p-Toluenesulfonic acid monohydrate - ≥98% , CAS No.6192-52-5

CAS: 6192-52-5 Cat. No.: T305333 Molecular Weight: 190.22 Beilstein Registry Number: 3568023 EC Number: 612-715-0

GRADE & PURITY ≥98%

Synonyms

4-methylbenzenesulfonic acid;hydrate | ptoluene sulfonic acid | p-Toluene sulfonic acid hydrate | p-Toluenesulfonic acid monohydrate | p-toluene sulfonate hydrate | p-Toluenesulphonic acid monohydrate | p-toluene-sulphonic acid monohydrate | p-toluensulph

Storage

Argon charged,Room temperature

Shipped In

Normal

Overview

p-Toluenesulfonic acid monohydrate, an oxonium salt, is an inexpensive and easy to handle organic catalyst used in organic synthesis. The study of its crystalline structure shows that it is monoclinic with P21/c space group. Its solubility in aqueous sulfuric acid solutions has been studied

p-Toluenesulfonic acid monohydrate (p-TsOH·H2O) may be used as a catalyst in the synthesis of the following:

· Unsymmetrical benzils.

· Highly substituted piperidines.

· 1,3,5-Trisubstituted benzenes by trimerization of alkynes.

· Triazoloquinazolinone and benzimidazoquinazolinone derivatives.

· 1,3,5-Trisubstituted pyrazoles derivatives.

· Selenated ketene dithioacetals

Specifications

Synonyms

4-methylbenzenesulfonic acid;hydrate | ptoluene sulfonic acid | p-Toluene sulfonic acid hydrate | p-Toluenesulfonic acid monohydrate | p-toluene sulfonate hydrate | p-Toluenesulphonic acid monohydrate | p-toluene-sulphonic acid monohydrate | p-toluensulph

Specifications & Purity

≥98%

Biochemical and Physiological Mechanisms

p-Toluenesulfonic acid monohydrate is an organic-soluble acid catalyst in organic synthesis. The catalyst has been incorporated in the esterification of carboxylic acids or transesterification of esters. The compound has been used as a reducing agent for

Storage

Argon charged, Room temperature

Shipped In

Normal

Purity

≥98%

Names and Identifiers

• Pubchem Sid: 504759109
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504759109
• Canonical Smiles: CC1=CC=C(C=C1)S(=O)(=O)O.O
• IUPAC Name: 4-methylbenzenesulfonic acid;hydrate
• InChIKey: KJIFKLIQANRMOU-UHFFFAOYSA-N
• INCHI: 1S/C7H8O3S.H2O/c1-6-2-4-7(5-3-6)11(8,9)10;/h2-5H,1H3,(H,8,9,10);1H2
• Isomeric SMILES: CC1=CC=C(C=C1)S(=O)(=O)O.O
• WGK Germany: 1
• RTECS: DB7164000
• Alternate CAS: 104-15-4
• UN Number: 2585
• Packing Group: III
• Molecular Weight: 190.22
• Beilstein: 3568023
• Reaxy-Rn: 3568023

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Class Benzene and substituted derivatives
      • Subclass Benzenesulfonic acids and derivatives

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Class: Benzene and substituted derivatives
• Subclass: Benzenesulfonic acids and derivatives
• Intermediate Tree Nodes: Not available
• Direct Parent: p-Methylbenzenesulfonates
• Alternative Parents: Tosyl compounds Benzenesulfonyl compounds 1-sulfo,2-unsubstituted aromatic compounds Sulfonyls Organosulfonic acids Organic oxides Hydrocarbon derivatives
• Molecular Framework: Aromatic homomonocyclic compounds
• Substituents: P-methylbenzenesulfonate - Tosyl compound - Benzenesulfonyl group - 1-sulfo,2-unsubstituted aromatic compound - Arylsulfonic acid or derivatives - Toluene - Sulfonyl - Organosulfonic acid - Organosulfonic acid or derivatives - Organic sulfonic acid or derivatives - Organic oxygen compound - Organic oxide - Hydrocarbon derivative - Organosulfur compound - Aromatic homomonocyclic compound
• Description: This compound belongs to the class of organic compounds known as p-methylbenzenesulfonates. These are benzenesulfonic acids (or derivative thereof) carrying a methyl group at the para- position.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Soluble in water, alcohols, and other polar organic solvents.
• Sensitivity: Hygroscopic
• Flash Point(°F): 302°F
• Flash Point(°C): 150℃
• Boil Point(°C): 140 °C/20 mmHg
• Melt Point(°C): 103-107℃
• Molecular Weight: 190.220 g/mol
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 1
• Exact Mass: 190.03 Da
• Monoisotopic Mass: 190.03 Da
• Topological Polar Surface Area: 63.800 Ų
• Heavy Atom Count: 12
• Formal Charge: 0
• Complexity: 206.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

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61. Yanying Hao, Anping Tian, Jin Zhu, Jinshi Fan, Yong Yang.  (2020)  Synthesis and Evaluation of Bio-Based Plasticizers from 5-Hydroxymethyl-2-Furancarboxylic Acid for Poly(vinyl chloride).  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/acs.iecr.0c03356]

62. Jianyu Wu, Zilun Tang, Xiaochun Liu, Wenjing Lin, Minghui Feng, Xiaofeng Lin, Yuxin Gu, Yong Li, Guobin Yi.  (2020)  A facile strategy improving poly(vinyl chloride) stability by introducing unsaturated maleic acid-sorbitol ester and zinc maleic acid-sorbitol ester complex.  POLYMER DEGRADATION AND STABILITY,      [PMID:] [10.1016/j.polymdegradstab.2020.109343]

63. Shiya Zhou, Shuwen Fu, Hanle Wang, Yanhao Deng, Xing Zhou, Wei Sun, Yinglei Zhai.  (2020)  Acetal-linked polymeric prodrug micelles based on aliphatic polycarbonates for paclitaxel delivery: preparation, characterization, in vitro release and anti-proliferation effects.  JOURNAL OF BIOMATERIALS SCIENCE-POLYMER EDITION,      [PMID:32619161] [10.1080/09205063.2020.1792046]

