such unit, and no set of two or more glycosidically linked carbohydrate units. Monosaccharides have the general formula CnH2nOn.
• External Descriptors: Aldoses

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Sensitivity: air sensitive
• Flash Point(°F): 235.4 °F
• Flash Point(°C): 113 °C
• Molecular Weight: 90.080 g/mol
• XLogP3: -1.600
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 90.0317 Da
• Monoisotopic Mass: 90.0317 Da
• Topological Polar Surface Area: 57.500 Ų
• Heavy Atom Count: 6
• Formal Charge: 0
• Complexity: 43.300
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 1
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

References

1. Muge Niu, Yucui Hou, Weize Wu, Shuhang Ren, Ru Yang.  (2018)  Successive C1–C2 bond cleavage: the mechanism of vanadium(V)-catalyzed aerobic oxidation of D-glucose to formic acid in aqueous solution.  PHYSICAL CHEMISTRY CHEMICAL PHYSICS,  20  (26): (17942-17951).  [PMID:29926044] [10.1039/C8CP02352B]