Phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide（BAPO） - ≥97% , CAS No.162881-26-7

CAS: 162881-26-7 Cat. No.: P138333 Molecular Weight: 418.46 EC Number: 605-307-9 PubChem CID: 164512

GRADE & PURITY ≥97%

Synonyms

Phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide, 97%, powder | NCGC00256655-01 | A810419 | D78117 | bis(2,4,6-trimethylbenzoyl)-phenyl phosphine oxide | P2312 | DTXSID8044597 | FT-0656698 | UNII-JOV61FMS35 | SCHEMBL15158 | bis(2,4,6-trimethylbenzoyl)phen

Storage

Protected from light,Room temperature,Desiccated,Cool

Shipped In

Normal

Overview

For the reaction mechanism of monoacyl- and bisacylphosphine oxide photoinitiators.
Versatile UV photoinitiator for radical polymerization of unsaturated resins, especially pigmented formulations.

Phenylbis(2,4,6-trimethylbenzoyl) phosphineoxide (BAPO) is potential photoinitiator widely used in the preparation ofdental composites. 

Application：

Phenylbis(2,4,6-trimethylbenzoyl) phosphine oxide can be used as a photoinitiator for:
Radical polymerization of dental resins. BAPO enhances the polymerization rate and conversion compared to other initiators.
Preparation of divinylbenzene modified polymer-based ceramic materials for high temperature sensor applications.

Specifications

Synonyms

Phenylbis(2, 4, 6-trimethylbenzoyl)phosphine oxide, 97%, powder | NCGC00256655-01 | A810419 | D78117 | bis(2, 4, 6-trimethylbenzoyl)-phenyl phosphine oxide | P2312 | DTXSID8044597 | FT-0656698 | UNII-JOV61FMS35 | SCHEMBL15158 | bis(2, 4, 6-trimethylbenzoyl)phen

Specifications & Purity

≥97%

Storage

Protected from light, Room temperature, Desiccated, Cool

Shipped In

Normal

Purity

≥97%

Names and Identifiers

• Pubchem Sid: 488188362
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/488188362
• Canonical Smiles: CC1=CC(=C(C(=C1)C)C(=O)P(=O)(C2=CC=CC=C2)C(=O)C3=C(C=C(C=C3C)C)C)C
• IUPAC Name: [phenyl-(2,4,6-trimethylbenzoyl)phosphoryl]-(2,4,6-trimethylphenyl)methanone
• InChIKey: GUCYFKSBFREPBC-UHFFFAOYSA-N
• INCHI: 1S/C26H27O3P/c1-16-12-18(3)23(19(4)13-16)25(27)30(29,22-10-8-7-9-11-22)26(28)24-20(5)14-17(2)15-21(24)6/h7-15H,1-6H3
• Isomeric SMILES: CC1=CC(=C(C(=C1)C)C(=O)P(=O)(C2=CC=CC=C2)C(=O)C3=C(C=C(C=C3C)C)C)C
• PubChem CID: 164512
• Molecular Weight: 418.46

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Class Benzene and substituted derivatives
      • Subclass Benzoic acids and derivatives

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Class: Benzene and substituted derivatives
• Subclass: Benzoic acids and derivatives
• Intermediate Tree Nodes: Not available
• Direct Parent: Benzoic acids and derivatives
• Alternative Parents: Benzoyl derivatives Phenylphosphines and derivatives Organophosphine oxides Organopnictogen compounds Organooxygen compounds Organic oxides Hydrocarbon derivatives
• Molecular Framework: Aromatic homomonocyclic compounds
• Substituents: Benzoic acid or derivatives - Benzoyl - Phenylphosphine - Organophosphine oxide - Organic oxygen compound - Organopnictogen compound - Organic oxide - Hydrocarbon derivative - Organophosphorus compound - Organooxygen compound - Aromatic homomonocyclic compound
• Description: This compound belongs to the class of organic compounds known as benzoic acids and derivatives. These are organic compounds containing a carboxylic acid substituent attached to a benzene ring.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: solubility acetone, acetonitrile, toluene, and hexanediol diacrylate: soluble
• Sensitivity: Light sensitive
• Melt Point(°C): 131-135 °C
• Molecular Weight: 418.500 g/mol
• XLogP3: 6.000
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 5
• Exact Mass: 418.17 Da
• Monoisotopic Mass: 418.17 Da
• Topological Polar Surface Area: 51.200 Ų
• Heavy Atom Count: 30
• Formal Charge: 0
• Complexity: 610.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