64. Jianwei Bai, Xiaofei Ma, Jingjie Zhang, Huijun Yan, Kewei Wang, Jun Wang.  (2020)  Synthesis of microporous aromatic framework with scholl-coupling reaction for efficient uranium (VI) capture.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,      [PMID:] [10.1016/j.colsurfa.2020.125131]

65. Wan-Xia Wu.  (2020)  Lipase-catalyzed synthesis and post-polymerization modification of new fully bio-based poly(hexamethylene γ-ketopimelate) and poly(hexamethylene γ-ketopimelate-co-hexamethylene adipate) copolyesters.  E-POLYMERS,  20  (1): (214-225).  [PMID:] [10.1515/epoly-2020-0016]

66. Lijin Huang, Naqing Mao, Qian Yan, Dingwen Zhang, Qin Shuai.  (2019)  Magnetic Covalent Organic Frameworks for the Removal of Diclofenac Sodium from Water.  ACS Applied Nano Materials,      [PMID:] [10.1021/acsanm.9b01969]

67. Ziyang Chang, Xianhui An, Xueren Qian.  (2019)  High mass loading polyaniline layer anchored cellulose fibers: Enhanced interface junction for high conductivity and flame retardancy.  CARBOHYDRATE POLYMERS,      [PMID:31887901] [10.1016/j.carbpol.2019.115660]

68. Yang Zhou, Zhipeng Gu, Jie Liu, Keqing Huang, Guiting Liu, Jun Wu.  (2019)  Arginine based poly (ester amide)/ hyaluronic acid hybrid hydrogels for bone tissue Engineering.  CARBOHYDRATE POLYMERS,      [PMID:31887895] [10.1016/j.carbpol.2019.115640]

69. Xiao-Fan Lu, Wen-Hua Ji, Lin Yuan, Shui Yu, Dian-Shun Guo.  (2019)  Preparation of Carboxy-Functionalized Covalent Organic Framework for Efficient Removal of Hg2+ and Pb2+ from Water.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/acs.iecr.9b03138]

70. Chi Wei-Wen, Zhang Rong-Yuan, Han Ting, Du Jian, Li Hong-Kun, Zhang Wei-Jie, Li Yong-Fang, Tang Ben Zhong.  (2019)  Facile Synthesis of Functional Poly(methyltriazolylcarboxylate)s by Solvent- and Catalyst-free Butynoate-Azide Polycycloaddition.  CHINESE JOURNAL OF POLYMER SCIENCE,  38  (1): (17-23).  [PMID:] [10.1007/s10118-019-2316-y]

71. Daidong Wei, Bing Liao, Jianheng Huang, Min Zhang, Hao Pang.  (2019)  Fabrication of castor oil-based hyperbranched urethane acrylate UV-curable coatings via thiol-ene click reactions.  PROGRESS IN ORGANIC COATINGS,      [PMID:] [10.1016/j.porgcoat.2019.05.039]

72. Nairong Hao, Xiaozheng Duan, Hongjun Yang, Ahmad Umair, Mo Zhu, Muhammad Zaheer, Jinxian Yang, Lianwei Li.  (2019)  How Does the Branching Effect of Macromonomer Influence the Polymerization, Structural Features, and Solution Properties of Long-Subchain Hyperbranched Polymers?.  MACROMOLECULES,      [PMID:] [10.1021/acs.macromol.8b02364]

73. Jie Zhu, Hua Han, Faxue Li, Xueli Wang, Jianyong Yu, Chih-Chang Chu, Dequn Wu.  (2018)  Self-assembly of amino acid-based random copolymers for antibacterial application and infection treatment as nanocarriers.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:30690388] [10.1016/j.jcis.2018.12.091]

74. Songqi Ma, Jingjing Wei, Zhen Jia, Tao Yu, Wangchao Yuan, Qiong Li, Sheng Wang, Shusen You, Ren Liu, Jin Zhu.  (2018)  Readily recyclable, high-performance thermosetting materials based on a lignin-derived spiro diacetal trigger.  Journal of Materials Chemistry A,  7  (3): (1233-1243).  [PMID:] [10.1039/C8TA07140C]

75. Puyou Jia, Minrui Zheng, Yufeng Ma, Guodong Feng, Haoyu Xia, Lihong Hu, Meng Zhang, Yonghong Zhou.  (2018)  Clean synthesis of epoxy plasticizer with quaternary ammonium phosphotungstate as catalyst from a byproduct of cashew nut processing.  Journal of Cleaner Production,      [PMID:] [10.1016/j.jclepro.2018.09.238]

76. Wei Yuan, Weiwen Chi, Ting Han, Jun Du, Hongkun Li, Yongfang Li, Ben Zhong Tang.  (2018)  Metal-free phenylpropiolate–azide polycycloaddition: efficient synthesis of functional poly(phenyltriazolylcarboxylate)s.  Polymer Chemistry,  9  (42): (5215-5223).  [PMID:] [10.1039/C8PY01041B]

77. Wei Daidong, Liao Bing, Yong Qiwen, Wang Huiyi, Li Tao, Huang Jianheng, Pang Hao.  (2018)  Castor oil-based waterborne hyperbranched polyurethane acrylate emulsion for UV-curable coatings with excellent chemical resistance and high hardness.  Journal of Coatings Technology and Research,  16  (2): (415-428).  [PMID:] [10.1007/s11998-018-0120-1]

78. Man Du, Baolong Huo, Jiemin Liu, Mengwen Li, Ao Shen, Xue Bai, Yaru Lai, Leqiu Fang, Yunxu Yang.  (2018)  A turn-on fluorescent probe based on Si-rhodamine for sensitive and selective detection of phosgene in solution and in the gas phase.  Journal of Materials Chemistry C,  6  (39): (10472-10479).  [PMID:] [10.1039/C8TC03242D]

