(S)-(−)-3-Methoxy-2-methyl-3-oxopropylzinc bromide solution - 0.5M in THF , CAS No.312693-18-8

CAS: 312693-18-8 Cat. No.: S465957 Molecular Weight: 246.42 EC Number: 106-559-8 PubChem CID: 16213687

GRADE & PURITY 0.5M in THF

Synonyms

3-Methoxy-(2S)-(-)-methyl-3-oxopropylZinc bromide, 0.5M in tetrahydrofuran | (S)-(-)-3-methoxy-2-methyl-3-oxopropylzinc bromide | (S)-(3-methoxy-2-methyl-3-oxopropyl)zinc(II) bromide | (S)-3-methoxy-2-methyl-3-oxopropylzinc bromide | MFCD00671994 | AKOS01

Storage

Store at 2-8°C

Shipped In

Wet ice

Overview

Description

(S)-(−)-3-Methoxy-2-methyl-3-oxopropylzinc bromide can be used:As an intermediate in the total synthesis of macrolide derivative laingolide B stereoisomers.As a substrate in the synthesis of (3R)-1-benzyl-3-methylpyrrolidine-2,5-dione (aliphatic carboxamide) using NiII-pincer complexes.

Specifications

Synonyms

3-Methoxy-(2S)-(-)-methyl-3-oxopropylZinc bromide, 0.5M in tetrahydrofuran | (S)-(-)-3-methoxy-2-methyl-3-oxopropylzinc bromide | (S)-(3-methoxy-2-methyl-3-oxopropyl)zinc(II) bromide | (S)-3-methoxy-2-methyl-3-oxopropylzinc bromide | MFCD00671994 | AKOS01

Specifications & Purity

0.5M in THF

Legal Information

Rieke® Metals, Inc. 产品 ®Rieke Metals, Inc. 的注册商标

Storage

Store at 2-8°C

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Names and Identifiers

• Canonical Smiles: CC([CH2-])C(=O)OC.[Zn+]Br
• IUPAC Name: bromozinc(1+);methyl (2S)-2-methanidylpropanoate
• InChIKey: ZHZWKFSRZQRSJL-FHNDMYTFSA-M
• INCHI: 1S/C5H9O2.BrH.Zn/c1-4(2)5(6)7-3;;/h4H,1H2,2-3H3;1H;/q-1;;+2/p-1/t4-;;/m0../s1
• Isomeric SMILES: C[C@H]([CH2-])C(=O)OC.[Zn+]Br
• WGK Germany: 3
• PubChem CID: 16213687
• UN Number: 2924
• Packing Group: II
• Molecular Weight: 246.42

Chemical and Physical Properties

• Flash Point(°F): 1.4 °F
• Flash Point(°C): -17 °C
• Boil Point(°C): 65-67° C