Pentamethylcyclopentadienylrhodium(III) chloride dimer - ≥97% , CAS No.12354-85-7

CAS: 12354-85-7 Cat. No.: P470206 Molecular Weight: 618.08 EC Number: 625-704-0

GRADE & PURITY ≥97%

Synonyms

Bis(pentamethylcyclopentadienylrhodium dichloride), Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium, Bis(dichloro(pentamethylcyclopentadienyl)rhodium), 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex, Dichloro(pentamethylcyclopentadienyl

Storage

Room temperature

Overview

Description

Pentamethylcyclopentadienylrhodium(III) chloride dimer can be used as a catalyst for:Oxidative olefination reactionsC-C bond cleavage of secondary alcoholsOrtho C-H olefination of phenol derivativesOxidative annulation of pyridinesOxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2C-H bondAmidation reactionsReductive alkylation reactionsUmicore Precatalysts for Asymmetric and Cross-Coupling CatalysisCatalyst for:Oxidative olefination reactionsC-C bond cleavage of secondary alcoholsOrtho C-H olefination of phenol derivativesOxidative annulation of pyridinesOxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2C-H bondAmidation reactionsReductive alkylation reactions

Specifications

Synonyms

Bis(pentamethylcyclopentadienylrhodium dichloride), Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium, Bis(dichloro(pentamethylcyclopentadienyl)rhodium), 1, 3-Cyclopentadiene, 1, 2, 3, 4, 5-pentamethyl-, rhodium complex, Dichloro(pentamethylcyclopentadienyl

Specifications & Purity

≥97%

Storage

Room temperature

Purity

≥97%

Names and Identifiers

• Canonical Smiles: Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
• InChIKey: QNIVKTTWBMFSBR-UHFFFAOYSA-J
• INCHI: 1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4
• WGK Germany: 3
• Molecular Weight: 618.08

Chemical and Physical Properties

• Melt Point(°C): >300°C

References

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7. Shihao Li, Jiafu Shi, Yu Chen, Xinyu Mao, Shusong Liu, Yang Yang, Hong Wu, Zhongyi Jiang.  (2025)  Light-Driven Synthesis of 2-Aminoethanol from Formaldehyde and Ammonia.  ACS Catalysis,      [PMID:] [10.1021/acscatal.5c00337]

8. Xinyu Chen, Jiahui Xie, Hui Wang, Yujie Tang, Yezhou Yang, Pilang Zheng, Qihua Yang, Xin Liu, Xiaobo Li.  (2025)  Multifunctional Nano-COF-Embedded Silica Composite for Efficient Photocatalytic NADH Regeneration.  CHEMISTRY-A EUROPEAN JOURNAL,      [PMID:40350757] [10.1002/chem.202500115]

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