79. Yunzhe Jiang, Chuanyao Liu, Jürgen Caro, Aisheng Huang.  (2018)  A new UiO-66-NH2 based mixed-matrix membranes with high CO2/CH4 separation performance.  MICROPOROUS AND MESOPOROUS MATERIALS,      [PMID:] [10.1016/j.micromeso.2018.08.003]

80. Chen Shao, Kun Shang, Huaibao Xu, Yu Zhang, Zhichao Pei, Yuxin Pei.  (2018)  Facile fabrication of hypericin-entrapped glyconanoparticles for targeted photodynamic therapy.  International Journal of Nanomedicine,      [PMID:30087563] [10.2147/IJN.S161262]

81. Ruming Jiang, Meng Cao, Meiying Liu, Liangji Liu, Qiang Huang, Hongye Huang, Yuanqing Wen, Qian-yong Cao, Xiaoyong Zhang, Yen Wei.  (2018)  AIE-active self-assemblies from a catalyst-free thiol-yne click reaction and their utilization for biological imaging.  Materials Science & Engineering C-Materials for Biological Applications,      [PMID:30184787] [10.1016/j.msec.2018.06.040]

82. Shi Wang, Hao Xu, Ailian Wang, Xu Liu, Jie Chen, Zhinan Wang, Di Feng, Qinghui Zeng, Liaoyun Zhang.  (2018)  Nanocomposite All-Solid-State Polymer Electrolyte for High-Performance Lithium Batteries.  Energy Technology,  7  (1): (122-130).  [PMID:] [10.1002/ente.201800362]

83. Man Du, Baolong Huo, Jiemin Liu, Mengwen Li, Leqiu Fang, Yunxu Yang.  (2018)  A near-infrared fluorescent probe for selective and quantitative detection of fluoride ions based on Si-Rhodamine.  ANALYTICA CHIMICA ACTA,      [PMID:30032767] [10.1016/j.aca.2018.05.013]

84. Li Song, Bao Zhang, E Jin, Chunsheng Xiao, Gao Li, Xuesi Chen.  (2018)  A reduction-sensitive thermo-responsive polymer: Synthesis, characterization, and application in controlled drug release.  EUROPEAN POLYMER JOURNAL,      [PMID:] [10.1016/j.eurpolymj.2018.02.022]

85. Peng Xinwen, Xiang Zhihua, Du Fan, Tan Jiewen, Zhong Linxin, Sun Runcang.  (2017)  Amphiphilic xylan–cholic acid conjugates: synthesis and self-assembly behaviors in aqueous solution.  CELLULOSE,  25  (1): (245-257).  [PMID:] [10.1007/s10570-017-1595-0]

86. Youbing Mu, Zelin Wu, Danfeng Pei, Jiming Wang, Xiaobo Wan.  (2017)  A versatile platform to achieve mechanically robust mussel-inspired antifouling coatings via grafting-to approach.  Journal of Materials Chemistry B,  6  (1): (133-142).  [PMID:32254201] [10.1039/C7TB02400B]

87. Liqi Dong, Youshan Zhang, Xuemin Duan, Xiaofei Zhu, Hui Sun, Jingkun Xu.  (2017)  Chiral PEDOT-Based Enantioselective Electrode Modification Material for Chiral Electrochemical Sensing: Mechanism and Model of Chiral Recognition.  ANALYTICAL CHEMISTRY,      [PMID:28809103] [10.1021/acs.analchem.7b01095]

88. Haosheng Xin, Tingwei Zhang, Wenzhi Li, Mingxue Su, Song Li, Qun Shao, Longlong Ma.  (2017)  Dehydration of glucose to 5-hydroxymethylfurfural and 5-ethoxymethylfurfural by combining Lewis and Brønsted acid.  RSC Advances,  7  (66): (41546-41551).  [PMID:] [10.1039/C7RA07684C]

89. Wei Yuan, Gaoyi Han, Yaoming Xiao, Yunzhen Chang, Ying Zhang, Hua Song.  (2017)  Semitransparent, flexible electrochemical capacitors with excellent stability fabricated with polypyrrole–titanium mesh electrodes.  JOURNAL OF APPLIED POLYMER SCIENCE,  134  (35): (45235).  [PMID:] [10.1002/app.45235]

90. Jinyue Dai, Songqi Ma, Na Teng, Xinyan Dai, Xiaobin Shen, Sheng Wang, Xiaoqing Liu, Jin Zhu.  (2017)  2,5-Furandicarboxylic Acid- and Itaconic Acid-Derived Fully Biobased Unsaturated Polyesters and Their Cross-Linked Networks.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/acs.iecr.7b00049]

91. Guanyao Wang, Xingyi Huang, Pingkai Jiang.  (2017)  Bio-inspired polydopamine coating as a facile approach to constructing polymer nanocomposites for energy storage.  Journal of Materials Chemistry C,  5  (12): (3112-3120).  [PMID:] [10.1039/C7TC00387K]

92. Wei Yuan, Weiwen Chi, Ruimin Liu, Hongkun Li, Yongfang Li, Ben Zhong Tang.  (2017)  Synthesis of Poly(phenyltriazolylcarboxylate)s with Aggregation-Induced Emission Characteristics by Metal-Free 1,3-Dipolar Polycycloaddition of Phenylpropiolate and Azides.  MACROMOLECULAR RAPID COMMUNICATIONS,  38  (5): (1600745).  [PMID:28105792] [10.1002/marc.201600745]

93. Xu Li, Lan Wu, Qiong Tang, Jinxiang Dong.  (2017)  Solvent-Free Acetalization of Glycerol with n-Octanal using Combined Brønsted Acid-Surfactant Catalyst.  TENSIDE SURFACTANTS DETERGENTS,  54  (1): (54-63).  [PMID:] [10.3139/113.110480]

