MorDalphos Pd G3 , CAS No.2222690-89-1

CAS: 2222690-89-1 Cat. No.: M432345 Molecular Weight: 833.37 PubChem CID: 117065520

Synonyms

Mesyl(2-(di-1-adamantylphosphino)morpholinobenzene)[2-(2′-amino-1,1′-biphenyl)]palladium(II),, MorDalphos-G3-palladacycle, (2-(Di-1-adamantylphosphino)morpholinobenzene)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate

Storage

Room temperature

Overview

General Description

MorDalphos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. MorDalphos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

Specifications

Synonyms

Mesyl(2-(di-1-adamantylphosphino)morpholinobenzene)[2-(2′-amino-1, 1′-biphenyl)]palladium(II), , MorDalphos-G3-palladacycle, (2-(Di-1-adamantylphosphino)morpholinobenzene)[2-(2′-amino-1, 1′-biphenyl)]palladium(II) methanesulfonate

Storage

Room temperature

Names and Identifiers

• Canonical Smiles: CS(=O)(=O)O.C1COCCN1C2=CC=CC=C2P(C34CC5CC(C3)CC(C5)C4)C67CC8CC(C6)CC(C8)C7.C1=CC=C([C-]=C1)C2=CC=CC=C2N.[Pd]
• IUPAC Name: bis(1-adamantyl)-(2-morpholin-4-ylphenyl)phosphane;methanesulfonic acid;palladium;2-phenylaniline
• InChIKey: RYGVVEDSBWPZKS-UHFFFAOYSA-N
• INCHI: 1S/C30H42NOP.C12H10N.CH4O3S.Pd/c1-2-4-28(27(3-1)31-5-7-32-8-6-31)33(29-15-21-9-22(16-29)11-23(10-21)17-29)30-18-24-12-25(19-30)14-26(13-24)20-30;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h1-4,21-26H,5-20H2;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;-1
• Isomeric SMILES: CS(=O)(=O)O.C1COCCN1C2=CC=CC=C2P(C34CC5CC(C3)CC(C5)C4)C67CC8CC(C6)CC(C8)C7.C1=CC=C([C-]=C1)C2=CC=CC=C2N.[Pd]
• PubChem CID: 117065520
• Molecular Weight: 833.37