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78. Zhenyu Li, Yaping Wang, Zekun Zhang, Jianxin Zhou, Yaoming Wang, Feiran Li, Zhuang Hao, Hui Sun.  (2025)  A synergistically designed strain-insensitive conductive hydrogel with humidity-adaptivity supporting sustained functional durability.  Materials Horizons,      [PMID:40814785] [10.1039/D5MH01139F]

79. Renjie Cao, Chuanzhen Huang, Zhenyu Shi, Zhen Wang, Longhua Xu, Shuiquan Huang, Meina Qu, Zhengkai Xu, Dijia Zhang, Baosu Guo, Tianye Jin, Hanlian Liu, Dun Liu, Peng Yao.  (2025)  Improvement of viscosity and stability of high-solid-loading ceramic slurry by the integrated technology of plasma hydroxylation and solid particle gradation.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,      [PMID:] [10.1016/j.colsurfa.2025.138593]

80. Panfeng Wang, Li Zhang, Wenting Xing, Zhaoyang Lu, Xiang Qi, Yongli Chai, Zengbing Zhao.  (2025)  3D Printing of Monolithic Carbon Electrodes with Hierarchical Pores Enabled by Nucleated Resin.  Energy Technology,      [PMID:] [10.1002/ente.202501225]

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82. Ning Wang, Junjiang Fan, Chi Zhang, Yingna Wu, Rui Yang, Hai Chang, Zirong Zhai.  (2025)  Oxygen-Free Pretreatment Enables Crack-Free Air Debinding in Vat Photopolymerized Silicon Nitride (Si3N4) Green Bodies.  CERAMICS INTERNATIONAL,      [PMID:] [10.1016/j.ceramint.2025.10.310]

83. Rongwen Wang, Jia Lin, Shuyuan Cui, Jingjing Liu, Yihang Yang, Guimei Huang, Jinhuo Wang.  (2025)  Fabrication and electrical conductivity of CNT-modified SiOC polymer-derived ceramics.  CERAMICS INTERNATIONAL,      [PMID:] [10.1016/j.ceramint.2025.10.386]

84. Chen Shaojun, Deng Yujie, Zhang Yonghang, Guo Sisi, Zhuo Haitao, Lu Wei, Wu Bing.  (2025)  Self-healing ionic gels for wearable strain sensors: synthesis, characterization, and applications in human motion detection.  JOURNAL OF MATERIALS SCIENCE,      [PMID:] [10.1007/s10853-025-11199-5]

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91. An Wang, Zhengheng Zhang, Yuxuan Qiao, Yao Xiao, Tian Cheng, Tengjiao Wang, Peng Li.  (2026)  Tough and mechanically damage-resistant polysiloxane-polyacrylate elastomers for dielectric elastomer actuators.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2026.173641]

92. Xu Jie, Wan Hong, Fang Zizheng, Peng Xinyang, Sun Jinteng, Liang Jing, Wang Xinxin, Lan Changming, Wu Ming-Bang, Zheng Ning, Liu Junqiu, Wu Baiheng.  (2026)  Continuous fabrication of Janus liquid crystal elastomer fibers with programmable actuation.  Nature Communications,      [PMID:41629322] [10.1038/s41467-026-68992-2]

93. Qiqi Xu, Pengfei Bi, Yingyue Tan, Jilong Ma, Xiong Zhang, Huijuan Zhang, Jinling Ma, Yu Wang.  (2026)  3D-printed polydimethylsiloxane separators with triply periodic minimal surface structure enable uniform zinc deposition.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2026.166161]

94. Huang Yan, Guo Xiaoxiao, Deng Yi, Ye Siyi, Zhu Yanling, Liu Zenghe, Chen Jianwen, Zhu Yutian.  (2026)  Atom-economy upcycling of commodity thermoset polyurethane into photocuring 3D printing resins based on selective cleavage—crosslink strategy.  Nature Communications,      [PMID:] [10.1038/s41467-026-70951-w]

95. Shijie Xu, Ying Li, Xingsheng Wan, Mingen Fei, Wendi Liu, Renhui Qiu.  (2026)  Sustainable 4D printing of bio-based shape memory polymer composites derived from isoborneol–thioctic acid with photothermal actuation.  COMPOSITES COMMUNICATIONS,      [PMID:] [10.1016/j.coco.2026.102807]

96. Yubei Zhang, Shan Li, Xiaodong Liu, Xin Li, Bingshan Liu, Tong Zhao, Weijian Han, Gong Wang.  (2026)  Interfacial evolution and strengthening mechanism in DLP 3D-Printed In718/SiBCN cermet composites via in-situ reaction.  MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING,      [PMID:] [10.1016/j.msea.2026.150396]