94. Dongren Cai, Jinbei Yang, Hairong Da, Ling Li, Hongxing Wang, Ting Qiu.  (2016)  Densities and viscosities of binary mixtures N,N-dimethyl-N-(3-sulfopropyl)cyclohexylammonium tosylate with water and methanol at T = (303.15 to 328.15) K.  JOURNAL OF MOLECULAR LIQUIDS,      [PMID:] [10.1016/j.molliq.2016.12.089]

95. Wei Chen, Yanyan Zhou, Ying Li, Jun Sun, Xiangqiang Pan, Qian Yu, Nianchen Zhou, Zhengbiao Zhang, Xiulin Zhu.  (2016)  Shape-memory and self-healing polyurethanes based on cyclic poly(ε-caprolactone).  Polymer Chemistry,  7  (44): (6789-6797).  [PMID:] [10.1039/C6PY01638C]

96. Tingwei Zhang, Wei Fan, Wenzhi Li, Zhiping Xu, Haosheng Xin, Mingxue Su, Yijuan Lu, Longlong Ma.  (2016)  One-Pot Conversion of Carbohydrates into 5-(Hydroxymethyl)furfural using Heterogeneous Lewis-Acid and Brønsted-Acid Catalysts.  Energy Technology,  5  (5): (747-755).  [PMID:] [10.1002/ente.201600492]

97. Sheng-Qi Chen, Chen He, Hui-Juan Li, Peng-Yun Li, Wei-Dong He.  (2016)  Janus long-chain hyperbranched copolymers of PSt and POEGMA from a self-assembly mediated click reaction.  Polymer Chemistry,  7  (14): (2476-2485).  [PMID:] [10.1039/C6PY00060F]

98. Taotao Qiang, Xin Gao, Jing Ren, Xiaoke Chen, Xuechuan Wang.  (2015)  A Chrome-Free and Chrome-Less Tanning System Based on the Hyperbranched Polymer.  ACS Sustainable Chemistry & Engineering,      [PMID:] [10.1021/acssuschemeng.5b00917]

99. Zhiping Xu, Wenzhi Li, Zhijie Du, Hao Wu, Hasan Jameel, Hou-min Chang, Longlong Ma.  (2015)  Conversion of corn stalk into furfural using a novel heterogeneous strong acid catalyst in γ-valerolactone.  BIORESOURCE TECHNOLOGY,      [PMID:26454364] [10.1016/j.biortech.2015.09.104]

100. Tao Chang, Xiaorui Gao, Li Bian, Xiying Fu, Mingxia Yuan, Huanwang Jing.  (2015)  Coupling of epoxides and carbon dioxide catalyzed by Brönsted acid ionic liquids.  CHINESE JOURNAL OF CATALYSIS,      [PMID:] [10.1016/S1872-2067(14)60227-8]

101. Jinyue Dai, Songqi Ma, Yonggang Wu, Lijing Han, Lisheng Zhang, Jin Zhu, Xiaoqing Liu.  (2015)  Polyesters derived from itaconic acid for the properties and bio-based content enhancement of soybean oil-based thermosets.  GREEN CHEMISTRY,  17  (4): (2383-2392).  [PMID:] [10.1039/C4GC02057J]

102. Xie Andong, Chen Hongxiang, Xu Caixia, Chen Hailun, Zhou Yu, Lin Yinli, Yang Minghua.  (2014)  Synthesis and characterization of waterborne polyurethane thickeners based on hyperbranched polyester.  Journal of Coatings Technology and Research,  12  (2): (325-332).  [PMID:] [10.1007/s11998-014-9636-1]

103. Ze Zhang, Ye-Zi You, De-Cheng Wu, Chun-Yan Hong.  (2014)  A novel multicomponent reaction and its application in sequence-ordered functional polymer synthesis.  POLYMER,      [PMID:] [10.1016/j.polymer.2014.12.012]

104. Jinyue Dai, Songqi Ma, Xiaoqing Liu, Lijing Han, Yonggang Wu, Xinyan Dai, Jin Zhu.  (2014)  Synthesis of bio-based unsaturated polyester resins and their application in waterborne UV-curable coatings.  PROGRESS IN ORGANIC COATINGS,      [PMID:] [10.1016/j.porgcoat.2014.10.007]

105. Dongming Xing, Lie Ma, Changyou Gao.  (2014)  Synthesis of Functionalized Poly(ester carbonate) with Laminin-Derived Peptide for Promoting Neurite Outgrowth of PC12 cells.  MACROMOLECULAR BIOSCIENCE,  14  (10): (1429-1436).  [PMID:24962245] [10.1002/mabi.201400186]

106. Leqin He, Shenjun Qin, Tao Chang, Yuzhuang Sun, Jiquan Zhao.  (2014)  Geminal Brønsted Acid Ionic Liquids as Catalysts for the Mannich Reaction in Water.  INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES,  15  (5): (8656-8666).  [PMID:24837832] [10.3390/ijms15058656]

107. Yuanlin Li, Ting Su, Sai Li, Yusi Lai, Bin He, Zhongwei Gu.  (2014)  Polymeric micelles with π–π conjugated moiety on glycerol dendrimer as lipophilic segments for anticancer drug delivery.  Biomaterials Science,  2  (5): (775-783).  [PMID:32481847] [10.1039/C3BM60267B]

108. Leqin He, Shenjun Qin, Tao Chang, Yuzhuang Sun, Xiaorui Gao.  (2012)  Biodiesel synthesis from the esterification of free fatty acids and alcohol catalyzed by long-chain Brønsted acid ionic liquid.  Catalysis Science & Technology,  3  (4): (1102-1107).  [PMID:] [10.1039/C2CY20714A]

109. Lianwei Li, Chen He, Weidong He, Chi Wu.  (2011)  Formation Kinetics and Scaling of “Defect-Free” Hyperbranched Polystyrene Chains with Uniform Subchains Prepared from Seesaw-Type Macromonomers.  MACROMOLECULES,      [PMID:] [10.1021/ma201687s]

