Rhodium(III) nitrate hydrate - ~36% rhodium (Rh) basis , CAS No.10139-58-9

CAS: 10139-58-9 Cat. No.: R431254 Molecular Weight: 288.92 EC Number: 233-397-6 PubChem CID: 150190
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GRADE & PURITY ~36% rhodium (Rh) basis
Synonyms
rhodium(3+);trinitrate | Rhodium(III) nitrate anhydrous | MFCD00011202 | DTXSID40890644 | EINECS 233-397-6 | RHODIUM(III)NITRATEHYDRATE | Nitric acid, rhodium(3+) salt | AKOS016010291 | RHODIUM(III) NITRATE | Rhodium nitrate | NSC 58267 | VXNYVYJABGOSBX-U
Storage
Room temperature
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Price
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250mg
R431254-250mg
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1g
R431254-1g
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Why this grade

~36% rhodium (Rh) basis for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

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Storage & shipping

Room temperature Ships FedEx DG Service Check lot-specific COA for exact specifications.

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Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

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Literature proof

Cited in 22 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Overview

Application

Rhodium nitrate is commonly used as a precursor to synthesize rhodium.

Specifications

Synonyms
rhodium(3+);trinitrate | Rhodium(III) nitrate anhydrous | MFCD00011202 | DTXSID40890644 | EINECS 233-397-6 | RHODIUM(III)NITRATEHYDRATE | Nitric acid, rhodium(3+) salt | AKOS016010291 | RHODIUM(III) NITRATE | Rhodium nitrate | NSC 58267 | VXNYVYJABGOSBX-U
Specifications & Purity
~36% rhodium (Rh) basis
Storage
Room temperature
Shipped In
FedEx DG Service
This product requires cold chain shipping. Ground and other economy services are not available.
Names and Identifiers
Canonical Smiles[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[Rh+3]
IUPAC Namerhodium(3+);trinitrate
InChIKeyVXNYVYJABGOSBX-UHFFFAOYSA-N
INCHI1S/3NO3.Rh/c3*2-1(3)4;/q3*-1;+3
Isomeric SMILES [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[Rh+3]
WGK Germany 3
PubChem CID 150190
UN Number 3085
Packing Group I
Molecular Weight 288.92

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

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✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

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📊 Datasheet

Quick-reference summary of product specifications and applications.

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🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

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Advanced Data

Taxonomic Classification

Taxonomy Tree

KingdomInorganic compounds
SuperclassMixed metal/non-metal compounds
ClassTransition metal oxoanionic compounds
SubclassTransition metal nitrates
Intermediate Tree Nodes Not available
Direct ParentTransition metal nitrates
Alternative Parents Inorganic salts  Inorganic oxides  
Molecular FrameworkNot available
Substituents Transition metal nitrate - Inorganic oxide - Inorganic salt
DescriptionThis compound belongs to the class of inorganic compounds known as transition metal nitrates. These are inorganic compounds in which the largest oxoanion is nitrate, and in which the heaviest atom not in an oxoanion is a transition metal.
External Descriptors Not available
3D Structure
Interactive Chemical Structure Model





Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:
Chemical and Physical Properties
Molecular Weight288.920 g/mol
XLogP3
Hydrogen Bond Donor Count0
Hydrogen Bond Acceptor Count9
Rotatable Bond Count0
Exact Mass288.869 Da
Monoisotopic Mass288.869 Da
Topological Polar Surface Area189.000 Ų
Heavy Atom Count13
Formal Charge0
Complexity18.800
Isotope Atom Count0
Defined Atom Stereocenter Count0
Undefined Atom Stereocenter Count0
Defined Bond Stereocenter Count0
Undefined Bond Stereocenter Count0
The total count of all stereochemical bonds0
Covalently-Bonded Unit Count4
Documents & Articles
Citations of This Product
References
1. Yuanjie Xu, Zemin An, Xin Yu, Jikang Yao, Qian Lv, Hua Yang, Zhengang Lv, Huichuang Guo, Qike Jiang, Wei Liu, Lizhi Wu, Li Tan, Yihu Dai, Yu Tang.  (2023)  Enhanced catalytic stability and structural evolution of Rh-BN interface in dry reforming of methane under intensified CO2 partial pressure.  JOURNAL OF CATALYSIS,      [PMID:] [10.1016/j.jcat.2023.08.010]
2. Qian Xiao, Xueyu Wang, Lianjun Song, Fengfeng Li, Qiuju Li, Lanlan He, Zhen Shen, Fangxiang Luo, Songdong Ding.  (2023)  Highly efficient and selective adsorption of palladium(II) from simulated nuclear waste solution using Amberlite XAD-7 resin impregnated with a phenanthroline-derived diamide.  HYDROMETALLURGY,      [PMID:] [10.1016/j.hydromet.2023.106127]
3. Wentao Wang, Shichang Zhang, Lifeng Chen, Zengyuan Li, Kun Wu, Ye Zhang, Zhe Su, Xiangbiao Yin, Mohammed F. Hamza, Yuezhou Wei, Shunyan Ning.  (2023)  Efficient separation of palladium from nitric acid solution by a novel silica-based ion exchanger with ultrahigh adsorption selectivity.  SEPARATION AND PURIFICATION TECHNOLOGY,      [PMID:] [10.1016/j.seppur.2023.124326]
4. Haoran Dong, Shunyan Ning, Zengyuan Li, Sizhi Xu, Shichang Zhang, Xinpeng Wang, Youbin Wang, Lifeng Chen, Xiangbiao Yin, Toyohisa Fujita, Mohammed F. Hamza, Yuezhou Wei.  (2023)  Efficient separation of palladium from high-level liquid waste with novel adsorbents prepared by sulfhydryl organic ligands containing imidazole, thiazole and oxazole composited with XAD7HP.  Journal of Water Process Engineering,      [PMID:] [10.1016/j.jwpe.2023.103681]
5. Xueyu Wang, Lianjun Song, Long Li, Zhuang Wang, Qiuju Li, Lanlan He, Xuanhao Huang, Songdong Ding.  (2022)  Extraction and Complexation Investigation of Palladium(II) by a Nitrilotriacetate-Derived Triamide Ligand.  INORGANIC CHEMISTRY,      [PMID:35977422] [10.1021/acs.inorgchem.2c00675]
6. Kubota Masahiko, Wu Hao, Kim Seong-Yun.  (2022)  Combination of N’-N’-di-n-hexyl-thiodiglycolamide and 2,2’-[(2-ethylhexyl)imino]bis[N,N-bis(2-ethylhexyl) acetamide] for the enhanced adsorption of palladium ions from simulated high-level liquid waste.  JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,  331  (4): (1731-1740).  [PMID:] [10.1007/s10967-022-08230-3]
7. Qiangqiang Xue, Huilin Yi, Zhengwen Li, Zhao Jiang, Meng Chen, Yujun Wang, Binhang Yan, Guangsheng Luo.  (2022)  Experimental and DFT studies on diesel-steam-reforming to hydrogen over a bimetallic Rh–Ni-based MgO-Al2O3 microsphere catalyst.  FUEL,      [PMID:] [10.1016/j.fuel.2022.123632]
