Tributyltin hydride - ≥97%, stabilized with 0.05% BHT , CAS No.688-73-3

CAS: 688-73-3 Cat. No.: T106234 Molecular Weight: 291.06 Beilstein Registry Number: 3587329 EC Number: 211-704-4 PubChem CID: 3032732

GRADE & PURITY ≥97%, stabilized with 0.05% BHT

Synonyms

T1473 | A836269 | DTXSID0040709 | MFCD00009416 | Tributlytin | Tributyltin | tributyl-tin | PIILXFBHQILWPS-UHFFFAOYSA-N | TRIBUTYLTIN HYDRIDE [MI] | AKOS032949789 | FT-0636016 | TBY | TRIBUTYL TIN | EINECS 211-704-4 | GS-6317 | UNII-4XDX163P3D | AKOS01590

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice,FedEx DG Service

Overview

A widely used radical reagent used in reductive cleavage, radical dehalogenation, and intramolecular radical cyclization. Radical promoted intramolecular cyclization leading to isoxazolo-benzaulene ring system. Vinyl tin fragment used in a synthesis of (+)-panepophenanthrin via biomimetic Diels-Alder dimerization.

application：

Tri-n-butyltin hydride is used as a radical reagent in reductive cleavage, radical dehalogenation and intramolecular radical cyclization. It also promotes intramolecular cyclization leading to isoxazolo-benzaulene ring system. Further, it acts as a reducing agent for the conversion of alkyl halides to hydrocarbons. In addition to this, it is used in a veterinary anthelmintic for poultry and an intermediate to make other butyltin compounds.

Specifications

Synonyms

T1473 | A836269 | DTXSID0040709 | MFCD00009416 | Tributlytin | Tributyltin | tributyl-tin | PIILXFBHQILWPS-UHFFFAOYSA-N | TRIBUTYLTIN HYDRIDE [MI] | AKOS032949789 | FT-0636016 | TBY | TRIBUTYL TIN | EINECS 211-704-4 | GS-6317 | UNII-4XDX163P3D | AKOS01590

Specifications & Purity

≥97%, stabilized with 0.05% BHT

Storage

Store at 2-8°C, Argon charged

Shipped In

Wet ice, FedEx DG Service

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥97%

Names and Identifiers

• Canonical Smiles: CCCC[Sn](CCCC)CCCC
• InChIKey: PIILXFBHQILWPS-UHFFFAOYSA-N
• INCHI: 1S/3C4H9.Sn/c3*1-3-4-2;/h3*1,3-4H2,2H3
• Isomeric SMILES: CCCC[Sn](CCCC)CCCC
• WGK Germany: 3
• PubChem CID: 3032732
• UN Number: 2788
• Packing Group: III
• Molecular Weight: 291.06
• Beilstein: 3587329

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organometallic compounds
    • Class Organo-post-transition metal compounds
      • Subclass Organotin compounds
        • Level5 Triorganotin compounds
          • Level6 Trialkyltins

• Kingdom: Organic compounds
• Superclass: Organometallic compounds
• Class: Organo-post-transition metal compounds
• Subclass: Organotin compounds
• Intermediate Tree Nodes: Triorganotin compounds
• Direct Parent: Trialkyltins
• Alternative Parents: Organic salts Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Trialkyltin - Hydrocarbon derivative - Organic salt - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as trialkyltins. These are triorganotin compounds where the tin atom is linked to exactly three alkyl groups.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Immiscible with water.
• Sensitivity: Air, Moisture and Heat Sensitive
• Refractive Index: 1.473
• Flash Point(°F): 104 °F
• Flash Point(°C): 40℃
• Boil Point(°C): 80°C
• Melt Point(°C): 0-1℃
• Molecular Weight: 290.050 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 9
• Exact Mass: 291.113 Da
• Monoisotopic Mass: 291.113 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 13
• Formal Charge: 0
• Complexity: 72.100
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3

References

1. Zhe Xu, Wang Yin, Yong Guan, Meidong Lang.  (2023)  The “De−Re Polymerization” Strategy: From Nondegradable Pet to Degradable Peat.  MACROMOLECULAR CHEMISTRY AND PHYSICS,      [PMID:] [10.1002/macp.202300149]

2. Enjie He, Kai Tu, Jiannan Cheng, Huanjun Lu, Lifen Zhang, Zhenping Cheng, Xiulin Zhu.  (2021)  Multimesophase transitions of main-chain liquid crystalline copolymers with strictly alternating fluorocarbon chains.  Polymer Chemistry,  12  (5): (736-743).  [PMID:] [10.1039/D0PY01644F]

3. Changchao Jia, Ping Yang, Hsueh-Shih Chen, Junpeng Wang.  (2015)  Template-free synthesis of mesoporous anatase titania hollow spheres and their enhanced photocatalysis.  CRYSTENGCOMM,  17  (15): (2940-2948).  [PMID:] [10.1039/C4CE02358G]

4. Peng Liu, Jiexing Liang, Shen Chen, Hailiang Zhang.  (2014)  Bulk and solution properties of a thermo-responsive rod–coil block polymer based on poly(N-isopropylacrylamide).  RSC Advances,  4  (90): (49028-49039).  [PMID:] [10.1039/C4RA07179D]

5. Jinkai Shu, Bozhi Ren, Wei Zhang, An Wang, Sen Lu, Shuyu Liu.  (2022)  Influencing Factors and Kinetics of Modified Shell Powder/La-Fe-TiO2 Photocatalytic Degradation of Pyridine Wastewater.  International Journal of Environmental Research and Public Health,  19  (22): (14835).  [PMID:36429553] [10.3390/ijerph192214835]