110. Qianling Cui, Feipeng Wu, Erjian Wang.  (2011)  Novel amphiphilic diblock copolymers bearing acid-labile oxazolidine moieties: Synthesis, self-assembly and responsive behavior in aqueous solution.  POLYMER,      [PMID:] [10.1016/j.polymer.2011.02.022]

111. Haowen Cui, Xu Zhang, Haian Xia.  (2024)  A novel deep eutectic solvent-methyl isobutyl ketone biphasic system for the catalytic conversion of wheat straw to furfural and recovery of cellulose and lignin.  INDUSTRIAL CROPS AND PRODUCTS,      [PMID:] [10.1016/j.indcrop.2024.119061]

112. Yannan Cheng, Yuanfang Huo, Yongle Yu, Ping duan, Xianzhen Dong, Zirui Yu, Qiang Cheng, Honglian Dai, Zhenyu Pan.  (2024)  A Photothermal Responsive System Accelerating Nitric Oxide Release to Enhance Bone Repair by Promoting Osteogenesis and Angiogenesis.  Materials Today Bio,      [PMID:39221216] [10.1016/j.mtbio.2024.101180]

113. Shiji Liu, Liang Shuai, Qian Zhu, Lei Cao, Feng Gu, Lanlan Fan, Shixian Xiong.  (2025)  All-aerosol-jet-printed Fe3+ modified bilayers polyaniline flexible room temperature sensor with enhanced ammonia sensing properties.  TALANTA,      [PMID:39908894] [10.1016/j.talanta.2025.127684]

114. Peng Zhao, Xiaojing Cui, Chizhou Wang, Xiaojie Shao, Hongyan Li, Ning Zhang, Xianglin Hou, Tiansheng Deng.  (2024)  Amphiphilic molecules affording efficient aqueous degradation of unsaturated polyester resin.  POLYMER DEGRADATION AND STABILITY,      [PMID:] [10.1016/j.polymdegradstab.2024.110774]

115. Xiaoshu Wei, Xin Dong, Meiying Huang, Zhipeng Zhou, Zihao Liang, Yuyao Li, Yonghang Yang, Jiaxing Lu, Zhilv Wang, Changye Zhan, Wei Liu, Zhikun Zheng.  (2024)  Aqueous synthesis of highly crystalline acylhydrazone COFs.  POLYMER,      [PMID:] [10.1016/j.polymer.2024.126927]

116. Qin Wang, Yu-long Liu, Zi-jie Huang, Zi-cheng Tang, De-xiang Sun, Jing-hui Yang, Xiao-dong Qi, Yong Wang.  (2025)  Bio-inspired polypyrrole nanowire arrays on melamine foam with high-performance photo/electro-thermal conversion for all-weather cleanup of crude oil.  Journal of Materials Chemistry A,      [PMID:] [10.1039/D4TA09132A]

117. Quan Yuan, Liwei Yan, Jinfeng Tian, Weiyi Ding, Zhengguang Heng, Mei Liang, Yang Chen, Huawei Zou.  (2024)  Ceramization of coordinated Zr4+ and Hf4+ in polysiloxane conferring silicone/phenolic hybrid resin with excellent thermal protection.  POLYMER,      [PMID:] [10.1016/j.polymer.2024.127089]

118. Xinhao Cen, Zhilin Cao, Liming Lin, Zhengzhou Wang.  (2024)  Construction of a mesoporous silica/ phytate-based flame-retardant hybrid and its modified epoxy resin and cyanate ester copolymer with simultaneously improved flame retardancy, smoke suppression and dielectric properties.  POLYMER,      [PMID:] [10.1016/j.polymer.2024.127418]

119. Jianbin Mo, Haochuan Li, Jinxin Yuan, Qiyu Liu, Weifeng Liu, Xueqing Qiu.  (2025)  Coordination-reinforced lignin/polyvinyl alcohol composites for indoor UV protection and temperature management.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:40132717] [10.1016/j.ijbiomac.2025.142355]

120. Xuesong Liu, Liuliu Cheng, Yehong Han, Mingyu Wang, Hongyuan Yan.  (2024)  Development of a novel second-generation polyester dendritic functionalized graphene oxide for efficient pipette tip micro solid-phase extraction and detection of venlafaxine and desvenlafaxine in urine.  JOURNAL OF CHROMATOGRAPHY A,      [PMID:39647375] [10.1016/j.chroma.2024.465582]

121. Jiatao Zhang, Bowen Guan, Yuan Zhang, Jian Hu, Tao Sun, Tungalag Dong, Xueyan Yun.  (2024)  Development of high barrier poly(l-actic acid)/chitosan/graphene oxide flexible films for meat packaging by layer-by-layer.  Food Bioscience,      [PMID:] [10.1016/j.fbio.2024.104304]

122. Jiatao Zhang, Tungalag Dong, Yuan Zhang, Jia Guo, Yulu Li, Xueyan Yun.  (2025)  Development of Micro-Crosslinked Poly(L-Lactic Acid) With Flexible, Anti-Aging, and Barrier Properties by In Situ Polymerization of Graphene Oxide.  JOURNAL OF POLYMER SCIENCE,      [PMID:] [10.1002/pol.20241069]

123. Xinyi Zhu, Bowen Li, Yimin Fan, Juan Yu.  (2025)  Direct ink writing of a bio-based ink made of low concentration cellulose nanofiber crosslinked with poly (ethylene glycol) via hydroxyl-yne click chemistry.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:39988164] [10.1016/j.ijbiomac.2025.141267]

124. Zhou Yiyang, Meng Qiuyue, Wang Chenxi, Ma Chenyu, Chen Ming, Xu Xinwen, Ding Yunsheng.  (2024)  Effect of Amino Acid Ionic Liquids on the Interfacial Structure and Degradation Behavior of PLA/PBAT Blends.  JOURNAL OF POLYMERS AND THE ENVIRONMENT,      [PMID:] [10.1007/s10924-024-03266-w]