8. Weifeng Chen, Guo Lv, Jinrun Fu, Haiyan Ren, Jialu Shen, Jie Cao, Xiang Liu.  (2021)  Demonstration of Controlled Hydrogen Release Using Rh@GQDs during Hydrolysis of NH3BH3.  ACS Applied Materials & Interfaces,      [PMID:34652125] [10.1021/acsami.1c15660]
9. Shiwei Wang, Bo Yan, Juan Chai, Tianhao Li, Hongbo Yu, Tong Li, Peng Cao, Fan Yang, Xuemin Yuan, Hongfeng Yin.  (2021)  Rhodium Encapsulated within Silicalite-1 Zeolite as Highly Efficient Catalyst for Nitrous Oxide Decomposition: From Single Atoms to Nanoclusters and Nanoparticles.  EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,  2021  (23): (2201-2210).  [PMID:] [10.1002/ejic.202100106]
10. Shunyan Ning, Shichang Zhang, Wei Zhang, Jie Zhou, Siyi Wang, Xinpeng Wang, Yuezhou Wei.  (2019)  Separation and recovery of Rh, Ru and Pd from nitrate solution with a silica-based IsoBu-BTP/SiO2-P adsorbent.  HYDROMETALLURGY,      [PMID:] [10.1016/j.hydromet.2019.105207]
11. Ning Li, Weifeng Chen, Jialu Shen, Shaona Chen, Xiang Liu.  (2019)  Synthesis of graphene quantum dots stabilized bimetallic AgRh nanoparticles and their applications.  INORGANICA CHIMICA ACTA,      [PMID:] [10.1016/j.ica.2019.119031]
12. Huixian Zhong, Jiaming Wang, Kang An, Kegong Fang, Yuan Liu.  (2019)  Nanoparticles of Rh confined and tailored by LaFeO3–La2O3 on SiO2 for direct ethanol synthesis from syngas.  Catalysis Science & Technology,  (13): (3454-3468).  [PMID:] [10.1039/C9CY00416E]
13. Huixian Zhong, Jiaming Wang, Shaoxia Guo, Kegong Fang, Yuan Liu.  (2019)  Mutual Tailored Bimetallic Rh–Co Supported on La Modified SiO2 for Direct Ethanol Synthesis from Syngas.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/acs.iecr.8b05474]
14. Ning Huang, Yue Ma, Boyang Liu, Letong Yang, Xiaocheng Lan, Xiaodong Wu, Tiefeng Wang.  (2024)  Designing a Rh-based bimetallic catalyst for heterogeneous ethylene hydroformylation: Combing theoretical predictions and experimental screening.  Catalysis Science & Technology,      [PMID:] [10.1039/D4CY00959B]
15. Jinni Shen, Yuhua Zhong, Jianhan Lin, Haifeng Li, Chengwei Qiu, Xu Liu, Xun Wang, Rong Hu, Jinlin Long, Xuxu Wang, Zizhong Zhang.  (2024)  Non-stoichiometric problem of photocatalytic water splitting on γ-Ga2O3: Cause and solution.  JOURNAL OF CATALYSIS,      [PMID:] [10.1016/j.jcat.2024.115929]
16. Jingjing Zhang, Yang Feng, Lixia Ling, Caiping Ma, Jungang Wang, Riguang Zhang, Maohong Fan, Bo Hou, Debao Li, Baojun Wang.  (2024)  Ratio screening of high performance Rh-Ni catalyst for ethanol synthesis from syngas: An integration of theoretical and experimental investigation.  Molecular Catalysis,      [PMID:] [10.1016/j.mcat.2024.114124]
17. Caixia Zhu, Kaizhuang Xu, Yuan Fang, Qian Lv, Kun Jiang, Huibo Zhao, Yang Chen, Peng Wang, Hua Yang, Lizhi Wu, Yu Tang, Li Tan.  (2022)  Synergetic effect of Ce/Zr for ethanol synthesis from syngas over Rh-based catalyst.  FUEL,      [PMID:] [10.1016/j.fuel.2022.126770]
18. Shichang Zhang, Qunying Huang, Lifeng Chen, Yilai Zhong, Fengtao Hu, Kun Wu, Xiangbiao Yin, Mohammed F. Hamza, Yuezhou Wei, Shunyan Ning.  (2024)  Phosphination of amino-modified mesoporous silica for the selective separation of strontium.  JOURNAL OF HAZARDOUS MATERIALS,      [PMID:38341887] [10.1016/j.jhazmat.2024.133741]
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