Tributyltin hydride solution - 1 M in cyclohexane , CAS No.688-73-3

CAS: 688-73-3 Cat. No.: T433324 Molecular Weight: 291.06 Beilstein Registry Number: 3587329 EC Number: 211-704-4 PubChem CID: 3032732

GRADE & PURITY 1 M in cyclohexane

Synonyms

T1473 | A836269 | DTXSID0040709 | MFCD00009416 | Tributlytin | Tributyltin | tributyl-tin | PIILXFBHQILWPS-UHFFFAOYSA-N | TRIBUTYLTIN HYDRIDE [MI] | AKOS032949789 | FT-0636016 | TBY | TRIBUTYL TIN | EINECS 211-704-4 | GS-6317 | UNII-4XDX163P3D | AKOS01590

Storage

Room temperature

Shipped In

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Overview

Application

Reactant or reagent for: Alkyne hydrostannations Intramolcular cyclization for the synthesis of zoanthamine alkaloids Stereoselective C-glycosylation of pyranosides using Heck allylation Synthesis of phenylbutenoid dimers for use in treating diseases Preparation of N -acyl derivatives of ecteinascidin 770 Syntehsis of cyclonucleosides using black light induced radical cyclization

Specifications

Synonyms

T1473 | A836269 | DTXSID0040709 | MFCD00009416 | Tributlytin | Tributyltin | tributyl-tin | PIILXFBHQILWPS-UHFFFAOYSA-N | TRIBUTYLTIN HYDRIDE [MI] | AKOS032949789 | FT-0636016 | TBY | TRIBUTYL TIN | EINECS 211-704-4 | GS-6317 | UNII-4XDX163P3D | AKOS01590

Specifications & Purity

1 M in cyclohexane

Storage

Room temperature

Shipped In

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This product requires cold chain shipping. Ground and other economy services are not available.

Names and Identifiers

• Canonical Smiles: CCCC[Sn](CCCC)CCCC
• InChIKey: PIILXFBHQILWPS-UHFFFAOYSA-N
• INCHI: 1S/3C4H9.Sn/c3*1-3-4-2;/h3*1,3-4H2,2H3
• Isomeric SMILES: CCCC[Sn](CCCC)CCCC
• WGK Germany: 3
• PubChem CID: 3032732
• UN Number: 2788
• Packing Group: III
• Molecular Weight: 291.06
• Beilstein: 3587329

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organometallic compounds
    • Class Organo-post-transition metal compounds
      • Subclass Organotin compounds
        • Level5 Triorganotin compounds
          • Level6 Trialkyltins

• Kingdom: Organic compounds
• Superclass: Organometallic compounds
• Class: Organo-post-transition metal compounds
• Subclass: Organotin compounds
• Intermediate Tree Nodes: Triorganotin compounds
• Direct Parent: Trialkyltins
• Alternative Parents: Organic salts Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Trialkyltin - Hydrocarbon derivative - Organic salt - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as trialkyltins. These are triorganotin compounds where the tin atom is linked to exactly three alkyl groups.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Refractive Index: 1.473
• Flash Point(°F): 104 °F
• Flash Point(°C): 40℃
• Boil Point(°C): 80°C
• Melt Point(°C): 0-1℃
• Molecular Weight: 290.050 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 9
• Exact Mass: 291.113 Da
• Monoisotopic Mass: 291.113 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 13
• Formal Charge: 0
• Complexity: 72.100
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3

References

1. Zhe Xu, Wang Yin, Yong Guan, Meidong Lang.  (2023)  The “De−Re Polymerization” Strategy: From Nondegradable Pet to Degradable Peat.  MACROMOLECULAR CHEMISTRY AND PHYSICS,      [PMID:] [10.1002/macp.202300149]

2. Enjie He, Kai Tu, Jiannan Cheng, Huanjun Lu, Lifen Zhang, Zhenping Cheng, Xiulin Zhu.  (2021)  Multimesophase transitions of main-chain liquid crystalline copolymers with strictly alternating fluorocarbon chains.  Polymer Chemistry,  12  (5): (736-743).  [PMID:] [10.1039/D0PY01644F]

3. Changchao Jia, Ping Yang, Hsueh-Shih Chen, Junpeng Wang.  (2015)  Template-free synthesis of mesoporous anatase titania hollow spheres and their enhanced photocatalysis.  CRYSTENGCOMM,  17  (15): (2940-2948).  [PMID:] [10.1039/C4CE02358G]

4. Peng Liu, Jiexing Liang, Shen Chen, Hailiang Zhang.  (2014)  Bulk and solution properties of a thermo-responsive rod–coil block polymer based on poly(N-isopropylacrylamide).  RSC Advances,  4  (90): (49028-49039).  [PMID:] [10.1039/C4RA07179D]

5. Jinkai Shu, Bozhi Ren, Wei Zhang, An Wang, Sen Lu, Shuyu Liu.  (2022)  Influencing Factors and Kinetics of Modified Shell Powder/La-Fe-TiO2 Photocatalytic Degradation of Pyridine Wastewater.  International Journal of Environmental Research and Public Health,  19  (22): (14835).  [PMID:36429553] [10.3390/ijerph192214835]