125. Dongpeng Li, Zhao Ke, Ke Xu, Tao Li, Dandan Li, Wei Wang, Guangtao Qian, Chunhai Chen.  (2024)  Effect of benzene side groups on polyimide membranes containing spiro-bis-benzimidazole scaffold structures for gas separation.  POLYMER,      [PMID:] [10.1016/j.polymer.2024.127764]

126. Li Maohua, Gong Ping, Zhang Zhenbang, Li Linhong, Chen Yapeng, Qin Yue, Guo Yingying, Yang Rongjie, Zhang Jianxiang, Zhou Yiwei, Xu Kang, Wang Yandong, Do Hainam, Jia Xiaofei, Cai Tao, Lin Cheng-Te, Jiang Nan, Yu Jinhong.  (2024)  Electric-field-aligned liquid crystal polymer for doubling anisotropic thermal conductivity.  Communications Materials,  5  (1): (1-9).  [PMID:] [10.1038/s43246-024-00455-x]

127. Zhengxiang Zhou, Qiangqiang Yan, Yinzhong Guo, Lucy Bai, Tom Kalantar, Amy Song, Wayne Zhang, Yingfeng Yu.  (2024)  Endowing Polyurethane with Degradability via a Cleavable Bis(cyclohexanone) Oxalyldihydrazone Structure for Adhesive Detachment.  ACS Applied Polymer Materials,      [PMID:] [10.1021/acsapm.4c01032]

128. Saitao Yan, Qisheng Ye, Jiayi Wu, Wangli Yao, Baoliang Chen, Xiaoying Zhu.  (2024)  Enhancing biofouling resistance in microfiltration membranes through capsaicin-derivative functionalization.  Journal of Materials Chemistry B,      [PMID:38595308] [10.1039/D4TB00033A]

129. Huan Li, Jianfeng Li, Xin Peng, Chen Zhang, Xiaoping An.  (2024)  Hydrophobic modification of carbon microspheres and their demulsification performance in oily wastewater.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,      [PMID:] [10.1016/j.colsurfa.2024.134823]

130. Huitao Lv, Jianzhang Gao, Jiaqi Chen, Tianyu Li, Yi Liang, Bin Hu, Fuqiu Ma, Yun Xue, Yongde Yan, Emmanuel Osei Tutu.  (2024)  Innovative deep decontamination of radioactive solid surfaces using microemulsions of deep eutectic solvents in supercritical carbon dioxide.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.151793]

131. Kaiqin Song, Liping Yu, Shoulu Yang, Yan Cao, Lifen Li, Zhigang Wu, Hongtao Shi, Qiaorun Ma.  (2024)  Insights into the Chemical Structure and Antioxidant Activity of Lignin Extracted from Bamboo by Acidic Deep Eutectic Solvents.  ACS Omega,      [PMID:39371967] [10.1021/acsomega.4c06259]

132. Xiaoyong Zhang, Fan Li, Zhaozhao Li, Yongping Bai.  (2025)  Mussel-inspired Strong and Tough Hydrogel with Self-adhesive based on Dynamic Interactions for Flexible Wearable Electronics.  Journal of Materials Chemistry A,      [PMID:] [10.1039/D4TA08383K]

133. Yuanfang Huo, Yannan Cheng, Xianzhen Dong, Qiang Cheng, Xinyue Liang, Ping Duan, Yongle Yu, Lesan Yan, Tong Qiu, Zhenyu Pan, Honglian Dai.  (2024)  Pleiotropic effects of nitric oxide sustained-release system for peripheral nerve repair.  Acta Biomaterialia,      [PMID:38761961] [10.1016/j.actbio.2024.05.012]

134. Haiqin Liu, Bowen Li, Sijie Gong, Haiyang Ding, Yimin Fan, Juan Yu.  (2024)  Preparation of strong, UV-blocking and sustainable glucose-cross-linked cellulose plastics via hydroxyl-yne click reaction.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:38513903] [10.1016/j.ijbiomac.2024.131008]

135. Liang Qi, Bo-Wen Duan, Hui Wang, Yan-Jun Liu, Han Han, Meng-Meng Han, Lei Xing, Hu-Lin Jiang, Stephen J. Pandol, Ling Li.  (2024)  Reactive Oxygen Species-Responsive Nanoparticles Toward Extracellular Matrix Normalization for Pancreatic Fibrosis Regression.  Advanced Science,      [PMID:38483920] [10.1002/advs.202401254]

136. Shijian Xu, Qianqian Jia, Kai Zhang, Chuanwei Lu, Chunpeng Wang, Jifu Wang, Qiang Yong, Fuxiang Chu.  (2024)  Recyclable and mechanically tough nanocellulose reinforced natural rubber composite conductive elastomers for flexible multifunctional sensor.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:38692545] [10.1016/j.ijbiomac.2024.131946]

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138. Qingbiao Yang, Hao Zhang, Zhen Zhang, Ming Chen, Ji Gao, Cunwei Fan, Zhenjiang Li, Wei He, Jie Sun, Kai Guo.  (2025)  Substitution of Alkylphenol Polyoxyethylene Ethers with Bio-Based Surfactants: Their Synthesis, Properties, and Performance Evaluation.  LANGMUIR,      [PMID:40108990] [10.1021/acs.langmuir.4c05232]

139. Nianzhao Gao, Yanglei Zheng, Jianan ShangGuan, Haoran Sun, Junyi Jiang, Shuangfei Xiang, Shujun Zhao, Feiya Fu, Xiangdong Liu.  (2024)  Superior Epoxy Vitrimer Containing Acetal and Disulfide Bonds for Achieving High Mechanical Properties, Reprocessability, and Degradability.  MACROMOLECULES,      [PMID:] [10.1021/acs.macromol.4c00734]

140. Xiaoyong Zhang, Fan Li, Shengyue Liang, Yongping Bai.  (2024)  Sweat-enhanced adhesive hydrogel enables interfacial exchange coupling for wearable strain sensor.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.153385]

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154. Huitao Lv, Jianzhang Gao, Jiaqi Chen, Tianyu Li, Chao Peng, Yaping Li, Fuqiu Ma, Yun Xue, Yongde Yan, Emmanuel Osei Tutu.  (2024)  Deep eutectic solvent microemulsions with abundant hydrogen ions in supercritical CO2 for decontamination of radioactive solid waste: Overcoming roadblocks to hydrogen ions deficiency.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.154888]

155. Chizhou Wang, Ning Zhang, Shaodi Wu, Weijie Wang, Peng Zhao, Shiyu Jia, Yongqin Qi, Xianglin Hou, Xiaojing Cui, Tiansheng Deng.  (2024)  Efficient degradation of amine cured epoxy resin via the cleavage of C-N bond by amphiphilic dodecylbenzenesulfonic acid.  COMPOSITES SCIENCE AND TECHNOLOGY,      [PMID:] [10.1016/j.compscitech.2024.110442]

156. Yang Yonghang, Liang Baokun, Kreie Jakob, Hambsch Mike, Liang Zihao, Wang Cheng, Huang Senhe, Dong Xin, Gong Li, Liang Chaolun, Lou Dongyang, Zhou Zhipeng, Lu Jiaxing, Yang Yang, Zhuang Xiaodong, Qi Haoyuan, Kaiser Ute, Mannsfeld Stefan C. B., Liu Wei, Gölzhäuser Armin, Zheng Zhikun.  (2024)  Elastic films of single-crystal two-dimensional covalent organic frameworks.  NATURE,  630  (8018): (878-883).  [PMID:38718837] [10.1038/s41586-024-07505-x]

157. Xiangyu Wang, Lifeng Li, Xinyi Xie, Xinping Ouyang, Xueqing Qiu, Qinzhen Fan, Lihua Cheng.  (2025)  Fractionation of birch sawdust into carbohydrates and high purity lignin by ZnBr2 molten salt hydrates under mild conditions.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:40113002] [10.1016/j.ijbiomac.2025.142241]

158. Xiaowei Wu, Yuqin Li, Zhengquan Yang, Mingyu Peng, Tian Gui, Xiangshu Chen, Hidetoshi Kita.  (2025)  Intensified esterification of oleic acid and n-butanol using a beta zeolite membrane reactor at low temperature.  FUEL,      [PMID:] [10.1016/j.fuel.2025.134510]

159. Shuqin Xu, Meiling Qiu, Liyuan Liang, Yue Chen, Yajia Wang, Jing Wu, Jinghua Chen.  (2025)  Multifunctions of Sustainable Chondroitin Sulfates with Predominant Subtypes and Low Molecular Weights on Neurite Outgrowth.  BIOMACROMOLECULES,      [PMID:39835408] [10.1021/acs.biomac.4c01713]

160. Tao Yinghua, Luo Peiyu, Jing Fengya, Liu Tao, Tan Xin, Lyu Zhiyang, VeerleBernaerts Katrien, Zhang Tianzhu, Jia Ruipeng.  (2025)  Collagen-Inspired 3D Printing Electrospinning Biomimetic Patch for Abdominal Wall Defect Regeneration.  Advanced Fiber Materials,      [PMID:] [10.1007/s42765-025-00547-4]

161. Yiping Jin, Zhongwen Zhou, Zekai Yuan, Runjia Hu, Tianran Zhang, Siji Chen, Guang Chen.  (2025)  Lignin-based biochar with improved properties derived from the microbial combined chemical pretreatment of corn straw for efficient antibiotic removal.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:40180083] [10.1016/j.ijbiomac.2025.142739]

162. Xu-Qin Ran, Can Zhu, Qian-Ying Mao, Shu-Ting Xu, Shuangping Liu, Peng Gu, Yun Jiang, Xiu-Ping Yan, Hai-Long Qian.  (2025)  Monodisperse fluorinated 3D covalent organic frameworks for enhanced adsorption and extraction of perfluorocarboxylic Acids†.  Journal of Materials Chemistry A,      [PMID:] [10.1039/D5TA01329A]

163. Qiaorun Ma, Xun Meng, Hongtao Shi, Lian Chen, Jiangyao Han, Lifen Li, Liping Yu.  (2025)  Evaluation of Acidic Deep Eutectic Solvents Treatment on Enzymatic Hydrolysis Lignins: Structural Analysis and Antioxidant Activity.  Polymers,  17  (8): (1006).  [PMID:40284271] [10.3390/polym17081006]

164. Kai Zhang, Tianting Pang, Jialing Song, Maryam Mansoor, Jian Zhong, Tingting Yan, Ming Xie, Danhong Cheng, Dengsong Zhang.  (2025)  Highly Efficient Capacitive Removal of Heavy Metal Ions from Wastewater via In Situ π–π Stacking Covalent Organic Frameworks on Graphene Oxide Sheets.  ACS Applied Materials & Interfaces,      [PMID:40173393] [10.1021/acsami.4c20869]

165. Feng Yulin, Xu Fen, Sun Lixian, Shao Qiwei, Xu Rudan, Chen Yue, Yu Chuyu, Du Maozhan, Xie Yingguang.  (2025)  EG@COF as a novel layered porous composite for improving performance of supercapacitor.  JOURNAL OF POROUS MATERIALS,      [PMID:] [10.1007/s10934-025-01804-y]

166. Yuchao Mao, Ruitao Wang, Zihua Wang, Xingxing Ni, Huaiyuan Wang.  (2025)  Zero Waste-acid Emission Synthesis of PANI and Composite Fillers for Enhanced Anticorrosion Performance of the Epoxy Coatings.  Journal of Environmental Chemical Engineering,      [PMID:] [10.1016/j.jece.2025.117248]

167. Gongwei Tian, Jianhui Chen, Dan Yang, Cuiyuan Liang, Qinyi Zhao, Yan Liu, Weihong Lu, Dianpeng Qi.  (2025)  Self-healable and stretchable electrochemical sensor for sweat glucose detection.  TALANTA,      [PMID:40505535] [10.1016/j.talanta.2025.128428]

168. Fanyang Meng, Thomas L. Eberhardt, Yaru Li, Chen Xu, Hui Pan.  (2025)  Assessment of the interaction mechanisms for a novel ternary deep eutectic solvent developed to enhance the enzymatic hydrolysis of bamboo.  BIORESOURCE TECHNOLOGY,      [PMID:40446859] [10.1016/j.biortech.2025.132737]

169. Baoya Shang, Jianbing Cui, Fei Sun, Tatsuo Kaneko, Weifu Dong, Mingqing Chen, Dongjian Shi.  (2025)  Constructing intrinsic solid phase change materials with reprocessability and thermal energy storage through multiple hydrogen bonds and acetals.  Journal of Energy Storage,      [PMID:] [10.1016/j.est.2025.117138]

170. Jiayue Hu, Fei Xin, Jiaying Du, Kaixuan Feng, Yu Chen.  (2025)  Phosphorus–Nitrogen Flame Retardant for Enhanced Fire Resistance in Unsaturated Polyester Resin.  JOURNAL OF APPLIED POLYMER SCIENCE,      [PMID:] [10.1002/app.57432]

171. Yi Zheng, Yingbo Yuan, Yuanfei Han, Tianyuan Su, Qingsheng Qi.  (2025)  Recyclable chemical-enzymatic hydrolysis cascade for the degradation and closed-loop recycling of blended fabrics.  BIORESOURCE TECHNOLOGY,      [PMID:40581055] [10.1016/j.biortech.2025.132897]

172. Yonggang Guo, Zichao Guo, Yi Wang, Kangle Li, Zhendong Yin, Mingchao Shao, Qihua Wang.  (2025)  “Magnetic-bond dual-drive modulation” MXene/CNT/SmFeN polyurethane films: Exceptional EMI shielding with mechanical robustness.  COMPOSITES PART B-ENGINEERING,      [PMID:] [10.1016/j.compositesb.2025.113094]

173. Yuya Liu, Fuzhen Liu, Zhan Wang, Huiling Huang, Jing Gao.  (2025)  Haematococcus pluvialis residue as a promising dye adsorbent: enhanced by choline chloride:p-toluenesulfonic acid and cellulase treatment.  PROCESS BIOCHEMISTRY,      [PMID:] [10.1016/j.procbio.2025.10.012]

174. Juan Yu, Xinyi Zhu, Ru Guo, Bowen Li, Liqin Jiang, Zhiguo Wang, Yimin Fan.  (2025)  Construction of lignin crosslinked nanocellulose 3D-printed solar evaporators for efficient seawater desalination via hydroxyl-yne click chemistry.  CARBOHYDRATE POLYMERS,      [PMID:41320427] [10.1016/j.carbpol.2025.124673]

175. Xiao-Fan Hu, Ting Jiang, Hanqing Fan, Yan-Fang Guan, Jie-Jie Chen, Han-Qing Yu, Menachem Elimelech.  (2025)  Dual-regulated covalent organic framework membranes with near-theoretical pore sizes for angstrom-scale ion separations.  Science Advances,  11  (46):   [PMID:41223271] [10.1126/sciadv.ady3587]

176. Shuqing Sun, Rui Yuan, Li Gao, Chao Zhang, Bingxin Liu, Jing Yuan, Shiai Xu.  (2025)  Investigation on the mechanism of low temperature failure of benzene dicarboxylate plasticizers/polyvinyl chloride.  POLYMER,      [PMID:] [10.1016/j.polymer.2025.129455]

177. Jiatao Zhang, Huanlong Liu, Yifeng Wu, Jia Guo, Yulu Li, Xiaojing Wang, Shaobo Li, Xueyan Yun, Tungalag Dong.  (2025)  Self-restacked mildly reduced graphene oxide: Ultrasensitive ammonia recognition and real-time quality sensing of lamb.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2025.171949]

178. Kaizheng Wang, Hang Ren, Lulu Li, Feipeng Wang, Dihao Lei, Jiran Qin, Zhengdong Zhou, Jian Li.  (2025)  Esterification of Composition-modified Coconut Fatty Acid Distillate for the Synthesis of Insulating Esters.  IEEE TRANSACTIONS ON DIELECTRICS AND ELECTRICAL INSULATION,      [PMID:] [10.1109/TDEI.2025.3626395]

179. Tong Yu, Cuiyu Huang, Yu Zhang, Quanling Xie, Xiwen He, Langxing Chen, Yukui Zhang.  (2026)  Electrostatic assembly-derived β-ketoenamine covalent organic framework/polyacrylonitrile composite nanofiltration membrane for efficient removal of emerging contaminants.  JOURNAL OF MEMBRANE SCIENCE,      [PMID:] [10.1016/j.memsci.2026.125163]

180. Qi Li-Hua, Wang Zheng, Zhang Tong-He, Feng Zhongmin, Huang Ling, Wang Shengping, Wang Huanting.  (2026)  Asymmetrical covalent organic framework mixed matrix membranes for highly efficient gas separation.  Nature Communications,      [PMID:41571677] [10.1038/s41467-026-68790-w]

181. Yinghao Wu, Xin Zhao, Chunlei Jiao, Haigang Wang, Ming Wei, Jian Li, Yanjun Xie, Shaoliang Xiao.  (2026)  Recyclable and Reprocessable Tung Oil-Based Epoxy Resin with High Mechanical Strength.  ACS Sustainable Chemistry & Engineering,      [PMID:] [10.1021/acssuschemeng.5c10423]

182. Shuqing Sun, Jianyu Gong, Rui Yuan, Li Gao, Bingxin Liu, Shiai Xu.  (2026)  Enhancing the Cold Resistance of Phthalate Plasticizers Through Synergistic Blending.  JOURNAL OF APPLIED POLYMER SCIENCE,      [PMID:] [10.1002/app.70438]